Aus der Branche

CO₂ as renewable carbon source
Carbon is the main element in numerous materials used in industrial processes and in our daily lives. It is currently mostly provided from fossil sources. But what if carbon could be used directly from CO₂ emissions? Biotechnology shows particularly great potential for the eco-effective conversion of climate-damaging CO₂ emissions into valuable basic chemicals. A consortium of 12 partners investigated this pathway in the EU-funded BioRECO₂VER project, examining the conversion of CO₂ emissions from refineries and the cement industry into the chemical building blocks isobutene (C₄H₈) and lactate (C₂H₆O₃).

Innovative chemo-enzymatic concept for CO₂ Capture
Project partner Luleå University of Technology (LTU) focused on the first process step of capturing and concentrating CO₂ from industrial point sources. Their team developed a hybrid chemo-enzymatic process consisting of a novel solvent blend and an ultrastable carbonic anhydrase (CA) enzyme. The solvent blend included an amino acid ionic liquid and a tertiary amine and displayed a good compromise between enzyme compatibility, absorption rate, capacity and desorption potential. In addition, LTU generated ultrastable enzyme mutants that showed 50% increased resistance to selected flue gas inhibitors compared to the original CA. This 3-component CO₂ capture process was scaled up in a pilot rig, and the set-up further used for real off gas pre-treatment in the project.

Two unique pilots for biotechnological CO₂ Conversion/Utilization
The biotechnological conversion of (captured) CO₂ and the co-substrate hydrogen by microorganisms poses technical and economic challenges because it takes place in the liquid phase and the substrates are gases which are poorly soluble. The BioRECO₂VER project investigated two approaches to address this: fermentation under elevated pressure and bio-electrochemistry with in situ production of hydrogen.

Pressurized fermenter
Project coordinator VITO designed a flexible and multifunctional high-pressure fermenter, customized for research activities with advanced online sensors, monitoring and control, and also including a membrane filtration unit to achieve high concentrations of the microbial biocatalysts. The set-up was broadly tested in the BioRECO₂VER project both with pure CO₂ and CO₂-rich off-gases but can also be used for investigations involving other poorly soluble gases, such as methane, oxygen, or synthesis gas. Pressures up to 10 bar can be applied.

First solely CO₂-based bio-electrochemical platform
University of Girona designed and tested a bio-electrochemical platform. The key differentiators of the pilot plant are:

• Two parallel lines to test engineered strains and bio-electrochemical systems
• Fully automated pilot plant capable to control key operational parameters (pCO₂, pO₂, pH₂, pH, Temperature) to intensify the process performance
• Solid-liquid separation unit (membrane) to recover the planktonic cells and return them into the bio-electrochemical systems.

This unique infrastructure will be used beyond the project to support further research and development activities in the broad area of CO₂ capture and conversion.

Indorama Ventures Public Company Limited (IVL) was awarded “Best Sustainability-Linked Transaction & Best ESG-Linked Financing Deal of the Year” for its THB 10 billion Sustainability-Linked Bond (SLB) issued in November 2021.

The award was announced at the 15th Best Deal & Solution Awards 2021 by Alpha Southeast Asia, an institutional publication focused on investment in Southeast Asia. This recognition marks IVL's commitment to sustainable growth and ESG performance as a global leader in the chemical industry.

Yash Lohia, Chairman of ESG Council at Indorama Ventures, said, "This award reflects our long-standing commitment to sustainability and creating opportunities for investors to take part in the positive transformation of the chemical industry. This award confirms that financial markets value our ambitious sustainability and ESG efforts towards a more sustainable future.”

IVL's THB 10 billion issuance sets a new benchmark as the largest SLB transaction in Thailand and the first offered to both institutions and high-net-worth investors. The financial instrument is linked to the company's sustainability goals of reducing GHG emissions intensity by 10% by 2025, increasing recycling of PET bale input to 750,000 tons per year by 2025, and achieving 25% renewable electricity consumption in 2030.

IVL appointed Bangkok Bank, Kasikorn Bank, Krungthai Bank, Siam Commercial Bank, and the Bangkok branch of HSBC as as arrangers and bookrunners for the green transaction.

• ADNOC und Borealis bestätigen endgültige Investitionsvereinbarung für Borouge 4 in Ruwais, Vereinigte Arabische Emirate (VAE) mit jährlicher Polyethylen-Produktion von 1,4 Millionen Tonnen
• Das Erweiterungsprojekt umfasst die Errichtung eines 1,5 Millionen-Tonnen-Ethancrackers, zweier hochmoderner Borstar®-Polyethylenanlagen sowie einer Produktionsanlage für vernetztes Polyethylen
• Borouge 4 wird die wachsende Kundennachfrage im Nahen Osten, Afrika und Asien mit differenzierten Polyolefinlösungen für die Bereiche Energie, Infrastruktur und Fortschrittliche Verpackungen bedienen
• Die neue Anlage profitiert von branchenführenden Technologien, welche die Energieeffizienz maßgeblich verbessern und die Emissionen senken, wofür auch eine Studie zur Kohlenstoffabscheidung durchgeführt wird
• Mit dieser Erweiterung wird Borouge zum größten Single-Site-Polyolefinkomplex ausgebaut und die gesamte TA'ZIZ Industrial Chemicals Zone mit Rohstoffen versorge

ADNOC und Borealis AG unterzeichneten die endgültige Investitionsvereinbarung für die vierte Borouge-Anlage („Borouge 4“) im Polyolefin-Produktionskomplex in Ruwais, VAE in Höhe von USD 6,2 Milliarden.

Die Expansion im Weltmaßstab unterstreicht das Engagement beider Partner für das weitere Wachstum von Borouge sowie für eine fortschrittliche Chemikalienproduktion in Ruwais, die eine wesentliche Säule der Technologie-, Innovations- und Industrieentwicklungsstrategie von Abu Dhabi und der Vereinigten Arabischen Emirate darstellt. Borouge produziert essentielle industrielle Rohstoffe, die einerseits an globale Kunden geliefert und andererseits auch von regionalen Unternehmen genutzt werden, was die lokalen Versorgungsketten sowie die Wertschöpfung im Land stärkt.

Borouge 4 wird vom erwarteten Anstieg der Kundennachfrage nach Polyolefinen profitieren, die durch die zunehmende Nutzung in Industrieprodukten im Nahen Osten, Afrika und Asien angetrieben wird. Darüber hinaus wird die Anlage den nächsten Wachstumsschritt des Industriekomplexes Ruwais einläuten, indem sie die TA'ZIZ Industrial Chemicals Zone mit Rohstoffen versorgt.

Borouge 4 wird einen für die Branche Fokus auf Nachhaltigkeit legen und dabei von den jeweiligen Kompetenzen seiner beiden Eigentümer profitieren. Die Anlage wird Borealis‘ unternehmenseigene Borstar-Technologie nutzen, um ein Produktportfolio zu entwickeln, das sich auf langlebige Anwendungen für die Bereiche Energie, Infrastruktur, fortschrittliche Verpackungen sowie Landwirtschaft konzentriert. In Verbindung mit dem Hexen-Co-Monomer wird Borealis‘ einzigartige Technologie die Produktion fortschrittlicher Verpackungsmaterialien ermöglichen, die einen Polyethylen-Recyclinganteil von bis zu 50 % aufweisen.

Vorbehaltlich einer umfassenden Studie könnte eine Kohlenstoffabscheidungsanlage, die die CO2-Emissionen um 80 % reduzieren würde, ebenfalls rechtzeitig bis zur Inbetriebnahme des Borouge-4-Komplexes einsatzfähig sein. Die Anlage ist außerdem so konzipiert, dass sie die jüngsten Initiativen von ADNOC für saubere Energie nutzt und die Kohlenstoffabhängigkeit seiner Stromversorgung durch den Zugang zu den sauberen Energiequellen von Abu Dhabi verringert. Diese Initiativen stehen im Einklang mit der strategischen „Netto-Null bis 2050“- Initiative der Vereinigten Arabischen Emirate.

Die erste Borouge-Anlage, die 450.000 Tonnen Polyethylen pro Jahr herstellt, wurde im Jahr 2001 in Betrieb genommen. Mit „Borouge 2 und Borouge 3 wurde die jährliche Produktionskapazität in den Jahren 2010 bzw. 2014 auf 2 bzw. 4,5 Millionen Tonnen Polyethylen und Polypropylen ausgebaut. Borouge 4 wird eine jährliche Polyolefinproduktion von 6,4 Millionen Tonnen ermöglichen, wodurch Borouge zur weltweit größten Single-Site-Polyolefinanlage wird.

Umfang von Borouge 4:

• ein Ethancracker mit einem jährlichen Output von 1,5 Millionen Ethylen, welcher der vierte Cracker in Borouges integriertem Petrochemie-Komplex in Ruwais sein wird;
• zwei zusätzliche Borstar®-Polyethylen- (PE) Anlagen, beide mit einer Jahreskapazität von jeweils 700.000 Tonnen, welche Borealis‘ hochmoderne Borstar-Technologie der dritten Generation (3G) nutzen;
• eine Produktionsanlage für vernetztes PE (XLPE) mit einer Jahreskapazität von 100.000 Tonnen;
• eine Hexen-1-Anlage, die Co-Monomere für bestimmte Polyethylen-Materialien produzieren wird.

Archroma celebrates 8 years of leading the way to a sustainable world, with innovations and solutions aimed at creating added value sustainable for its partners, consumers and the planet.

Archroma came to life on 1st October 2013 from textile, paper and emulsions businesses acquired from Clariant by SK Capital Partners.
Building on decades of commitment to developing safer eco-friendlier chemistry, Archroma has become in the past 8 years a prominent name for more sustainable colors and performance, collaborating with leading brands such as Primark, G-Star, Patagonia, Esprit and more.

Archroma has introduced innovations, such as the EarthColors® made from non-edible plant waste from the food and herbal industry, Denisol® Pure, an indigo for aniline-free* denim, aniline being a category 2 carcinogen substance, and Smartrepel®, a PFC-free* water repellent solution. The company is also about to launch a new plant-based softener.

The company started to develop holistic solutions designed to bring innovation and performance, whilst reducing the impacts on water, energy and other natural resources. The savings generated by these 70+ system solutions are demonstrated by Archroma's proprietary ONE WAY Impact Calculator, a tool launched in 2012 and continuously upgraded to simulate and optimize the footprint of application processes.

Archroma also recently launched CASUAL X SMART, a sulfur dyeing system for trendy wash-down effects to make clothes that look smart at home and at work. The colors won't fade in the washing cycle, and the application process allows resource savings of up to 33% water, 21% energy and 35% chemical usage compared to a benchmark reactive & pigment garment dyeing.

With ONE WAY, a brand can calculate how much impact their current production and the Archroma Way collection will have on water, energy, chemical, raw material or CO2 footprint.

More and more brands are actively speaking up against the use of PFAS chemicals in products and supply chains. ChemSec’s corporate initiative the PFAS Movement was started in 2020, with the aim of creating a network of companies that would like to see PFAS chemicals regulated more efficiently. As of September 2021, 50 companies have joined the movement.

PFAS, short for per- and polyfluoroalkyl substances, is a chemical family consisting of almost 5,000 industrially produced chemicals. In manufacturing, PFAS are favored for their durability and well-functioning properties. They provide features such as non-stick, water repellency and anti-grease to many types of everyday products, including cosmetics, food packaging, frying pans and clothes, just to name a few.

Lately, more and more reports have been suggesting that PFAS are a serious problem. Human epidemiological studies have found associations between PFAS exposure and a number of health disorders.

One of the biggest challenges connected to PFAS is that, with very few exceptions, they are perfectly legal to use. This means that the brands and retailers who want to stop them from being used as ingredients in their products have very limited ways of communicating this in the global supply chain. As long as there is not a restriction in place, suppliers will continue to use these very effective chemicals in manufacturing. That’s why companies act together with a unified voice, like in the case of ChemSec’s PFAS Movement.

Devan Chemicals has been supporting high performance sport in the UK and Belgium with its ‘cool comfort technology’ Moov&Cool.

Worldwide, hot temperatures are a new reality that brings extra challenges for athletes. Thermoregulation technology is becoming more and more important in order for athletes to perform at their best on the pinnacle of sports.

Working alongside the English Institute for Sport (EIS) and Sally Cowan Ltd, the technology is being applied to garments with the aim of improving the thermal comfort of elite athletes.

Moov&Cool consists of a multi-functional polymer technology that proposes to absorb heat during performance and improve the moisture management properties of the fabric. The treatment has been designed to simultaneously react to sweat build up and heat emission.

In Belgium, Devan has been involved in the Gold2Gold project carried out by Sport Vlaanderen. Gold2Gold is a unique collaboration between sports, government and the industry to prepare Belgian athletes to perform better in hot environments during world-level championships. Thermoregulating technology is increasingly becoming a key aspect of endurance performance for elite athletes. At that top level, small differences in body core temperature can make the difference between being on the podium or sometimes not even finishing the race.

Some of the newly added substances are used in consumer products such as cosmetics, scented articles, rubber and textiles. Others are used as solvents, flame retardants or to manufacture plastics products. Most have been added to the Candidate List because they are hazardous to human health as they are toxic for reproduction, carcinogenic, respiratory sensitisers or endocrine disruptors.

Companies must follow their legal obligations and ensure the safe use of these chemicals. They also have to notify ECHA under the Waste Framework Directive if their products contain substances of very high concern. This notification is submitted to ECHA’s SCIP database and the information will later be published on the Agency’s website.

Background
The Candidate List includes substances of very high concern that may have serious effects on our health or the environment. These substances may be placed on the Authorisation List in the future, which means that companies would need to apply for permission to continue using them. The Candidate List has now 219 entries – some of these cover groups of chemicals so the overall number of impacted chemicals is higher.
 
Under the REACH Regulation, companies may have legal obligations when their substance is included – either on its own, in mixtures or in articles – in the Candidate List. Any supplier of articles containing a Candidate List substance above a concentration of 0.1 % weight by weight has to give sufficient information to their customers and consumers to allow safe use.
 
Importers and producers of articles containing a Candidate List substance have six months from the date of its inclusion in the list (8 July 2021) to notify ECHA. Suppliers of substances on the Candidate List (supplied either on their own or in mixtures) have to provide their customers with a safety data sheet.
 
As of 5 January 2021, suppliers of articles on the EU market containing Candidate List substances in a concentration above 0.1% weight by weight must notify these articles to ECHA’s SCIP database. This duty comes from the Waste Framework Directive.
 
More information on these obligations and related tools are available here.

Archroma announced that the soon-to-be 5’760 color references of its Color Atlas library are made available within its ‘Datacolor TOOLS’ platform, an easy-to-use color quality control application for industries where color accuracy is a critical component of overall product quality.

Datacolor® provides color management solutions that empower customers to make objective, cost-effective and smart color decisions, in applications such as textile & apparel, paint & coatings, plastics, photography, design and many others. The perfect integration of its instruments and software help formulate, measure, control and communicate color, and its state-of-the-art algorithms reproduce color on materials and displays.

The Color Atlas was launched in 2016 to provide fashion designers and stylists with off-the-shelf color inspiration that can be implemented in production with just a few clicks.

Today, the Color Atlas contains 4’320 colors applicable on cotton poplin, almost the double compared to similar tools available to textile and fashion specialists. Technical support is available to designer, manufacturers, as well as brands and retailers, through Archroma’s global offices - for every single color from its selection to its implementation in production. Engineered color standards empowered by NFC technology are also available for all colors and reproducible in production.
Archroma also just launched a similar tool with 1,440 colors on polyester. Both libraries will be available in the ‘Datacolor TOOLS’ platform for color searching.

Each color from the Color Atlas by Archroma® is available for purchase from Archroma as an ‘Engineered Color Standard’, precise digital data and access to global dyeing technical support.

With that, the brands, designers and mills using the ‘Datacolor TOOLS’ platform will have at their disposal the ability to search the 5’760 colors of the Color Atlas by Archroma®, to quickly find colors for their seasonal color palettes.

Archroma, a global leader in specialty chemicals towards sustainable solutions, announced the release of its Sustainability Report for its fiscal year 2020.

Prepared again in accordance with the Global Reporting Initiative (GRI) standards, and building on a strong track record, the report outlines the company’s progress on its priority sustainability topics, such as human health and environmental safety, resource efficiency, sustainable sourcing and product stewardship, as well as diversity & inclusion, and talent management.

For the first time Archroma conducted a survey with its stakeholders to confirm the relevance of the sustainability topics covered in the report. These include biodiversity, occupational and product safety, and fair labor practices, as well as maybe less expected topics such as compliance, economic performance, and culture.

The report can be downloaded at: www.archroma.com/sustainability.

With the pollen season starting, new independent test results by the German external laboratory BMA-Labor have shown Purissimo’s™ effectiveness against pollen, making it an all-in-one solution for reducing allergens.

Devan’s allergen control technology, known as Purissimo™, has been found effective against allergens from pollen. The technology had already been proven to significantly reduce the amount of allergens from house dust mites and pets (cats & dogs).

“Allergens are small protein molecules, which can cause allergic reactions and asthma. All allergy sufferers are different when it comes to their sensitivity to allergens”, says Sofie Depluverez, PhD researcher at Devan. “However, few people are only allergic to a single allergen – and the effects of multiple allergens can add up. The key to reducing and even eliminating symptoms is to reduce your exposure to the allergens themselves.”

Allergy threshold
When people move into a house or bring in a new dog, the number of allergens starts to rise. In the beginning there are little to none, so the allergy threshold causing symptoms is far from being reached. Nobody is suffering any reaction at this stage.

“As time goes by, the various allergens start to build up inside the house, certainly when ventilation is limited”, Depluverez continues. “As the allergen concentration increases (especially in combination with seasonal allergens such as pollen), the allergy threshold may be reached if no allergen reduction measures are in place.”

Purissimo™
Purissimo™ is a natural allergen control technology that significantly reduces allergens from pet dander, dust mites and pollen in textiles throughout the home. The technology is based on encapsulated probiotics, which are naturally occurring microorganisms similar in kind to those you can find in probiotic yogurt, tempeh, kombucha.

Inactive probiotics (spores) are encapsulated and integrated onto the textiles. Friction opens the microcapsules and releases the spores. The spores absorb humidity and self-activate. They are transformed into probiotic bacteria that start to consume the allergens.

“As the probiotics consume the allergens, exposure is gradually reduced to below threshold levels”, Depluverez adds. “Therefore, individuals with respiratory allergies will be exposed to fewer ‘attacks’ and perceive a better well-being.”