From the Sector

Textiles for technical applications often derive their special function via the application of coatings. This way, textiles become, for example wind and water proof or more resistant to abrasion. Usually, petroleum-based substances such as polyacrylates or polyurethanes are used. However, these consume exhaustible resources and the materials can end up in the environment if handled improperly. Therefore, the German Institutes of Textile and Fiber Research Denkendorf (DITF) are researching materials from renewable sources that are recyclable and do not pollute the environment after use. Polymers that can be produced from bacteria are here of particular interest.

These biopolymers have the advantage that they can be produced in anything from small laboratory reactors to large production plants. The most promising biopolymers include polysaccharides, polyamides from amino acids and polyesters such as polylactic acid or polyhydroxyalkanoates (PHAs), all of which are derived from renewable raw materials. PHAs is an umbrella term for a group of biotechnologically produced polyesters. The main difference between these polyesters is the number of carbon atoms in the repeat unit. To date, they have mainly been investigated for medical applications. As PHAs products are increasingly available on the market, coatings made from PHAs may also be increasingly used in technical applications in the future.

The bacteria from which the PHAs are obtained grow with the help of carbohydrates, fats and an increased CO₂ concentration and light with suitable wavelength.

The properties of PHA can be adapted by varying the structure of the repeat unit. This makes polyhydroxyalkanoates a particularly interesting class of compounds for technical textile coatings, which has hardly been investigated to date. Due to their water-repellent properties, which stem from their molecular structure, and their stable structure, polyhydroxyalkanoates have great potential for the production of water-repellent, mechanically resilient textiles, such as those in demand in the automotive sector and for outdoor clothing.

The DITF have already carried out successful research work in this area. Coatings on cotton yarns and fabrics made of cotton, polyamide and polyester showed smooth and quite good adhesion. The PHA types for the coating were both procured on the open market and produced by the research partner Fraunhofer IGB. It was shown that the molten polymer can be applied to cotton yarns by extrusion through a coating nozzle. The molten polymer was successfully coated onto fabric using a doctor blade. The length of the molecular side chain of the PHA plays an important role in the properties of the coated textile. Although PHAs with medium-length side chains are better suited to achieving low stiffness and a good textile handle, their wash resistance is low. PHAs with short side chains are suitable for achieving high wash and abrasion resistance, but the textile handle is somewhat stiffer.

The team is currently investigating how the properties of PHAs can be changed in order to achieve the desired resistance and textile properties in equal measure. There are also plans to formulate aqueous formulations for yarn and textile finishing. This will allow much thinner coatings to be applied to textiles than is possible with molten PHAs.

Other DITF research teams are investigating whether PHAs are also suitable for the production of fibers and nonwovens.

Textiles are a given in civil engineering: they stabilize water protection dams, prevent runoff containing pollutants from landfills, facilitate the revegetation of slopes at risk of erosion, and even make asphalt layers of roads thinner. Until now, textiles made of highly resistant synthetic fibers have been used for this purpose, which have a very long lifetime. For some applications, however, it would not only be sufficient but even desirable for the auxiliary textile to degrade in the soil when it has done its job. Environmentally friendly natural fibers, on the other hand, often decompose too quickly. The German Institutes of Textile and Fiber Research Denkendorf (DITF) are developing a bio-based protective coating that extends their service life.

Depending on humidity and temperature, natural fiber materials can degrade in the soil in a matter of months or even a few days. In order to significantly extend the degradation time and make them suitable for geotextiles, the Denkendorf team researches a protective coating. This coating, based on lignin, is itself biodegradable and does not generate microplastics in the soil. Lignin is indeed biodegradable, but this degradation takes a very long time in nature.

Together with cellulose, Lignin forms the building materials for wood and is the "glue" in wood that holds this composite material together. In paper production, usually only the cellulose is used, so lignin is produced in large quantities as a waste material. So-called kraft lignin remains as a fusible material. Textile production can deal well with thermoplastic materials. All in all, this is a good prerequisite for taking a closer look at lignin as a protective coating for geotextiles.

Lignin is brittle by nature. Therefore, it is necessary to blend the kraft lignin with softer biomaterials. These new biopolymer compounds of brittle kraft lignin and softer biopolymers were applied to yarns and textile surfaces in the research project via adapted coating systems. For this purpose, for example, cotton yarns were coated with lignin at different application rates and evaluated. Biodegradation testing was carried out using soil burial tests both in a climatic chamber with temperature and humidity defined precisely according to the standard and outdoors under real environmental conditions. With positive results: the service life of textiles made of natural fibers can be extended by many factors with a lignin coating: The thicker the protective coating, the longer the protection lasts. In the outdoor tests, the lignin coating was still completely intact even after about 160 days of burial.

Textile materials coated with lignin enable sustainable applications. For example, they have an adjustable and sufficiently long service life for certain geotextile applications. In addition, they are still biodegradable and can replace previously used synthetic materials in some applications, such as revegetation of trench and stream banks.

Thus, lignin-coated textiles have the potential to significantly reduce the carbon footprint: They reduce dependence on petroleum-based products and avoid the formation of microplastics in the soil.

Further research is needed to establish lignin, which was previously a waste material, as a new valuable material in industrial manufacturing processes in the textile industry.

The research work was supported by the Baden-Württemberg Ministry of Food, Rural Areas and Consumer Protection as part of the Baden-Württemberg State Strategy for a Sustainable Bioeconomy.

• AMSilk Partners with Mercedes-Benz to Present a Sustainable Bio-Based Product
• The use of a biotechnology-based and certified-vegan silk-like fabric marks a first in the automotive sector

AMSilk GmbH (“AMSilk”), a leader in supplying innovative high-performance bio-based silk materials, announced a partnership with Mercedes-Benz, for the development of novel, sustainable car door pulls, as part of the car manufacturer’s latest technology programme, the VISION EQXX.

The new concept car, VISION EQXX, features innovative interior materials, revealing a way forward for luxury design that conserves resources and is in balance with nature. Among the organic interior design features are new door pulls made from AMSilk’s Biosteel® fiber. This high-strength, certified-vegan, silk-like fabric is made using AMSilk’s proprietary biotechnology expertise. AMSilk is the world’s first industrial supplier of vegan silk biopolymers which are 100% biodegradable, recyclable, renewable and zero-waste.

Marking a first in the automotive sector, AMSilk’s Biosteel® provides a solution to the car industry whose need to replace petroleum-based content by natural, bio-based materials is increasingly growing.
This new project is the most efficient electric vehicle Mercedes-Benz has ever built and marks a new expression of efficiency and sustainability in interior design. The all-electric VISION EQXX was unveiled in a digital world premiere on the “Mercedes me” media online platform.

Ulrich Scherbel, Chief Executive Officer of AMSilk said: “We are extremely proud to partner with Mercedes-Benz on the technology programme VISION EQXX, providing sustainable interior design solutions from our best-in-class bio-based fibers. Amid a fresh wave of ambitious climate pledges, we are proud to be playing a leading role in providing solutions for a zero-waste future.”