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Co-friendly textiles without PFAS Image: Empa
22.04.2024

Co-friendly textiles without PFAS

Rain jackets, swimming trunks or upholstery fabrics: Textiles with water-repellent properties require chemical impregnation. Although fluorine-containing PFAS chemicals are effective, they are also harmful to human health and accumulate in the environment. Empa researchers are now developing a process with alternative substances that can be used to produce environmentally friendly water-repellent textile fibers. Initial analyses show: The "good" fibers repel water more effectively and dry faster than those of conventional products.

Rain jackets, swimming trunks or upholstery fabrics: Textiles with water-repellent properties require chemical impregnation. Although fluorine-containing PFAS chemicals are effective, they are also harmful to human health and accumulate in the environment. Empa researchers are now developing a process with alternative substances that can be used to produce environmentally friendly water-repellent textile fibers. Initial analyses show: The "good" fibers repel water more effectively and dry faster than those of conventional products.

If swimming trunks are to retain their shape after swimming and to dry quickly, they must combine two properties: They must be elastic and must not soak up water. Such a water-repellent effect can be achieved by treating the textiles with chemicals that give the elastic garment so-called hydrophobic properties. In the 1970s, new synthetic fluorine compounds began to be used for this purpose – compounds that seemed to offer countless application possibilities, but later turned out to be highly problematic. This is because these fluorocarbon compounds, PFAS for short, accumulate in the environment and are harmful to our health (see box). Empa researchers are therefore working with Swiss textile companies to develop alternative environmentally friendly processes that can be used to give fibers a water-repellent finish. Dirk Hegemann from Empa's Advanced Fibers laboratory in St. Gallen explains the Innosuisse-funded project: "We use so-called highly cross-linked siloxanes, which create silicone-like layers and – unlike fluorine-containing PFAS – are harmless."

Empa's plasma coating facilities range from handy table-top models to room-filling devices. For the coating of textile fibers, the siloxanes are atomized and activated in a reactive gas. They thereby retain their functional properties and enclose the textile fibers in a water-repellent coating that is only 30 nanometers thin. Fibers coated this way can then be processed into water-repellent textiles of all kinds, for example garments or technical textiles such as upholstery fabrics.

The advantage over conventional wet-chemical processes: Even with complex structured textiles, the seamless distribution of the hydrophobic substances is guaranteed right into all turns of the intertwined fibers. This is crucial, because even a tiny wettable spot would be enough for water to penetrate into the depths of a pair of swimming trunks, preventing the garment from drying quickly. "We have even succeeded in permanently impregnating more demanding, elastic fibers with the new process, which was previously not possible," says Hegemann.

Great interest from industry
In initial laboratory analyses, textiles made from the new fibers with an environmentally friendly coating are already performing slightly better than conventional PFAS-coated fabrics. They absorb less water and dry faster. However, the miraculous properties of the fluorine-free coating only really come into their own after the textiles have been washed several times: While the performance of conventional PFAS coatings in stretchy textiles declines considerably after repeated wash cycles, the fluorine-free fibers retain their water-repellent properties.

Hegemann and his team are now working on scaling up the fluorine-free laboratory process into efficient and economically viable industrial processes. "The industry is very interested in finding sustainable alternatives to PFAS," says Hegemann. The Swiss textile companies Lothos KLG, beag Bäumlin & Ernst AG and AG Cilander are already on board when it comes to developing environmentally friendly fluorine-free textiles. "This is a successful collaboration that combines materials, fiber technology and plasma coating and leads to an innovative, sustainable and effective solution," says Dominik Pregger from Lothos. And Bernd Schäfer, CEO of beag, adds: "The technology is environmentally friendly and also has interesting economic potential."

More information:
Empa PFAS Plasma Fibers
Source:

Dr. Andrea Six, EMPA

Photo: Sibi Suku, unsplash
29.01.2024

Naturalistic silk spun from artificial spider gland

Researchers led by Keiji Numata at the RIKEN Center for Sustainable Resource Science in Japan, along with colleagues from the RIKEN Pioneering Research Cluster, have succeeded in creating a device that spins artificial spider silk that closely matches what spiders naturally produce. The artificial silk gland was able to re-create the complex molecular structure of silk by mimicking the various chemical and physical changes that naturally occur in a spider’s silk gland. This eco-friendly innovation is a big step towards sustainability and could impact several industries. This study was published January 15 in the scientific journal Nature Communications.

Researchers led by Keiji Numata at the RIKEN Center for Sustainable Resource Science in Japan, along with colleagues from the RIKEN Pioneering Research Cluster, have succeeded in creating a device that spins artificial spider silk that closely matches what spiders naturally produce. The artificial silk gland was able to re-create the complex molecular structure of silk by mimicking the various chemical and physical changes that naturally occur in a spider’s silk gland. This eco-friendly innovation is a big step towards sustainability and could impact several industries. This study was published January 15 in the scientific journal Nature Communications.

Famous for its strength, flexibility, and light weight, spider silk has a tensile strength that is comparable to steel of the same diameter, and a strength to weight ratio that is unparalleled. Added to that, it’s biocompatible, meaning that it can be used in medical applications, as well as biodegradable. So why isn’t everything made from spider silk? Large-scale harvesting of silk from spiders has proven impractical for several reasons, leaving it up to scientists to develop a way to produce it in the laboratory.

Spider silk is a biopolymer fiber made from large proteins with highly repetitive sequences, called spidroins. Within the silk fibers are molecular substructures called beta sheets, which must be aligned properly for the silk fibers to have their unique mechanical properties. Re-creating this complex molecular architecture has confounded scientists for years. Rather than trying to devise the process from scratch, RIKEN scientists took a biomimicry approach. As Numata explains, “in this study, we attempted to mimic natural spider silk production using microfluidics, which involves the flow and manipulation of small amounts of fluids through narrow channels. Indeed, one could say that that the spider’s silk gland functions as a sort of natural microfluidic device.”

The device developed by the researchers looks like a small rectangular box with tiny channels grooved into it. Precursor spidroin solution is placed at one end and then pulled towards the other end by means of negative pressure. As the spidroins flow through the microfluidic channels, they are exposed to precise changes in the chemical and physical environment, which are made possible by the design of the microfluidic system. Under the correct conditions, the proteins self-assembled into silk fibers with their characteristic complex structure.

The researchers experimented to find these correct conditions, and eventually were able to optimize the interactions among the different regions of the microfluidic system. Among other things, they discovered that using force to push the proteins through did not work; only when they used negative pressure to pull the spidroin solution could continuous silk fibers with the correct telltale alignment of beta sheets be assembled.

“It was surprising how robust the microfluidic system was, once the different conditions were established and optimized,” says Senior Scientist Ali Malay, one of the paper’s co-authors. “Fiber assembly was spontaneous, extremely rapid, and highly reproducible. Importantly, the fibers exhibited the distinct hierarchical structure that is found in natural silk fiber.”

The ability to artificially produce silk fibers using this method could provide numerous benefits. Not only could it help reduce the negative impact that current textile manufacturing has on the environment, but the biodegradable and biocompatible nature of spider silk makes it ideal for biomedical applications, such as sutures and artificial ligaments.

“Ideally, we want to have a real-world impact,” says Numata. “For this to occur, we will need to scale-up our fiber-production methodology and make it a continuous process. We will also evaluate the quality of our artificial spider silk using several metrics and make further improvements from there.”

Source:

RIKEN Center for Sustainable Resource Science, Japan

New conductive, cotton-based fiber developed for smart textiles Photo: Dean Hare, WSU Photo Services
29.12.2023

New conductive, cotton-based fiber developed for smart textiles

A single strand of fiber developed at Washington State University has the flexibility of cotton and the electric conductivity of a polymer, called polyaniline.

The newly developed material showed good potential for wearable e-textiles. The WSU researchers tested the fibers with a system that powered an LED light and another that sensed ammonia gas, detailing their findings in the journal Carbohydrate Polymers.

“We have one fiber in two sections: one section is the conventional cotton: flexible and strong enough for everyday use, and the other side is the conductive material,” said Hang Liu, WSU textile researcher and the study’s corresponding author. “The cotton can support the conductive material which can provide the needed function.”

A single strand of fiber developed at Washington State University has the flexibility of cotton and the electric conductivity of a polymer, called polyaniline.

The newly developed material showed good potential for wearable e-textiles. The WSU researchers tested the fibers with a system that powered an LED light and another that sensed ammonia gas, detailing their findings in the journal Carbohydrate Polymers.

“We have one fiber in two sections: one section is the conventional cotton: flexible and strong enough for everyday use, and the other side is the conductive material,” said Hang Liu, WSU textile researcher and the study’s corresponding author. “The cotton can support the conductive material which can provide the needed function.”

While more development is needed, the idea is to integrate fibers like these into apparel as sensor patches with flexible circuits. These patches could be part of uniforms for firefighters, soldiers or workers who handle chemicals to detect for hazardous exposures. Other applications include health monitoring or exercise shirts that can do more than current fitness monitors.

“We have some smart wearables, like smart watches, that can track your movement and human vital signs, but we hope that in the future your everyday clothing can do these functions as well,” said Liu. “Fashion is not just color and style, as a lot of people think about it: fashion is science.”

In this study, the WSU team worked to overcome the challenges of mixing the conductive polymer with cotton cellulose. Polymers are substances with very large molecules that have repeating patterns. In this case, the researchers used polyaniline, also known as PANI, a synthetic polymer with conductive properties already used in applications such as printed circuit board manufacturing.

While intrinsically conductive, polyaniline is brittle and by itself, cannot be made into a fiber for textiles. To solve this, the WSU researchers dissolved cotton cellulose from recycled t-shirts into a solution and the conductive polymer into another separate solution. These two solutions were then merged together side-by-side, and the material was extruded to make one fiber.

The result showed good interfacial bonding, meaning the molecules from the different materials would stay together through stretching and bending.

Achieving the right mixture at the interface of cotton cellulose and polyaniline was a delicate balance, Liu said.

“We wanted these two solutions to work so that when the cotton and the conductive polymer contact each other they mix to a certain degree to kind of glue together, but we didn’t want them to mix too much, otherwise the conductivity would be reduced,” she said.

Additional WSU authors on this study included first author Wangcheng Liu as well as Zihui Zhao, Dan Liang, Wei-Hong Zhong and Jinwen Zhang. This research received support from the National Science Foundation and the Walmart Foundation Project.

Source:

Sara Zaske, WSU News & Media Relations

06.11.2023

Shape-shifting fiber can produce morphing fabrics

The low-cost FibeRobo, which is compatible with existing textile manufacturing techniques, could be used in adaptive performance wear or compression garments.

Researchers from MIT and Northeastern University developed a liquid crystal elastomer fiber that can change its shape in response to thermal stimuli. The fiber, which is fully compatible with existing textile manufacturing machinery, could be used to make morphing textiles, like a jacket that becomes more insulating to keep the wearer warm when temperatures drop.

The low-cost FibeRobo, which is compatible with existing textile manufacturing techniques, could be used in adaptive performance wear or compression garments.

Researchers from MIT and Northeastern University developed a liquid crystal elastomer fiber that can change its shape in response to thermal stimuli. The fiber, which is fully compatible with existing textile manufacturing machinery, could be used to make morphing textiles, like a jacket that becomes more insulating to keep the wearer warm when temperatures drop.

Instead of needing a coat for each season, imagine having a jacket that would dynamically change shape so it becomes more insulating to keep you warm as the temperature drops.
A programmable, actuating fiber developed by an interdisciplinary team of MIT researchers could someday make this vision a reality. Known as FibeRobo, the fiber contracts in response to an increase in temperature, then self-reverses when the temperature decreases, without any embedded sensors or other hard components.

The low-cost fiber is fully compatible with textile manufacturing techniques, including weaving looms, embroidery, and industrial knitting machines, and can be produced continuously by the kilometer. This could enable designers to easily incorporate actuation and sensing capabilities into a wide range of fabrics for myriad applications.

The fibers can also be combined with conductive thread, which acts as a heating element when electric current runs through it. In this way, the fibers actuate using electricity, which offers a user digital control over a textile’s form. For instance, a fabric could change shape based on any piece of digital information, such as readings from a heart rate sensor.

“We use textiles for everything. We make planes with fiber-reinforced composites, we cover the International Space Station with a radiation-shielding fabric, we use them for personal expression and performance wear. So much of our environment is adaptive and responsive, but the one thing that needs to be the most adaptive and responsive — textiles — is completely inert,” says Jack Forman, a graduate student in the Tangible Media Group of the MIT Media Lab, with a secondary affiliation at the Center for Bits and Atoms, and lead author of a paper on the actuating fiber.

He is joined on the paper by 11 other researchers at MIT and Northeastern University, including his advisors, Professor Neil Gershenfeld, who leads the Center for Bits and Atoms, and Hiroshi Ishii, the Jerome B. Wiesner Professor of Media Arts and Sciences and director of the Tangible Media Group. The research will be presented at the ACM Symposium on User Interface Software and Technology.

Morphing materials
The MIT researchers wanted a fiber that could actuate silently and change its shape dramatically, while being compatible with common textile manufacturing procedures. To achieve this, they used a material known as liquid crystal elastomer (LCE).

A liquid crystal is a series of molecules that can flow like liquid, but when they’re allowed to settle, they stack into a periodic crystal arrangement. The researchers incorporate these crystal structures into an elastomer network, which is stretchy like a rubber band.

As the LCE material heats up, the crystal molecules fall out of alignment and pull the elastomer network together, causing the fiber to contract. When the heat is removed, the molecules return to their original alignment, and the material to its original length, Forman explains.

By carefully mixing chemicals to synthesize the LCE, the researchers can control the final properties of the fiber, such as its thickness or the temperature at which it actuates.

They perfected a preparation technique that creates LCE fiber which can actuate at skin-safe temperatures, making it suitable for wearable fabrics.

“There are a lot of knobs we can turn. It was a lot of work to come up with this process from scratch, but ultimately it gives us a lot of freedom for the resulting fiber,” he adds.
However, the researchers discovered that making fiber from LCE resin is a finicky process. Existing techniques often result in a fused mass that is impossible to unspool.

Researchers are also exploring other ways to make functional fibers, such as by incorporating hundreds of microscale digital chips into a polymer, utilizing an activated fluidic system, or including piezoelectric material that can convert sound vibrations into electrical signals.

Fiber fabrication
Forman built a machine using 3D-printed and laser-cut parts and basic electronics to overcome the fabrication challenges. He initially built the machine as part of the graduate-level course MAS.865 (Rapid-Prototyping of Rapid-Prototyping Machines: How to Make Something that Makes [almost] Anything).

To begin, the thick and viscous LCE resin is heated, and then slowly squeezed through a nozzle like that of a glue gun. As the resin comes out, it is cured carefully using UV lights that shine on both sides of the slowly extruding fiber.

If the light is too dim, the material will separate and drip out of the machine, but if it is too bright, clumps can form, which yields bumpy fibers.

Then the fiber is dipped in oil to give it a slippery coating and cured again, this time with UV lights turned up to full blast, creating a strong and smooth fiber. Finally, it is collected into a top spool and dipped in powder so it will slide easily into machines for textile manufacturing.
From chemical synthesis to finished spool, the process takes about a day and produces approximately a kilometer of ready-to-use fiber.

“At the end of the day, you don’t want a diva fiber. You want a fiber that, when you are working with it, falls into the ensemble of materials — one that you can work with just like any other fiber material, but then it has a lot of exciting new capabilities,” Forman says.

Creating such a fiber took a great deal of trial and error, as well as the collaboration of researchers with expertise in many disciplines, from chemistry to mechanical engineering to electronics to design.

The resulting fiber, called FibeRobo, can contract up to 40 percent without bending, actuate at skin-safe temperatures (the skin-safe version of the fiber contracts up to about 25 percent), and be produced with a low-cost setup for 20 cents per meter, which is about 60 times cheaper than commercially available shape-changing fibers.

The fiber can be incorporated into industrial sewing and knitting machines, as well as nonindustrial processes like hand looms or manual crocheting, without the need for any process modifications.
The MIT researchers used FibeRobo to demonstrate several applications, including an adaptive sports bra made by embroidery that tightens when the user begins exercising.

They also used an industrial knitting machine to create a compression jacket for Forman’s dog, whose name is Professor. The jacket would actuate and “hug” the dog based on a Bluetooth signal from Forman’s smartphone. Compression jackets are commonly used to alleviate the separation anxiety a dog can feel while its owner is away.

In the future, the researchers want to adjust the fiber’s chemical components so it can be recyclable or biodegradable. They also want to streamline the polymer synthesis process so users without wet lab expertise could make it on their own.

Forman is excited to see the FibeRobo applications other research groups identify as they build on these early results. In the long run, he hopes FibeRobo can become something a maker could buy in a craft store, just like a ball of yarn, and use to easily produce morphing fabrics.

“LCE fibers come to life when integrated into functional textiles. It is particularly fascinating to observe how the authors have explored creative textile designs using a variety of weaving and knitting patterns,” says Lining Yao, the Cooper-Siegel Associate Professor of Human Computer Interaction at Carnegie Mellon University, who was not involved with this work.

This research was supported, in part, by the William Asbjornsen Albert Memorial Fellowship, the Dr. Martin Luther King Jr. Visiting Professor Program, Toppan Printing Co., Honda Research, Chinese Scholarship Council, and Shima Seiki. The team included Ozgun Kilic Afsar, Sarah Nicita, Rosalie (Hsin-Ju) Lin, Liu Yang, Akshay Kothakonda, Zachary Gordon, and Cedric Honnet at MIT; and Megan Hofmann and Kristen Dorsey at Northeastern University.

Source:

MIT and Northeastern University

Researchers made shape-changing fibers by encapsulating a balloon-like tube in a braided textile sheath. (c) : Muh Amdadul Hoque. Researchers made shape-changing fibers by encapsulating a balloon-like tube in a braided textile sheath.
27.09.2023

Artificial Muscle Fibers Could Serve as Cell Scaffolds

In two new studies, North Carolina State University researchers designed and tested a series of textile fibers that can change shape and generate force like a muscle. In the first study, the researchers focused on the materials’ influence on the artificial muscles’ strength and contraction length. The findings could help researchers tailor the fibers for different applications.

In the second, proof-of-concept study, the researchers tested their fibers as scaffolds for live cells. Their findings suggest the fibers – known as “fiber robots” – could potentially be used to develop 3D models of living, moving systems in the human body.

In two new studies, North Carolina State University researchers designed and tested a series of textile fibers that can change shape and generate force like a muscle. In the first study, the researchers focused on the materials’ influence on the artificial muscles’ strength and contraction length. The findings could help researchers tailor the fibers for different applications.

In the second, proof-of-concept study, the researchers tested their fibers as scaffolds for live cells. Their findings suggest the fibers – known as “fiber robots” – could potentially be used to develop 3D models of living, moving systems in the human body.

“We found that our fiber robot is a very suitable scaffold for the cells, and we can alter the frequency and contraction ratio to create a more suitable environment for cells,” said Muh Amdadul Hoque, graduate student in textile engineering, chemistry and science at NC State. “These were proof-of concept studies; ultimately, our goal is to see if we can study these fibers as a scaffold for stem cells, or use them to develop artificial organs in future studies.”
 
Researchers made the shape-changing fibers by encapsulating a balloon-like tube, made of a material similar to rubber, in a braided textile sheath. Inflating the interior balloon with an air pump makes the braided sheath expand, causing it to shorten.

The researchers measured the force and contraction rates of fibers made from different materials in order to understand the relationship between material and performance. They found that stronger, larger diameter yarns generated a stronger contraction force. In addition, they found that the material used to make the balloon impacted the magnitude of the contraction and generated force.
 
“We found that we could tailor the material properties to the required performance of the device,” said Xiaomeng Fang, assistant professor of textile engineering, chemistry and science at NC State. “We also found that we can make this device small enough so we can potentially use it in fabric formation and other textile applications, including in wearables and assistive devices.”
 
In a follow-up study, researchers evaluated whether they could use the shape-changing fibers as a scaffold for fibroblasts, a cell type found in connective tissues that help support other tissues or organs.

“The idea with stretching is to mimic the dynamic nature of how your body moves,” said Jessica Gluck, assistant professor of textile engineering, chemistry and science at NC State, and a study co-author.

They studied the cells’ response to the motion of the shape-changing fibers, and to different materials used in the fibers’ construction. They found the cells were able to cover and even penetrate the fiber robot’s braiding sheath. However, they saw decreases in the cells’ metabolic activity when the fiber robot’s contraction extended beyond a certain level, compared to a device made of the same material that they kept stationary.

The researchers are interested in building on the findings to see if they could use the fibers as a 3D biological model, and to investigate whether movement would impact cell differentiation. They said their model would be an advance over other existing experimental models that have been developed to show cellular response to stretching and other motion, since they can only move in two dimensions.
 
“Typically, if you want to add stretch or strain on cells, you would put them onto a plastic dish, and stretch them in one or two directions,” Gluck said. “In this study, we were able to show that in this 3D dynamic culture, the cells can survive for up to 72 hours.

“This is particularly useful for stem cells,” Gluck added. “What we could do in the future is look at what could happen at the cellular level with mechanical stress on the cells. You could look at muscle cells and see how they’re developing, or see how the mechanical action would help differentiate the cells.”

The study, “Effect of Material Properties on Fiber-Shaped Pneumatic Actuators Performance” was published in Actuators on March 18. Emily Petersen was a co-author. The study was funded by start-up funding awarded to Fang from the Department of Textile Engineering, Chemistry and Science at NC State.

The study, “Development of a Pneumatic-Driven Fiber-Shaped Robot Scaffold for Use as a Complex 3D Dynamic Culture System” was published online in Biomimetics on April 21. In addition to Gluck, Hoque and Fang, co-authors included Nasif Mahmood, Kiran M. Ali, Eelya Sefat, Yihan Huang, Emily Petersen and Shane Harrington. The study was funded by the NC State Wilson College of Textiles, the Department of Textile Engineering, Chemistry and Science and the Wilson College of Textiles Research Opportunity Seed Fund Program.

Source:

North Carolina State University, Laura Oleniacz. Übersetzung Textination

(c) Institut auf dem Rosenberg
01.09.2023

‘Blue Nomad’ - Floating Into the Future with Flax Fibres

As humanity grapples with climate change and rising sea levels, our collective imagination is more critical than ever. In light of this, bcomp presents the phenomenal work initiated by the students from Institut auf dem Rosenberg in St. Gallen and SAGA Space Architects. They’ve developed an extraordinary solution to address the environmental challenges we face: the ‘Blue Nomad’ floating habitat.

‘Blue Nomad’ is a solar-powered home designed for comfortable living on the ocean. It symbolises a future where we must explore and adapt to the changing earth’s environment. Drawing inspiration from the first Polynesian nomadic settlements and equipped with solar panels for self-sustainability, the habitat promotes a vision of living and traveling on water.

As humanity grapples with climate change and rising sea levels, our collective imagination is more critical than ever. In light of this, bcomp presents the phenomenal work initiated by the students from Institut auf dem Rosenberg in St. Gallen and SAGA Space Architects. They’ve developed an extraordinary solution to address the environmental challenges we face: the ‘Blue Nomad’ floating habitat.

‘Blue Nomad’ is a solar-powered home designed for comfortable living on the ocean. It symbolises a future where we must explore and adapt to the changing earth’s environment. Drawing inspiration from the first Polynesian nomadic settlements and equipped with solar panels for self-sustainability, the habitat promotes a vision of living and traveling on water.

bcomp is particularly excited about the project as the scaled model that was exhibited in London and Monaco prominently features their very own ampliTex™ flax fibres. A plan of building an actual prototype of the floating home is being developed by Institut auf dem Rosenberg and SAGA. It could be made from a structurally optimised weave of flax fibre, showcasing the future of organic and regenerative high-performance materials replacing conventional synthetic and fossil-based technologies. As a company, bcomp is proud to provide sustainable material solutions, and seeing their flax fibres used in such an innovative and meaningful project is both humbling and inspiring.

‘Blue Nomad’ isn’t just a solitary habitat, but a concept for a new kind of community. Imagined as modular blocks, these habitats can form larger communities and oceanic farms, allowing inhabitants to share resources while moving from one oceanic farm to the next. It’s a striking vision of a future where the lines between land and water blur, and sustainability and community building lie at the heart of human settlements.

But this vision is not just theoretical. Plans are being made for a maiden voyage of ‘Blue Nomad’ across Europe, powered purely by solar energy, promoting ocean sustainability, climatology, and future nomadism.

This project serves as a powerful reminder of what can be achieved when education, innovative design, and sustainability are united. The ‘Blue Nomad’ represents the future we envision – a future where sustainable materials play a crucial role in safeguarding our planet.

The ‘Blue Nomad’ project was exhibited at the London Design Biennale 2023 as well as the Monaco Energy Boat Challenge where it was captivating visitors and garnering significant attention from the public.    

Source:

Bcomp

Photo: Claude Huniade
11.07.2023

Ionofibres a new track for smart and functional textiles

Electronically conductive fibres are already in use in smart textiles, but in a recently published research article, ionically conductive fibres have proven to be of increasing interest. The so-called ionofibres achieve higher flexibility and durability and match the type of conduction our body uses. In the future, they may be used for such items as textile batteries, textile displays, and textile muscles.

The research project is being carried out by doctoral student Claude Huniade at the University of Borås and is a track within a larger project, Weafing, the goal of which is to develop novel, unprecedented garments for haptic stimulation comprising flexible and wearable textile actuators and sensors, including control electronics, as a new type of textile-based large area electronics.

WEAFING stands for Wearable Electroactive Fabrics Integrated in Garments. It started 1 January 2019 and ended 30 June 2023.

Electronically conductive fibres are already in use in smart textiles, but in a recently published research article, ionically conductive fibres have proven to be of increasing interest. The so-called ionofibres achieve higher flexibility and durability and match the type of conduction our body uses. In the future, they may be used for such items as textile batteries, textile displays, and textile muscles.

The research project is being carried out by doctoral student Claude Huniade at the University of Borås and is a track within a larger project, Weafing, the goal of which is to develop novel, unprecedented garments for haptic stimulation comprising flexible and wearable textile actuators and sensors, including control electronics, as a new type of textile-based large area electronics.

WEAFING stands for Wearable Electroactive Fabrics Integrated in Garments. It started 1 January 2019 and ended 30 June 2023.

These wearables are based on a new kind of textile muscles which yarns are coated with electromechanically active polymers and contract when a low voltage is applied. Textile muscles offer a completely novel and very different quality of haptic sensation, accessing also receptors of our tactile sensory system that do not react on vibration, but on soft pressure or stroke.

Furthermore, being textile materials, they offer a new way of designing and fabricating wearable haptics and can be seamlessly integrated into fabrics and garments. For these novel form of textile muscles, a huge range of possible applications in haptics is foreseen: for ergonomics, movement coaching in sports, or wellness, for enhancement of virtual or augmented reality applications in gaming or for training purposes, for inclusion of visually handicapped people by providing them information about their environment, for stress reduction or social communication, adaptive furniture, automotive industry and many more.

In Claude Huniade’s project, the goal is to produce conductive yarns without conductive metals.

"My research is about producing electrically conductive textile fibres, and ultimately yarns, by coating non-metals sustainably on commercial yarns. The biggest challenge is in the balance between keeping the textile properties and adding the conductive feature," said Claude Huniade.

Currenty, the uniqueness of his research leans towards the strategies employed when coating. These strategies expand to the processes and the materials used.

Uses ionic liquid
One of the tracks he investigates is about a new kind of material as textile coating, ionic liquids in combination with commercial textile fibres. Just like salt water, they conduct electricity but without water. Ionic liquid is a more stable electrolyte than salt water as nothing evaporates.

"The processable aspect is an important requirement since textile manufacturing can be harsh on textile fibres, especially when upscaling their use. The fibres can also be manufactured into woven or knitted without damaging them mechanically while retaining their conductivity. Surprisingly, they were even smoother to process into fabrics than the commercial yarns they are made from," explained Claude Huniade.

Ionofibres could be used as sensors since ionic liquids are sensitive to their environment. For example, humidity change can be sensed by the ionofibers, but also any stretch or pressure they are subjected to.

"Ionofibres could truly shine when they are combined with other materials or devices that require electrolytes. Ionofibres enable certain phenomena currently limited to happen in liquids to be feasible in air in a lightweight fashion. The applications are multiple and unique, for example for textile batteries, textile displays or textile muscles," said Claude Huniade.

Needs further research
Yet more research is needed to combine the ionofibres with other functional fibres and to produce the unique textile devices.

How do they stand out compared to common electronically conductive fibres?

"In comparison to electronically conductive fibres, ionofibers are different in how they conduct electricity. They are less conductive, but they bring other properties that electronically conductive fibers often lack. Ionofibres achieve higher flexibility and durability and match the type of conduction that our body uses. They actually match better than electronically conductive fibres with how electricity is present in nature," he concluded.

Source:

University of Borås

Thread-like pumps can be woven into clothes (c) LMTS EPFL
27.06.2023

Thread-like pumps can be woven into clothes

Ecole Polytechnique Fédérale de Lausanne (EPFL) researchers have developed fiber-like pumps that allow high-pressure fluidic circuits to be woven into textiles without an external pump. Soft supportive exoskeletons, thermoregulatory clothing, and immersive haptics can therefore be powered from pumps sewn into the fabric of the devices themselves.

Many fluid-based wearable assistive technologies today require a large and noisy pump that is impractical – if not impossible – to integrate into clothing. This leads to a contradiction: wearable devices are routinely tethered to unearable pumps. Now, researchers at the Soft Transducers Laboratory (LMTS) in the School of Engineering have developed an elegantly simple solution to this dilemma.

Ecole Polytechnique Fédérale de Lausanne (EPFL) researchers have developed fiber-like pumps that allow high-pressure fluidic circuits to be woven into textiles without an external pump. Soft supportive exoskeletons, thermoregulatory clothing, and immersive haptics can therefore be powered from pumps sewn into the fabric of the devices themselves.

Many fluid-based wearable assistive technologies today require a large and noisy pump that is impractical – if not impossible – to integrate into clothing. This leads to a contradiction: wearable devices are routinely tethered to unearable pumps. Now, researchers at the Soft Transducers Laboratory (LMTS) in the School of Engineering have developed an elegantly simple solution to this dilemma.

“We present the world’s first pump in the form of a fiber; in essence, tubing that generates its own pressure and flow rate,” says LMTS head Herbert Shea. “Now, we can sew our fiber pumps directly into textiles and clothing, leaving conventional pumps behind.” The research has been published in the journal Science.

Lightweight, powerful…and washable
Shea’s lab has a history of forward-thinking fluidics. In 2019, they produced the world’s first stretchable pump.

“This work builds on our previous generation of soft pump,” says Michael Smith, an LMTS post-doctoral researcher and lead author of the study. “The fiber format allows us to make lighter, more powerful pumps that are inherently more compat-ible with wearable technology.”

The LMTS fiber pumps use a principle called charge injection electrohydrodynamics (EHD) to generate a fluid flow without any moving parts. Two helical electrodes embedded in the pump wall ionize and accelerate molecules of a special non-conductive liquid. The ion movement and electrode shape generate a net forward fluid flow, resulting in silent, vibration-free operation, and requiring just a palm-sized power supply and battery.

To achieve the pump’s unique structure, the researchers developed a novel fabrication technique that involves twisting copper wires and polyurethane threads together around a steel rod, and then fusing them with heat. After the rod is removed, the 2 mm fibers can be integrated into textiles using standard weaving and sewing techniques.

The pump’s simple design has a number of advantages. The materials required are cheap and readily available, and the manufacturing process can be easily scaled up. Because the amount of pressure generated by the pump is directly linked to its length, the tubes can be cut to match the application, optimizing performance while minimizing weight. The robust design can also be washed with conventional detergents.

From exoskeletons to virtual reality
The authors have already demonstrated how these fiber pumps can be used in new and exciting wearable technologies. For example, they can circulate hot and cold fluid through garments for those working in extreme temperature environments or in a therapeutic setting to help manage inflammation; and even for those looking to optimize athletic performance.

“These applications require long lengths of tubing anyway, and in our case, the tubing is the pump. This means we can make very simple and lightweight fluidic circuits that are convenient and comfortable to wear,” Smith says.

The study also describes artificial muscles made from fabric and embedded fiber pumps, which could be used to power soft exoskeletons to help patients move and walk.

The pump could even bring a new dimension to the world of virtual reality by simulating the sensation of temperature. In this case, users wear a glove with pumps filled with hot or cold liquid, allowing them to feel temperature changes in response to contact with a virtual object.

Pumped up for the future
The researchers are already looking to improve the performance of their device. “The pumps already perform well, and we’re confident that with more work, we can continue to make improvements in areas like efficiency and lifetime,” says Smith. Work has already started on scaling up the production of the fiber pumps, and the LMTS also has plans to embed them into more complex wearable devices.

“We believe that this innovation is a game-changer for wearable technology,” Shea says.

More information:
EPFL Fibers exoskeleton wearables
Source:

Celia Luterbacher, School of Engineering | STI

A cotton knit fabric dyed blue and washed 10 times to simulate worn garments is enzymatically degraded to a slurry of fine fibers and "blue glucose" syrup that are separated by filtration - both of these separated fractions have potential recycle value. A cotton knit fabric dyed blue and washed 10 times to simulate worn garments is enzymatically degraded to a slurry of fine fibers and "blue glucose" syrup that are separated by filtration - both of these separated fractions have potential recycle value. Credit: Sonja Salmon.
11.04.2023

Researchers Separate Cotton from Polyester in Blended Fabric

In a new study, North Carolina State University researchers found they could separate blended cotton and polyester fabric using enzymes – nature’s tools for speeding chemical reactions. Ultimately, they hope their findings will lead to a more efficient way to recycle the fabric’s component materials, thereby reducing textile waste. However, they also found the process need more steps if the blended fabric was dyed or treated with chemicals that increase wrinkle resistance.

In a new study, North Carolina State University researchers found they could separate blended cotton and polyester fabric using enzymes – nature’s tools for speeding chemical reactions. Ultimately, they hope their findings will lead to a more efficient way to recycle the fabric’s component materials, thereby reducing textile waste. However, they also found the process need more steps if the blended fabric was dyed or treated with chemicals that increase wrinkle resistance.

“We can separate all of the cotton out of a cotton-polyester blend, meaning now we have clean polyester that can be recycled,” said the study’s corresponding author Sonja Salmon, associate professor of textile engineering, chemistry and science at NC State. “In a landfill, the polyester is not going to degrade, and the cotton might take several months or more to break down. Using our method, we can separate the cotton from polyester in less than 48 hours.”
 
According to the U.S. Environmental Protection Agency, consumers throw approximately 11 million tons of textile waste into U.S. landfills each year. Researchers wanted to develop a method of separating the cotton from the polyester so each component material could be recycled.

In the study, researchers used a “cocktail” of enzymes in a mildly acidic solution to chop up cellulose in cotton. Cellulose is the material that gives structure to plants’ cell walls. The idea is to chop up the cellulose so it will “fall out” out of the blended woven structure, leaving some tiny cotton fiber fragments remaining, along with glucose. Glucose is the biodegradable byproduct of degraded cellulose. Then, their process involves washing away the glucose and filtering out the cotton fiber fragments, leaving clean polyester.
 
“This is a mild process – the treatment is slightly acidic, like using vinegar,” Salmon said. “We also ran it at 50 degrees Celsius, which is like the temperature of a hot washing machine.
“It’s quite promising that we can separate the polyester to a clean level,” Salmon added. “We still have some more work to do to characterize the polyester’s properties, but we think they will be very good because the conditions are so mild. We’re just adding enzymes that ignore the polyester.”

They compared degradation of 100% cotton fabric to degradation of cotton and polyester blends, and also tested fabric that was dyed with red and blue reactive dyes and treated with durable press chemicals. In order to break down the dyed materials, the researchers had to increase the amount of time and enzymes used. For fabrics treated with durable press chemicals, they had to use a chemical pre-treatment before adding the enzymes.

“The dye that you choose has a big impact on the potential degradation of the fabric,” said the study’s lead author Jeannie Egan, a graduate student at NC State. “Also, we found the biggest obstacle so far is the wrinkle-resistant finish. The chemistry behind that creates a significant block for the enzyme to access the cellulose. Without pre-treating it, we achieved less than 10% degradation, but after, with two enzyme doses, we were able to fully degrade it, which was a really exciting result.”

Researchers said the polyester could be recycled, while the slurry of cotton fragments could be valuable as an additive for paper or useful addition to composite materials. They’re also investigating whether the glucose could be used to make biofuels.

“The slurry is made of residual cotton fragments that resist a very powerful enzymatic degradation,” Salmon said. “It has potential value as a strengthening agent. For the glucose syrup, we’re collaborating on a project to see if we can feed it into an anaerobic digester to make biofuel. We’d be taking waste and turning it into bioenergy, which would be much better than throwing it into a landfill.”

The study, “Enzymatic textile fiber separation for sustainable waste processing,” was published in Resources, Environment and Sustainability. Co-authors included Siyan Wang, Jialong Shen, Oliver Baars and Geoffrey Moxley. Funding was provided by the Environmental Research and Education Foundation, Kaneka Corporation and the Department of Textile Engineering, Chemistry and Science at NC State.

Source:

North Carolina State University, Laura Oleniacz

In the future, one will be able to use their phone to read the clothing woven-in labels made with inexpensive photonic fibers. (c) Marcin Szczepanski/Lead Multimedia Storyteller, University of Michigan College of Engineering. In the future, one will be able to use their phone to read the clothing woven-in labels made with inexpensive photonic fibers.
15.02.2023

The new butterfly effect: A ‘game changer’ for clothing recycling?

Photonic fibers borrow from butterfly wings to enable invisible, indelible sorting labels

Less than 15% of the 92 million tons of clothing and other textiles discarded annually are recycled—in part because they are so difficult to sort. Woven-in labels made with inexpensive photonic fibers, developed by a University of Michigan-led team, could change that.
 
“It’s like a barcode that’s woven directly into the fabric of a garment,” said Max Shtein, U-M professor of materials science and engineering and corresponding author of the study in Advanced Materials Technologies. “We can customize the photonic properties of the fibers to make them visible to the naked eye, readable only under near-infrared light or any combination.”

Photonic fibers borrow from butterfly wings to enable invisible, indelible sorting labels

Less than 15% of the 92 million tons of clothing and other textiles discarded annually are recycled—in part because they are so difficult to sort. Woven-in labels made with inexpensive photonic fibers, developed by a University of Michigan-led team, could change that.
 
“It’s like a barcode that’s woven directly into the fabric of a garment,” said Max Shtein, U-M professor of materials science and engineering and corresponding author of the study in Advanced Materials Technologies. “We can customize the photonic properties of the fibers to make them visible to the naked eye, readable only under near-infrared light or any combination.”

Ordinary tags often don’t make it to the end of a garment’s life—they may be cut away or washed until illegible, and tagless information can wear off. Recycling could be more effective if a tag was woven into the fabric, invisible until it needs to be read. This is what the new fiber could do.
 
Recyclers already use near-infrared sorting systems that identify different materials according to their naturally occurring optical signatures—the PET plastic in a water bottle, for example, looks different under near-infrared light than the HDPE plastic in a milk jug. Different fabrics also have different optical signatures, but Brian Iezzi, a postdoctoral researcher in Shtein’s lab and lead author of the study, explains that those signatures are of limited use to recyclers because of the prevalence of blended fabrics.

“For a truly circular recycling system to work, it’s important to know the precise composition of a fabric—a cotton recycler doesn’t want to pay for a garment that’s made of 70% polyester,” Iezzi said. “Natural optical signatures can’t provide that level of precision, but our photonic fibers can.”

The team developed the technology by combining Iezzi and Shtein’s photonic expertise—usually applied to products like displays, solar cells and optical filters—with the advanced textile capabilities at MIT’s Lincoln Lab. The lab worked to incorporate the photonic properties into a process that would be compatible with large-scale production.
 
They accomplished the task by starting with a preform—a plastic feedstock that comprises dozens of alternating layers. In this case, they used acrylic and polycarbonate. While each individual layer is clear, the combination of two materials bends and refracts light to create optical effects that can look like color. It’s the same basic phenomenon that gives butterfly wings their shimmer.

The preform is heated and then mechanically pulled—a bit like taffy—into a hair-thin strand of fiber. While the manufacturing process method differs from the extrusion technique used to make conventional synthetic fibers like polyester, it can produce the same miles-long strands of fiber. Those strands can then be processed with the same equipment already used by textile makers.

By adjusting the mix of materials and the speed at which the preform is pulled, the researchers tuned the fiber to create the desired optical properties and ensure recyclability. While the photonic fiber is more expensive than traditional textiles, the researchers estimate that it will only result in a small increase in the cost of finished goods.

“The photonic fibers only need to make up a small percentage—as little as 1% of a finished garment,” Iezzi said. “That might increase the cost of the finished product by around 25 cents—similar to the cost of those use-and-care tags we’re all familiar with.”

Shtein says that in addition to making recycling easier, the photonic labeling could be used to tell consumers where and how goods are made, and even to verify the authenticity of brand-name products. It could be a way to add important value for customers.

“As electronic devices like cell phones become more sophisticated, they could potentially have the ability to read this kind of photonic labeling,” Shtein said. “So I could imagine a future where woven-in labels are a useful feature for consumers as well as recyclers.”

The team has applied for patent protection and is evaluating ways to move forward with the commercialization of the technology.
The research was supported by the National Science Foundation and the Under Secretary of Defense for Research and Engineering.

Source:

Gabe Cherry, College of Engineering, University of Michigan / Textination

Photo: Bcomp
22.11.2022

Made in Switzerland: Is Flax the New Carbon?

  • Bcomp wins BMW Group Supplier Innovation Award in the category “Newcomer of the Year”

The sixth BMW Group Supplier Innovation Awards were presented at the BMW Welt in Munich on 17 November 2022. The coveted award was presented in a total of six categories: powertrain & e-mobility, sustainability, digitalisation, customer experience, newcomer of the year and exceptional team performance.

Bcomp won the BMW Group Supplier Innovation Award in the Newcomer of the Year category. Following a successful collaboration with BMW M Motorsport for the new BMW M4 GT4 that extensively uses Bcomp’s powerRibs™ and ampliTex™ natural fibre solutions and BMW iVentures recently taking a stake in Bcomp as lead investor in the Series B round, this award is another major step and recognition on the path to decarbonizing mobility.

  • Bcomp wins BMW Group Supplier Innovation Award in the category “Newcomer of the Year”

The sixth BMW Group Supplier Innovation Awards were presented at the BMW Welt in Munich on 17 November 2022. The coveted award was presented in a total of six categories: powertrain & e-mobility, sustainability, digitalisation, customer experience, newcomer of the year and exceptional team performance.

Bcomp won the BMW Group Supplier Innovation Award in the Newcomer of the Year category. Following a successful collaboration with BMW M Motorsport for the new BMW M4 GT4 that extensively uses Bcomp’s powerRibs™ and ampliTex™ natural fibre solutions and BMW iVentures recently taking a stake in Bcomp as lead investor in the Series B round, this award is another major step and recognition on the path to decarbonizing mobility.

“Innovations are key to the success of our transformation towards electromobility, digitalisation and sustainability. Our award ceremony recognises innovation and cooperative partnership with our suppliers – especially in challenging times,” said Joachim Post, member of the Board of Management of BMW AG responsible for Purchasing and Supplier Network at the ceremony held at BMW Welt in Munich.

BMW first started to work with Bcomp’s materials in 2019 when they used high-performance natural fibre composites in the BMW iFE.20 Formula E car. From this flax fibre reinforced cooling shaft, the collaboration evolved and soon after, the proprietary ampliTex™ and powerRibs™ natural fibre solutions were found successfully substituting selected carbon fibre components in DTM touring cars from BMW M Motorsport. By trickling down and expanding into other vehicle programs, such developments highlight the vital role that BMW M Motorsports plays as a technology lab for the entire BMW Group. This continues in the form of the latest collaboration with Bcomp to include a higher proportion of renewable raw materials in the successor of the BMW M4 GT4.

With the launch of the new BMW M4 GT4, it will be the serial GT car with the highest proportion of natural fibre components. Bcomp’s ampliTex™ and powerRibs™ flax fibre solutions can be found throughout the interior on the dashboard and centre console, as well as on bodywork components such as the hood, front splitter, doors, trunk, and rear wing. Aside from the roof, there are almost no carbon fibre reinforced plastic (CFRP) components that were not replaced by the renewable high-performance flax materials. “Product sustainability is increasing in importance in the world of motorsport too,” says Franciscus van Meel, Chairman of the Board of Management at BMW M GmbH.

Bcomp is a leading solutions provider for natural fibre reinforcements in high performance applications from race to space.

The company started as a garage project in 2011 with a mission to create lightweight yet high performance skis. The bCores™ were launched and successfully adopted by some of the biggest names in freeride skiing. The founders, material science PhDs from École Polytechnique Fédérale de Lausanne (EPFL), used flax fibres to reinforce the balsa cores and improve shear stiffness. Impressed by the excellent mechanical properties of flax fibres, the development to create sustainable lightweighting solutions for the wider mobility markets started.

Flax is an indigenous plant that grows naturally in Europe and has been part of the agricultural history for centuries. It requires very little water and nutrients to grow successfully. In addition, it acts as a rotational crop, thus enhancing harvests on existing farmland. Neither cultivation nor processing of the flax plants requires any chemicals that could contaminate ground water and harvesting is a completely mechanical process. After harvesting the entire flax plant can be used for feed, to make oil and its fibres are especially used for home textiles and clothing. The long fibre that comes from the flax plant possesses very good mechanical properties and outstanding damping properties in relation to its density, making it especially suited as a natural fibre reinforcement for all kinds of polymers.

The harvesting and processing of flax takes place locally in the rural areas it was grown in. Using European flax sourced through a well-established and transparent supply chain it allows to support the economic and social structure in rural areas thanks to the large and skilled workforce required to sustain the flax production. When it comes to the production of technical products like the powerRibs™ reinforcement grid, Bcomp is investing in local production capacities close to its headquarters in the city of Fribourg, Switzerland, thus creating new jobs and maintaining technical know-how in the area. The production is built to be as efficient as possible and with minimal environmental impact and waste.

Further strengthening the local economy, Bcomp aims to hire local companies for missions and with the headquarters being located in Fribourg’s “Blue Factory” district, Bcomp can both benefit from and contribute to the development of this sustainable and diverse quarter.

Source:

Bcomp; BMW Group

© ITM/TUD - Biomimetic fish fin with dielectric elastomer actors und fiber reinforcement.
08.11.2022

Funding for Fibre-Elastomer Composites: Intelligent materials for robotics and prostheses

  • Successful approval of the 2nd funding period of the DFG Research Training Group 2430 "Interactive fibre-elastomer composites"

Researchers based in Dresden are going to develop a completely new class of materials in which actuators and sensors are integrated directly into flexible fibre composites – contrary to the state of the art. To this end, the German Research Foundation (DFG) approved the 2nd phase of Research Training Group 2430 "Interactive Fibre-Elastomer Composites" at TU Dresden in cooperation with the Leibniz Institute of Polymer Research Dresden. The spokesperson is Professor Chokri Cherif from the Institute for Textile Machinery and High-Performance Textile Materials Technology (ITM) at TU Dresden. A total of 22 doctoral students will be supported in eleven interdisciplinary sub-projects over the next 4.5 years, in addition to material and project funding.
 

  • Successful approval of the 2nd funding period of the DFG Research Training Group 2430 "Interactive fibre-elastomer composites"

Researchers based in Dresden are going to develop a completely new class of materials in which actuators and sensors are integrated directly into flexible fibre composites – contrary to the state of the art. To this end, the German Research Foundation (DFG) approved the 2nd phase of Research Training Group 2430 "Interactive Fibre-Elastomer Composites" at TU Dresden in cooperation with the Leibniz Institute of Polymer Research Dresden. The spokesperson is Professor Chokri Cherif from the Institute for Textile Machinery and High-Performance Textile Materials Technology (ITM) at TU Dresden. A total of 22 doctoral students will be supported in eleven interdisciplinary sub-projects over the next 4.5 years, in addition to material and project funding.
 
As a result the simulation-based development of intelligent material combinations for so-called self-sufficient fibre composites shall be available. Actuators and sensors are already integrated into the structures and no longer placed subsequently, as it is actual the case. In the first funding phase, the important basis for the large two-dimensional deformations in soft, biomimetic structures were developed. The further funding by the DFG is a confirmation of the outstanding results achieved so far. Building on this, the second funding phase will focus on ionic and helical actuator-sensor concepts. Combined with intelligent design and control algorithms, self-sufficient, three-dimensionally deforming material systems will emerge. This will make these systems more robust, complex preforming patterns can be customised at the desired location - reversibly and contact-free.
 
Fibre composites are used increasingly in moving components due to their high specific stiffness and strengths as well as the possibility of tailoring these properties. By integrating adaptive functions into such materials, the need for subsequent actuator placement is eliminated and the robustness of the system is significantly improved. Actuators and sensors based on textiles, such as those being researched and developed at the ITM, are particularly promising in this respect, as they can be integrated directly into the fibre composites during the manufacturing process.

With their innovative properties, interactive fibre-elastomer composites are predestined for numerous fields of application in mechanical and vehicle engineering, robotics, architecture, orthotics and prosthetics: Examples include systems for precise gripping and transport processes (e.g. in hand prostheses, closures and deformable membranes) and components (e.g. trim tabs for land and water vehicles).

More information:
robot Fibers Composites Funding
Source:

TU Dresden: Institute for Textile Machinery and High Performance Textile Materials (ITM)

(c) Empa
05.04.2022

In the heat of the wound: Smart bandage

A bandage that releases medication as soon as an infection starts in a wound could treat injuries more efficiently. Empa researchers are currently working on polymer fibers that soften as soon as the environment heats up due to an infection, thereby releasing antimicrobial drugs.

It is not possible to tell from the outside whether a wound will heal without problems under the dressing or whether bacteria will penetrate the injured tissue and ignite an inflammation. To be on the safe side, disinfectant ointments or antibiotics are applied to the wound before the dressing is applied. However, these preventive measures are not necessary in every case. Thus, medications are wasted and wounds are over-treated.

A bandage that releases medication as soon as an infection starts in a wound could treat injuries more efficiently. Empa researchers are currently working on polymer fibers that soften as soon as the environment heats up due to an infection, thereby releasing antimicrobial drugs.

It is not possible to tell from the outside whether a wound will heal without problems under the dressing or whether bacteria will penetrate the injured tissue and ignite an inflammation. To be on the safe side, disinfectant ointments or antibiotics are applied to the wound before the dressing is applied. However, these preventive measures are not necessary in every case. Thus, medications are wasted and wounds are over-treated.

Even worse, the wasteful use of antibiotics promotes the emergence of multi-resistant germs, which are an immense problem in global healthcare. Empa researchers at the two Empa laboratories Biointerfaces and Biomimetic Membranes and Textiles in St. Gallen want to change this. They are developing a dressing that autonomously administers antibacterial drugs only when they are really needed.

The idea of the interdisciplinary team led by Qun Ren and Fei Pan: The dressing should be "loaded" with drugs and react to environmental stimuli. "In this way, wounds could be treated as needed at exactly the right moment," explains Fei Pan. As an environmental stimulus, the team chose a well-known effect: the rise in temperature in an infected, inflamed wound.

Now the team had to design a material that would react appropriately to this increase in temperature. For this purpose, a skin-compatible polymer composite was developed made of several components: acrylic glass (polymethyl methacrylate, or PMMA), which is used, for example, for eyeglass lenses and in the textile industry, and Eudragit, a biocompatible polymer mixture that is used, for example, to coat pills. Electrospinning was used to process the polymer mixture into a fine membrane of nanofibers. Finally, octenidine was encapsulated in the nanofibers as a medically active component. Octenidine is a disinfectant that acts quickly against bacteria, fungi and some viruses. In healthcare, it can be used on the skin, on mucous membranes and for wound disinfection.

Signs of inflammation as triggers
As early as in the ancient world, the Greek physician Galen described the signs of inflammation. The five Latin terms are still valid today: dolor (pain), calor (heat), rubor (redness), tumor (swelling) and functio laesa (impaired function) stand for the classic indications of inflammation. In an infected skin wound, local warmth can be as high as five degrees. This temperature difference can be used as a trigger: Suitable materials change their consistency in this range and can release therapeutic substances.

Shattering glove
"In order for the membrane to act as a "smart bandage" and actually release the disinfectant when the wound heats up due to an infection, we put together the polymer mixture of PMMA and Eudragit in such a way that we could adjust the glass transition temperature accordingly," says Fei Pan. This is the temperature, at which a polymer changes from a solid consistency to a rubbery, toughened state. Figuratively, the effect is often described in reverse: If you put a rubber glove in liquid nitrogen at –196 degrees, it changes its consistency and becomes so hard that you can shatter it like glass with one blow.

The desired glass transition temperature of the polymer membrane, on the other hand, was in the range of 37 degrees. When inflammation kicks in and the skin heats up above its normal temperature of 32 to 34 degrees, the polymer changes from its solid to a softer state. In laboratory experiments, the team observed the disinfectant being released from the polymer at 37 degrees – but not at 32 degrees. Another advantage: The process is reversible and can be repeated up to five times, as the process always "switches itself off" when it cools down. Following these promising initial tests, the Empa researchers now want to fine-tune the effect. Instead of a temperature range of four to five degrees, the smart bandage should already switch on and off at smaller temperature differences.

Smart and unsparing
To investigate the efficacy of the nanofiber membranes against wound germs, further laboratory experiments are now in the pipeline. Team leader Qun Ren has long been concerned with germs that nestle in the interface between surfaces and the environment, such as on a skin wound. "In this biological setting, a kind of no man's land between the body and the dressing material, bacteria find a perfect biological niche," says the Empa researcher. Infectious agents such as staphylococci or Pseudomonas bacteria can cause severe wound healing disorders. It was precisely these wound germs that the team allowed to become acquainted with the smart dressing in the Petri dish. And indeed: The number of bacteria was reduced roughly 1000-fold when octenidine was released from the smart dressing. "With octenidine, we have achieved a proof of principle for controlled drug release by an external stimulus," said Qun Ren. In future, she said, the technology could be applied to other types of drugs, increasing the efficiency and precision in their dosage.

The smart dressing
Empa researchers are working in interdisciplinary teams on various approaches to improve medical wound treatment. For example, liquid sensors on the outside of the dressing are to make it visible when a wound is healing poorly by changing their color. Critical glucose and pH values serve as biomarkers.

To enable bacterial infections to be contained directly in the wound, the researchers are also working on a polymer foam loaded with anti-inflammatory substances and on a skin-friendly membrane made of plant material. The cellulose membrane is equipped with antimicrobial protein elements and kills bacteria extremely efficiently in laboratory tests.

Moreover, digitalization can achieve more economical and efficient dosages in wound care: Empa researchers are developing digital twins of the skin that allow control and prediction of the course of a therapy using real-time modeling.

Further information:
Prof. Dr. Katharina
Maniura Biointerfaces
Phone +41 58 765 74 47
Katharina.Maniura@empa.ch

Prof. Dr. René Rossi
Biomimetic Membranes and Textiles
Phone +41 58 765 77 65
Rene.rossi@empa.ch

Source:

EMPA, Andrea Six

Photo: pixabay
15.02.2022

Advanced Fibers: When damaged ropes change color

High-performance fibres that have been exposed to high temperatures usually lose their mechanical properties undetected and, in the worst case, can tear precisely when lives depend on them. For example, safety ropes used by fire brigades or suspension ropes for heavy loads on construction sites. Empa researchers have now developed a coating that changes color when exposed to high temperatures through friction or fire.

The firefighter runs into the burning building and systematically searches room by room for people in need of rescue. Attached to him is a safety rope at the other end of which his colleagues are waiting outside in front of the building. In an emergency - should he lose consciousness for any reason - they can pull him out of the building or follow him into the building for rescue. However, if this rope has been exposed to excessive heat during previous operations, it may tear apart. This means danger to life!

High-performance fibres that have been exposed to high temperatures usually lose their mechanical properties undetected and, in the worst case, can tear precisely when lives depend on them. For example, safety ropes used by fire brigades or suspension ropes for heavy loads on construction sites. Empa researchers have now developed a coating that changes color when exposed to high temperatures through friction or fire.

The firefighter runs into the burning building and systematically searches room by room for people in need of rescue. Attached to him is a safety rope at the other end of which his colleagues are waiting outside in front of the building. In an emergency - should he lose consciousness for any reason - they can pull him out of the building or follow him into the building for rescue. However, if this rope has been exposed to excessive heat during previous operations, it may tear apart. This means danger to life!

And up to now there has been no way of noticing this damage to the rope. 2021 a team of researchers from Empa and ETH Zurich has developed a coating which changes color due to the physical reaction with heat, thus clearly indicating whether a rope will continue to provide the safety it promises in the future.

Researchers from ETH Zurich and Empa developed a coating system in 2018 as part of a Master's thesis, which the Empa team was now able to apply to fibers. "It was a process involving several steps," says Dirk Hegemann from Empa's Advances Fibers lab. The first coatings only worked on smooth surfaces, so the method first had to be adapted so that it would also work on curved surfaces. Empa has extensive know-how in the coating of fibers - Hegemann and his team have already developed electrically conductive fibers in the past. The so-called sputtering process has now also been successfully applied to the latest coating.

Three layers are required to ensure that the fiber actually changes color when heated. The researchers apply silver to the fibre itself, in this case PET (i.e. polyester) and VectranTM, a high-tech fibre. This serves as a reflector - in other words, as a metallic base layer. This is followed by an intermediate layer of titanium nitrogen oxide, which ensures that the silver remains stable. And only then follows the amorphous layer that causes the color change: Germanium-antimony tellurium (GST), which is just 20 nanometers thick. When this layer is exposed to elevated temperatures, it crystallizes, changing the color from blue to white. The colour change is based on a physical phenomenon known as interference. Two different waves (e.g. light) meet and amplify or weaken each other. Depending on the chemical composition of the temperature-sensitive layer, this color change can be adjusted to a temperature range between 100 and 400 degrees and thus adapted to the mechanical properties of the fiber type.

Tailor-made solutions
The possible areas of application for the colour-changing fibres are still open, and Hegemann is currently looking for possible project partners. In addition to safety equipment for firefighters or mountaineers, the fibres can also be used for load ropes in production facilities, on construction sites, etc. In any case, research on the subject is far from complete. At present, it is not yet possible to store the fibers for long periods of time without losing their functionality. "Unfortunately, the phase-change materials oxidize over the course of a few months," says Hegemann. This means that the corresponding phase change - crystallization - no longer takes place, even with heat, and the rope thus loses its "warning signal". In any case, it has been proven that the principle works, and durability is a topic for future research, says Hegemann. "As soon as the first partners from industry register their interest in our own products, the fibers can be further optimized according to their needs".

Information:
Dr. Dirk Hegemann
Advanced Fibers
Tel. +41 58 765 7268
Dirk.Hegemann@empa.ch

More information:
Empa Fibers Ropes temperature
Source:

EMPA, Andrea Six

Photo: pixabay, Hilary Clark
01.02.2022

Cotton Fibers 2.0: Fireproof and comfortable

A new chemical process developed by Empa turns cotton into a fire-resistant fabric, that nevertheless retains the skin-friendly properties of cotton.

Conventional flame retardant cotton textiles suffer from release of formaldehyde and are uncomfortable to wear. Empa scientists managed to circumvent this problem by creating a physically and chemically independent network of flame retardants inside the fibers. This approach retains the inherently positive properties of cotton fibers, which account for three-quarters of the world's demand for natural fibers in clothing and home textiles. Cotton is skin-friendly because it can absorb considerable amounts of water and maintain a favorable microclimate on the skin.

A new chemical process developed by Empa turns cotton into a fire-resistant fabric, that nevertheless retains the skin-friendly properties of cotton.

Conventional flame retardant cotton textiles suffer from release of formaldehyde and are uncomfortable to wear. Empa scientists managed to circumvent this problem by creating a physically and chemically independent network of flame retardants inside the fibers. This approach retains the inherently positive properties of cotton fibers, which account for three-quarters of the world's demand for natural fibers in clothing and home textiles. Cotton is skin-friendly because it can absorb considerable amounts of water and maintain a favorable microclimate on the skin.

For firefighters and other emergency service personnel, protective clothing provides the most important barrier. For such purposes, cotton is mainly used as an inner textile layer that needs additional properties: For example, it must be fireproof or protect against biological contaminants. Nevertheless, it should not be hydrophobic, which would create an uncomfortable microclimate. These additional properties can be built into the cotton fibers by suitable chemical modifications.

Durability vs. toxicity
"Until now, it has always taken a compromise to make cotton fireproof," says Sabyasachi Gaan, a chemist and polymer expert who works at Empa's Advanced Fibers lab. Wash-durable flame retardant cotton in industry is produced by treating the fabric with flame retardants, which chemically links to the cellulose in the cotton. Currently, the textile industry has no other choice than to utilize formaldehyde-based chemicals – and formaldehyde is classified as a carcinogen. This has been an unsolved problem for decades. While formaldehyde-based flame retardant treatments are durable, they have additional drawbacks: The -OH groups of cellulose are chemically blocked, which considerably reduces the capability of cotton to absorb water, which results in an uncomfortable textile.

Gaan knows the chemistry of cotton fibers well and has spent many years at Empa developing flame retardants based on phosphorus chemistry that are already used in many industrial applications. Now he has succeeded in finding an elegant and easy way to anchor phosphorous in form of an independent network inside the cotton.

Independent network between cotton fibers
Gaan and his colleagues Rashid Nazir, Dambarudhar Parida and Joel Borgstädt utilized a tri-functional phosphorous compound (trivinylphosphine oxide), which has the capability of reacting only with specifically added molecules (nitrogen compounds like piperazin) to form its own network inside cotton. This makes the cotton permanently fire-resistant without blocking the favorable -OH groups. In addition, the physical phosphine oxide network also likes water. This flame retardant treatment does not include carcinogenic formaldehyde, which would endanger textile workers during textile manufacturing. The phosphine oxide networks, thus formed, does not wash out: After 50 launderings, 95 percent of the flame retardant network is still present in the fabric.

To render additional protective functionalities to the flame retardant cotton developed at Empa, the researchers also incorporated in situ generated silver nanoparticles inside the fabric. This works nicely in a one-step process together with generating the phosphine oxide networks. Silver nanoparticles provide the fiber with antimicrobial properties and survive 50 laundry cycles, too.

A high-tech solution from the pressure cooker
"We have used a simple approach to fix the phosphine oxide networks inside the cellulose," Gaan says. "For our lab experiments, we first treated the cotton with an aqueous solution of phosphorus and nitrogen compounds and then steamed it in a readily available pressure cooker to facilitate the crosslinking reaction of the phosphorus and the nitrogen molecules." The application process is compatible with equipment used in the textile industry. "Steaming textiles after dyeing, printing and finishing is a normal step in textile industry. So it doesn't require an additional investment to apply our process," states the Empa chemist.

Meanwhile, this newly developed phosphorus chemistry and its application is protected by a patent application. "Two important hurdles remain," Gaan says. "For future commercialization we need to find a suitable chemical manufacturer who can produce and supply trivinylphosphine oxide. In addition, trivinylphosphine oxide has to be REACH-registered in Europe."

Contact:
Dr. Sabyasachi Gaan
Advanced Fibers
Phone: +41 58 765 7611
sabyasachi.gaan@empa.ch
 
Contact:
Prof. Dr. Manfred Heuberger
Advanced Fibers
Phone: +41 58 765 7878
manfred.heuberger@empa.ch

A gel that releases drugs
The novel phosphorus chemistry can also be used to develop other materials, e.g. to make hydrogels that can release drugs upon changes in pH. Such gels could find application in treating wounds that heal slowly. In such wounds, the pH of the skin surface increases and the new phosphorus-based gels can be triggered to release medication or a dye that alerts doctors and nurses to the problem. Empa has also patented the production of such hydrogels.

Source:

EMPA, Rainer Klose

(c) STFI
14.12.2021

Funding Project Raw Material Classification of Recycled Fibers

For centuries, old textiles have been used to make tear fibers and processed into new textile products. This effective recycling is one of the oldest material cycles in the world. Today, it is not only clothing that is recycled, but also high-quality technical textiles. As the products of the textile industry evolve, so do the demands on textile recycling. The basis for this is a clear assessment and classification of raw materials.

For centuries, old textiles have been used to make tear fibers and processed into new textile products. This effective recycling is one of the oldest material cycles in the world. Today, it is not only clothing that is recycled, but also high-quality technical textiles. As the products of the textile industry evolve, so do the demands on textile recycling. The basis for this is a clear assessment and classification of raw materials.

In the research project of the German Institutes of Textile and Fiber Research Denkendorf (DITF) and the Sächsisches Textilforschungsinstitut e.V. (STFI - Saxony Textile Research Institute), a methodology is being developed that will make it possible to analyze the tearing as well as the subsequent processes with regard to fiber quality. The systematic analysis should make it possible to optimize the subsequent spinning processes in such a way that the recycled content of the yarn can be increased without the yarn properties differing significantly from those of a yarn consisting of 100% good fibers. These yarns can then be processed into sustainable textile products such as clothing or composite components.

The project, which is funded by the BMWi/IGF, is scheduled to run for two years and will end on December 31, 2022. The main benefits for the participating companies are to enable them to make greater use of secondary raw materials, to open up new markets through technologies or products developed in the project, to initiate synergies and long-term cooperation, and to prepare a joint market presence.    

The project includes several steps:

  • Material selection and procurement
    Cotton fibers to be processed are obtained from used textiles (T-shirts) and waste from the cotton spinning mill. Aramid fibers are processed from used protective clothing and technical textiles.
  • Optimization of the preparation / dissolution of the textiles
    To ensure that the fibers are detached from the corresponding textiles as gently as possible and with a not too high reduction, exact settings have to be found for the tearing process, which are technologically very demanding and require a lot of experience.
  • Determination of the quality criteria for the evaluation of the fiber dissolution
    In order to define the quality criteria, the fibers coming from the tearing mill are determined by means of an MDTA-4 measuring device from Textechno GmbH & Co. KG. The criteria determined are to be used to characterize the (lowest possible) fiber shortening caused by the tearing process.
  • Determination of optimized settings in the spinning process
    In order to determine the optimum settings for producing a yarn from the recycled fibers, they are spun after the rotor spinning process. By adjusting the spinning process, the aim is to produce a yarn that has good uniformity and also appropriate firmness.
  • Production and comparison of yarns from recycled raw materials
    In order that the recycled fibers - consisting of aramid and cotton - can each be used to produce an area-measured material, the material is to be processed at industrial scale. For this purpose, the fibers are processed over a complete blowroom line with following sliver production over adapted cards. After drawing and the following roving production, yarns are produced according to the rotor or ring spinning process. The finished yarns are used to produce knitted fabrics.
  • Coordination, analysis of results and preparation of reports
    The final report is prepared by the DITF and the STFI. The results will be transferred through publications, technical information to associations and trade fair presentations. Regular meetings with the participating companies are planned.

Textination spoke with Stephan Baz, Deputy Head of the Competence Center Staple Fiber, Weaving & Simulation, Head of Staple Fiber Technology and Markus Baumann, Research Associate at the Competence Center Staple Fiber, Weaving & Simulation (both DITF) as well as Bernd Gulich, Head of Department Nonwovens/Recycling and Johannes Leis, Research Associate Focus Nonwovens/Recycling (both STFI) about the current status of the funding project.

What is the current status of the project?
We are currently in the phase of carrying out trials and the iterative optimization of several project components. As expected, several loops are necessary for the mechanical preparation itself and also for the adjustment of the spinning process with the different variants. Ultimately, after all, the project aims at coordinating the processes of mechanical preparation and spinning as processing in order to achieve optimum results. At the same time, determining the quality criteria of the fibers produced is not trivial. This also requires the further development of processes and test methods that can be implemented productively in industry and that allow the quality of the fibers produced to be assessed effectively and unaffected by residual yarns, for example. What is really remarkable is the interest and willingness of the industry to drive the project work forward. The considerable quantities of materials required for our trials were purchased from ReSales Textilhandel und -recycling GmbH, Altex Textil-Recycling GmbH & Co. KG and Gebrüder Otto GmbH & Co. KG. Furthermore, with Temafa Maschinenfabrik GmbH, Nomaco GmbH & Co. KG, Schill + Seilacher GmbH, Spinnerei Neuhof GmbH & Co. KG and Maschinenfabrik Rieter AG, many members of the project-supporting committee are actively involved in the project, from consulting to the providing of technologies. The company Textechno Herbert Stein GmbH & Co. KG has provided a testing device of the type MDTA4 for the duration of the project and supports our work with regard to the evaluation of the mechanically prepared fibers. We are of course particularly pleased about this, as it has allowed us to look at and analyze several technologies in both mechanical preparation, testing and spinning. We expect to be able to make more detailed statements at the beginning of the coming year.

Which approaches do you think are particularly promising?
With regard to technologies, we must refer to the evaluation and analysis of the trials, which are currently still ongoing. We will be able to go into more detail in the first quarter of next year.

Of course, things are already emerging. With meta-aramid waste, promising approaches could be found very quickly; with post-consumer cotton, this is considerably more complex. Obviously, there is a link between the quality of the raw material and the quality of the products. In some cases, we have already been able to determine very low average fiber lengths in the procured goods; to a certain extent, these are of course directly reflected in the output of our processes. From this, and this is not a new finding, a great importance of the design of the textiles is again derived.

What are the challenges?
In addition to the expected high short fiber content, the residual yarns after the tearing process are an issue of particular focus. The proportion of these residual yarns can vary between the materials and preparation technologies, but the further dissolution of the products of the tearing process is essential.

If the processes are considered further in a utilization phase, the question of design naturally also arises for the best possible use of recycled fibers. Many problems, but also the approaches to solutions for the use of comparatively short fibers, can also be expected to apply to the (multiple) use of mechanically recycled fibers.

Can we speak of upcycling in the final product?
We see yarn-to-yarn recycling neither as upcycling nor downcycling, but as closed-loop recycling. The background is that the products are to go into the same application from which they came and have to compete with primary material. This means that certain specific requirements have to be met and at the same time there is considerable price pressure. In the case of downcycling, a significant reduction in properties is accepted, while in the case of upcycling, the higher-priced application can make up for the reprocessing effort. In the attempt to produce yarn material again from yarn material, both are only permissible to a small extent. This represents the particular challenge.

What does a recyclate prepared from used textiles mean for the spinning process?
Part of this question is to be answered in the project by the detailed classification of the processed fibers and is thus the subject of the tests currently underway. It turns out that, in addition to the rather obvious points such as significantly reduced fiber length, process disturbances due to undissolved fabrics and yarn pieces, there are also less obvious aspects to be considered, such as a significantly increased outgoing quantity for processing in the spinning process. The outgoing quantity is of particular interest here, because in the end the newly produced yarn should also contain a considerable proportion of prepared fibers.

What consequences does this have for textile machinery manufacturing?
The consequences that can already be estimated at the present time are that, particularly in the processing of cotton, the machinery in the spinning preparatory mill is specialized in the processing of (new) natural fibers with a certain amount of dirt. In contrast to new fibers, processed fibers are clean fibers with a significantly higher proportion of short fibers. Elements that are good at removing dirt also reject an increased amount of short fibers, which can lead to unintentionally high waste quantities under certain circumstances. It is therefore necessary to adapt the established machine technology to the new requirement profile of the raw material "processed fibers". Analogous adaptations are probably necessary along the entire processing chain up to the yarn. In the drafting system of the spinning machine, of course, this is due more to the high short fiber ratio than to elements that have been optimized for cleaning out dirt and foreign substances.

Source:

Textination GmbH

(c) nova-Institut GmbH
07.12.2021

Finalists for „Cellulose Fibre Innovation of the Year 2022” announced

Cellulose Fibre Innovation of the Year 2022: Cellulose Fibre Solutions are expanding from hygiene and textiles as well as non-wovens up to alternatives for carbon fibres for light-weight applications.

Great submissions made the nomination for the Innovation Award difficult. All of them present promising sustainable solutions in the field of cellulose fibres value chain. Six of them now get the chance to demonstrate their potential to a wide audience in Cologne (Germany), and online.

Cellulose Fibre Innovation of the Year 2022: Cellulose Fibre Solutions are expanding from hygiene and textiles as well as non-wovens up to alternatives for carbon fibres for light-weight applications.

Great submissions made the nomination for the Innovation Award difficult. All of them present promising sustainable solutions in the field of cellulose fibres value chain. Six of them now get the chance to demonstrate their potential to a wide audience in Cologne (Germany), and online.

For the second time, nova-Institute grants the “Cellulose Fibre Innovation of the Year” within the framework of the “International Conference on Cellulose Fibres 2022” (2-3 February 2022). The advisory board of the conference nominated six  products, ranging from cellulose made of orange- and wood pulp to a novel technology for cellulose fibre production. The presentations, election of the winner by the conference audience and the award ceremony will take place on the first day of the conference.

Cellulose fibres show an increasingly expanding wide range of applications, while at the same time markets are driven by technological developments and political framework conditions, especially bans and restrictions on plastics and increasing sustainability requirements. The conference provides rich information on opportunities for cellulose fibres through policy assessment, a session on sustainability, recycling and alternative feedstocks as well as latest development in pulp, cellulose fibres and yarns. This includes application such as non-wovens, packaging and composites.

Here are the nominees:
Carbon Fibres from Wood – German Institutes of Textile and Fiber Research Denkendorf (Germany)
The HighPerCellCarbon® technology is a sustainable and alternative process for the production of carbon fibres made from wood. The technology starts with wet spinning of cellulosic fibres using ionic liquids (IL) as direct solvent in an environmentally friendly, closed loop filament spinning process (HighPerCell® technology). These filaments are directly converted into carbon fibres by a low-pressure stabilisation process, followed by a suitable carbonisation process. No exhaust fumes or toxic by-products are formed during the whole process. Furthermore, the approach allows a complete recycling of solvent and precursor fibres, creating a unique and environmentally friendly process. Carbon fibres are used in many lightweight applications and the fibres are a sustainable alternative to fossil-based ones.

Fibers365, Truly Carbon-Negative Virgin Fibres from Straw – Fibers365 (Germany)
Fibers365 are the first carbon-negative virgin straw fibres on the market. The Fibers365 concept is based on a unique, state of the art process to provide functional, carbon negative, and competitive non-wood biomass products such as virgin fibres for paper, packaging and textile purposes as well as high value process energy, biopolymer and fertilizer side streams. The products are extracted from the stems of annual food plants such as straw by a chemical-free, regional, farm level steam explosion pulping technology, allowing an easy separation of the fibres from sugars, lignin, organic acid and minerals. In the case of annual plants, CO2 emissions are recaptured within 12 months from their production date, offering “instant”, yearly compensation of corresponding emissions.

Iroony® Hemp and Flax Cellulose – RBX Créations (France)
Iroony® is a branded cellulose made by RBX Créations from hemp. This resistant hemp plant grows quickly within in a few months, massively captures carbon and displays a high content of cellulose. The biomass is directly collected from French farmers who cultivate without chemicals or irrigation, in extended rotation cycles, contributing to soil regeneration and biodiversity. For a diversified supply, the hemp can be combined with organically-grown flax. Through its patented process, RBX Créations extracts high-purity cellulose, perfectly suitable for spinning technologies such as HighPerCell® of DITF research centre. The resulting fibres display versatile properties of fineness, tenacity and stretch, for applications like clothing or technical textiles. Iroony® combines low impact, trackability and performance.

SPINNOVA, Sustainable Textile Fibre without Harmful Chemicals – Spinnova (Finland)
Spinnova’s innovative technology enables production of sustainable textile fibres in a mechanical process, without dissolving or any harmful chemicals. The process involves use of paper-grade pulp and mechanical refining to turn pulp into microfibrillated cellulose (MFC). The fibre suspension consisting of MFC is extruded to form textile fibre, without regeneration processes. The Spinnova process does not generate any side waste, and the environmental footprint of SPINNOVA® including 65 % less CO2 emissions and 99 % less water compared to cotton production. Spinnova’s solution is also scalable: Spinnova targets to reach 1 million tonnes annual production capacity in the next 10 to 12 years.    

Sustainable Menstruation Panties: Application-driven Fibre Functionalisation – Kelheim Fibres (Germany)
Kelheim’s plant-based and biodegradable fibres contribute significantly to a sustainable future in the field of reusable hygiene textiles. Through innovative functionalisation they are specifically adjusted to the requirements of the single layers and thereby reach a performance comparable to that of synthetic fibres. A unique duality in fibre technology is created: sustainably manufactured cellulosic fibres that allow for high wearing comfort and reusability with extraordinary, durable performance. Fibre concepts comprise Celliant® Viscose, an in-fibre infrared solution and Danufil® Fibres in the top sheet, Galaxy, a trilobal fibre for the ADL, Bramante, a hollow viscose fibre, in the absorbing core and a water repellent woven fabric, a biodegradable PLA film or a sustainable coating as a back sheet.

TENCEL™ branded Lyocell Fibre made of Orange and Wood Pulp – Orange Fiber (Italy)
Orange Fiber is the world's first company to produce a sustainable textile fibre from a patented process for the extraction of cellulose to be spun from citrus juice leftovers, which are more than 1 million tonnes a year just in Italy. The result of our partnership with Lenzing Group, leading global producer of wood-based specialty fibres, is the first ever TENCEL™ branded lyocell fibre made of orange and wood pulp. A novel cellulosic fibre to further inspire sustainability across the value chain and push the boundaries of innovation. This fibre, part of the TENCEL™ Limited Edition initiative, is characterized by soft appeal and high moisture absorbance and has already obtained the OEKO-TEX Standard 100 certificate and is undergoing a diverse set of other sustainability assessments.

Photo: pixabay
19.10.2021

Micromechanical Simulation of the Resilience of Nonwovens

Nonwovens are an important component of different products of several uses, e.g. transport of humidity in sanitary products, insulation materials or filters. Nonwovens are usually produced on large engineering facilities. For this, experimental studies of design with regard to the optimization of these nonwoven-structures prove to be very difficult.

Influence Design Parameters
There are so many parameters of design, as for example fibers, surface weight or type of nonwoven bonding and finishing that are affecting the properties of nonwovens. For the change of one single parameter, e.g. the material of fiber, it is necessary to adapt the whole process of fabrication from the spinning of the fibers via their stacking to the nonwoven hardening.

Nonwovens are an important component of different products of several uses, e.g. transport of humidity in sanitary products, insulation materials or filters. Nonwovens are usually produced on large engineering facilities. For this, experimental studies of design with regard to the optimization of these nonwoven-structures prove to be very difficult.

Influence Design Parameters
There are so many parameters of design, as for example fibers, surface weight or type of nonwoven bonding and finishing that are affecting the properties of nonwovens. For the change of one single parameter, e.g. the material of fiber, it is necessary to adapt the whole process of fabrication from the spinning of the fibers via their stacking to the nonwoven hardening.

Following the production of such a prototype a time consuming and cost-intensive characterization of the properties of nonwovens carried out experimentally has to be done.  Therefore, for this reason detailed studies considering several parameters of design are uneconomic.

Thus, micromechanical models of simulation are developed at Fraunhofer ITWM in cooperation with Procter & Gamble Service GmbH (P & G). By means of these models it is possible to forecast numerically the effective properties of nonwovens for diverse parameters of design. To virtually modify and optimize individual parameters in this connection it is only necessary to adapt the corresponding inputs of the model.

Fast Predictions Possible
In this case, the focus of the numerical predictions is primarily lying on the time-dependent behavior of the nonwovens.  The dynamic properties can be determined by means of numerical simulation of cyclic measurements. In doing so, a good correspondence of simulation and measurements is obtained.

Compared to experiments the required time of simulation for the behavior in case of low frequencies does not change. Therefore, we can obtain rapid forecasts for the long-term behavior (month till years) and the corresponding resilience of nonwovens using numerical models. A lot of alternatives can be simulated and studied within a few hours.

The fact that not only effective (macroscopic) properties of nonwovens can be computed, but also local physical values such as distribution of tension in binding agents and fibres is a further advantage of this micromechanical  approach. So, the simulation contributes to a better understanding of the properties of nonwovens.

Future designs deal with an extension of the models with regard to simulation of the productionv processes. By this, a fully digitalized layout design of nonwovens, from the manufacturing process till the optimization of functionality is possible.

Source:

Fraunhofer Institute for Industrial Mathematics ITWM

Photo: pixabay
17.08.2021

Innovative wound care: Customized wound dressings made from tropoelastin

Customized, biomedically applicable materials based on tropoelastin are being developed in a joint project by Skinomics GmbH from Halle, Martin Luther University Halle-Wittenberg and the Fraunhofer Institute for Microstructure of Materials and Systems IMWS. The material combines biocompatibility, durability, biodegradability and favorable mechanical properties similar to those of skin. Preclinical tests have confirmed that it is suitable for use as a wound dressing material used in the treatment of chronic and complex wounds.

Customized, biomedically applicable materials based on tropoelastin are being developed in a joint project by Skinomics GmbH from Halle, Martin Luther University Halle-Wittenberg and the Fraunhofer Institute for Microstructure of Materials and Systems IMWS. The material combines biocompatibility, durability, biodegradability and favorable mechanical properties similar to those of skin. Preclinical tests have confirmed that it is suitable for use as a wound dressing material used in the treatment of chronic and complex wounds.

Particularly in the context of an aging society, special wound dressings are gaining in importance. The treatment of complex wound diseases such as venous ulcers, leg ulcers, or foot ulcers is challenging for medical staff, long-term and painful for those affected and cost-intensive for the healthcare system. Innovative protein-based materials are now being used for the treatment of such wounds. However, since they are made from animal tissues, they carry increased risks of infection or can result in undesirable immune reactions. In addition, there are increasing reservations in the population about medical products of animal origin.

In the joint research project, the project partners are currently developing customized, biomedically applicable materials based on human tropoelastin. This precursor protein is converted in the body to elastin, a vital and long-lived structural biopolymer that has exceptional mechanical properties and thus gives the skin and other organs the elasticity and resilience they need to function.

“Elastin is chemically and enzymatically extremely stable, biocompatible and does not produce immunological rejections when used as a biomaterial in humans. Therefore, we want to create new and innovative solutions for the treatment of complex wounds based on human tropoelastin,” says Dr. Christian Schmelzer, Head of the Department of Biological and Macromolecular Materials at Fraunhofer IMWS.

Individual wound treatment
As part of the research project led by Prof. Dr. Markus Pietzsch of Martin Luther University Halle-Wittenberg, the researchers succeeded in developing a biotechnological process for modifying tropoelastin. The modified tropoelastin is processed at Fraunhofer IMWS. Here, an electrospinning procedure is used to produce ultra-thin nanofibers with diameters of only a few hundred nanometers. The resulting nonwovens are further crosslinked to stabilize them for the respective application. The procedures developed have been optimized so that biomedical parameters such as pore size, stability and mechanical properties are variable and can thus be customized to meet the requirements of the respective wound treatment. The materials produced using the new procedures are being investigated by Skinomics GmbH in initial preclinical tests with regard to their skin compatibility and have already achieved promising results.

At the end of the project by the end of this year, applications for intellectual property rights are to be filed, building the basis for a subsequent product development phase for certified medical products.

PERFORMANCE DAYS Nothing to Waste - Closing the Loop (c) PERFORMANCE DAYS
20.10.2020

PERFORMANCE DAYS Nothing to Waste - Closing the Loop

  • Finite resources and endless mountains of rubbish set the tone of the upcoming 25th edition of PERFORMANCE DAYS. Closing the loop means nothing is wasted, not even time, as recycled clothing gets recycled again and again.

In keeping with this topic, the trade fair organizers are planning expert discussion panels to help present the facts as well as visions of the future. Expect the corresponding displays of sustainable materials, chosen by the PERFORMANCE FORUM Jury. Look for materials such as fibers from recycled PET bottles, recyclable mono-component materials or blends, and shirts that decompose to biomass in a "Cradle-to-Cradle" approach. "Nothing to Waste - Closing the Loop" is open to the public at the Messe München fairgrounds and as a Digital Fair online starting on December 9-10, 2020.

  • Finite resources and endless mountains of rubbish set the tone of the upcoming 25th edition of PERFORMANCE DAYS. Closing the loop means nothing is wasted, not even time, as recycled clothing gets recycled again and again.

In keeping with this topic, the trade fair organizers are planning expert discussion panels to help present the facts as well as visions of the future. Expect the corresponding displays of sustainable materials, chosen by the PERFORMANCE FORUM Jury. Look for materials such as fibers from recycled PET bottles, recyclable mono-component materials or blends, and shirts that decompose to biomass in a "Cradle-to-Cradle" approach. "Nothing to Waste - Closing the Loop" is open to the public at the Messe München fairgrounds and as a Digital Fair online starting on December 9-10, 2020.

The PERFORMANCE DAYS trade fair has chosen a new Focus Topic that concerns not only our own industry. The textile industry has long been achieving more efficient production by recycling its own waste products and using recycled materials from outside the industry, for example, PET-bottles. Nevertheless, textiles exist alongside glass, paper, metal, and plastics as a separate branch of waste management. Despite ambitious efforts at recycling by the waste and textile industries, the efficient use of textile waste as a resource remains a challenge. Compounding this challenge are the difficulties caused by a global world: production, consumers, and disposal sites are miles apart, shared expert knowledge about the other industries is lacking, and international standards and political support are nearly non-existent.

Final destination: the waste bin
Information from the Federal Office for the Environment shows that 0.8% of the oil produced is used in the textile industry for the production of new textiles. But the costly processing chain of this finite resource ends all too quickly in waste. A Greenpeace survey reveals outdated fashions or clothing of worn quality is thrown away within three years, only to land in the trash dumpsters. The European Environmental Agency estimates that 5.8 million tons of used textiles are discarded every year and either incinerated, used for landfill, or taken to mechanical-biological sewage treatment plants. Even if used clothing is collected by state or private companies, in many cases it cannot be sold (as second hand), donated, or recycled (into rags or insulating material). In the best case scenario, it is incinerated and converted to thermal energy.

Recycling and circular design
From an economic and environmental perspective, the term recycling refers to waste-free products, waste avoidance, and waste recovery and disposal. In our industry as it stands, recycling at the end of the product life cycle usually means converting the product into some other product, i.e., not clothing. This is the "Open-Loop" process. Accordingly, textiles are eventually incinerated, but the amount of energy recovered can vary greatly depending on how efficiently the waste incineration plant works. Such devaluing of the product to a product with less value than the original product is known as Downcycling. However, Downcycling is not the only solution: the "Closed-Loop" approach has the goal of making new clothes out of old ones through recycling. The closed loop for renewable natural resources, for example, can mean that natural fibers used in textiles will end up becoming soil, which is the nutrient for new natural fibers, i.e., a cradle-to-cradle approach. Synthetic garments similarly require extracting the man-made fibers and reprocessing them to produce another garment.

Planning for the end in advance
Rather than thinking about recycling opportunities at the end of the product life cycle, brands can already begin developing closed loop options while in the design phase. Among other things, designing out the waste can reduce the environmental impact of the products. To extend the useful life, consider leasing the materials and/or adding labels with instructions for disposal, repair, or repurposing. And, what about the idea of preparing 100% used textiles that can be reintroduced into the supply chain as 100% new textiles? Separating the different types of fiber used in blends is complex, cost-intensive, and further complicated when labels are non-existent (or no longer existing) or it is simply not (yet) technically possible. More and more clothing makers and suppliers are trying to avoid mixing fibers and are switching to "mono-materials" or "mono-components." Shirts are easy to make in this way, but if you add buttons, zippers, etc., the issue becomes more complex.

Nothing to waste - not even time
If you are like many end consumers, brand managers, and producers and want to make use of valuable resources in a more sustainable manner, register now on the trade fair website under "Visitor Login." There you can access a free trade fair ticket for December 9-10, 2020. You can also learn about the complimentary and soon to be expanded offers at the Digital Fair. Don’t forget to sign-up for the free Newsletter mailings. 

•     09.-10. December 2020      DIGITAL FAIR  Trends Winter 2022/23 

 

UPDATE
CoVid-19 continues to keep the world on edge. Many PERFORMANCE DAYS visitors, as well as exhibitors, have already announced that travelling to Munich in December would be simply impossible for them. Due to the increasing number of infections, further international travel bans and company-internal travel restrictions are now threatening. As a result, the December 2020 edition of PERFORMANCE DAYS will unfortunately not take place at the Messe München, but as Digital Fair! On the planned dates of December 09-10, both approved and advanced new tools will go online and provide further proof of PERFORMANCE DAYS’ expansion of its pioneering role in creating a digital textile trade fair experience.