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Aerogel (c) Outlast Technologies GmbH
31.01.2023

Aerogel: Frozen Smoke for Clothing and Work Safety

Comprised of up to 99.8 percent air, aerogel is the lightest solid in the world. The material, which is also called “frozen smoke” due to its appearance and physical properties, exhibits extremely low heat conductivity which exceeds other insulations many times over. This is why NASA has already been using aerogel for aerospace projects for many years.

Despite this, it has not been possible to bind the material to textiles in a high concentration and enable straightforward further processing over the roughly 90-year history of the material. Outlast Technologies GmbH has developed an innovative process - a patent has already been filed for -  for permanently adhering large amounts of aerogel to different media, like nonwoven fabric, felt and composites materials. Their original properties are retained throughout, so they can easily be further processed using conventional production methods.

Comprised of up to 99.8 percent air, aerogel is the lightest solid in the world. The material, which is also called “frozen smoke” due to its appearance and physical properties, exhibits extremely low heat conductivity which exceeds other insulations many times over. This is why NASA has already been using aerogel for aerospace projects for many years.

Despite this, it has not been possible to bind the material to textiles in a high concentration and enable straightforward further processing over the roughly 90-year history of the material. Outlast Technologies GmbH has developed an innovative process - a patent has already been filed for -  for permanently adhering large amounts of aerogel to different media, like nonwoven fabric, felt and composites materials. Their original properties are retained throughout, so they can easily be further processed using conventional production methods.

The fabrics sold under the Aersulate name are only 1 to 3 mm thick and achieve very high insulation values which are largely retained even under pressure and in moist conditions. Despite their high performance, they are still soft and can be used for shoes, clothing and work safety products, as well as for sleeping bags and technical applications.
 
“Thanks to its extraordinary physical properties, NASA has already been using aerogel for many years,” remarked Volker Schuster, Head of Research and Development at Outlast Technologies. “For example, for the insulation of its Mars rovers and for capturing dust from the tail of a comet during the Stardust mission,” he continued. Since the development of aerogel by American scientist and chemical engineer Samuel Stephens Kistler in 1931, no-one had been able to apply the versatile material to textiles in large amounts without changing their original properties, despite intensive research. This means that the products were often not only very rigid, but made processing with conventional production methods impossible due to their high degree of dust abrasion. With the newly developed Aersulate technology, which was presented for the first time in June 2022, the Heidenheim-based specialist for textile thermoregulation is opening a different chapter in insulation history.

High-performance insulation just 1 to 3 mm thick
“The consistency of aerogel can be best described as liquid dust particles which spread uncontrollably throughout a room within seconds thanks to their minimal thickness,” explained Schuster. “This is why processing is a big challenge.” Outlast Technologies has managed, after a development period of around five years, to bring an innovative process involving the adhering of aerogel between multiple layers of material to market maturity. Depending on the area of application, nonwoven fabric, felt and different composite materials can be used as the media. What is special here is that the properties of the respective textiles are not adversely affected by the Aersulate technology, meaning that they can easily be further processed with conventional means and under industrial conditions despite their acquired thermal properties.
 
As a silicate-based solid, aerogel is obtained from natural quartz sand, yet exhibits a density over 1,000 times lower than glass manufactured from the same raw material. The extraordinary thermo-insulating properties of the material are thanks to its extremely porous structure, which enables it to be composed of up to 99.8 percent air.
 
“One liter of aerogel weighs just 50 g,” explained Schuster. “Just 10 g of the material has the same surface area as a soccer field, though.” Thanks to these properties, Aersulate textiles exceed all other previously known insulation materials in terms of performance, despite the fact that they are only 1 to 3 mm thick. Tests carried out by the German Institute for Textile and Fiber Research in Denkendorf (DITF) using the Alambeta method showed that the thermal resistance of an Aersulate fleece is more than double that of a conventional fleece of the same thickness. Add to this the fact that the thermo-insulating properties of Aersulate products remain high despite pressure and wetness, while they decrease enormously with other conventional materials like felt and polyurethane foam (PU) under these conditions.

Work safety and functional clothing with Aersulate
Thanks to the textile medium, thin Aersulate products are especially suitable for the shoe and clothing industry, as well as all areas of work safety. The user benefits from different properties, depending on the intended use. “With a glove made of Aersulate just 1 mm thick, you can put your hand into boiling water without being scalded, for example,” explained Schuster. “The material’s extremely hydrophobic properties play quite literally into our hands here.” In the case of knee patches on work and functional pants, as well as shoes and soles, on the other hand, the material properties also become relevant when compression occurs. This is because the thermo-insulation properties of other materials would be reduced little by little due to moisture from the outside and sweat from the inside on the one hand, and by the continual influence of body weight on the other.
          
In addition to the human body, luggage and technical devices can also be protected from extreme temperatures and the effects of weather with Aersulate. For this purpose, corresponding cell phone or equipment pockets could be sewn into garments, for example, to maintain their battery life even at very cold outside temperatures and to safeguard the devices from overheating in case of high heat exposure. “With the broad range of possible textile medium materials, Aersulate is suitable for all applications requiring high thermal resistance on the one hand, where only a little space is available and both compression and moisture can be expected on the other,” said Schuster in summary.

Source:

Outlast Technologies / Textination

SARD Durable Labeling with lanthanide-based Security Substance ©wederundgut AG
05.04.2016

DURABLE LABELING WITH LANTHANIDE-BASED SECURITY SUBSTANCE

  • Forgery-safe Branded Fashion via washable Authentification Certificate

In 2014 German customs seized about 1.3 million counterfeit garments and accessories worth EUR 10.94 million. Particularly renowned brands suffer from piracy and try using different measures, such as hologram labels or special sewing yarns to protect their fashion - so far with little success, because professional counterfeiters can copy these marks most convincing.

  • Forgery-safe Branded Fashion via washable Authentification Certificate

In 2014 German customs seized about 1.3 million counterfeit garments and accessories worth EUR 10.94 million. Particularly renowned brands suffer from piracy and try using different measures, such as hologram labels or special sewing yarns to protect their fashion - so far with little success, because professional counterfeiters can copy these marks most convincing.

But that could change now: As the first brand apparel manufacturer the Swiss wederundgut ag recently added on their UNiSONO -Shirts a labeling with a lanthanide-based SARD - safety substance which is completely tamper-proof due to high-covalent and doped crystal lattice. It has a unique, tailored composition with individual emission spectra and can be detected and deciphered only with an especially for this application developed laser measuring instrument. The incorporation in a multi-layer, firmly with the shirt fabric glued label, the marking cannot be destroyed neither by the wash liquor nor by mechanical influences during the washing process.

"Brand counterfeiting is becoming more and more a problem for the fashion industry.  Especially well-known brands are suffering from the proliferation of plagiarism" Ueli Fish, CEO of wederundgut ag, explains. "It is therefore in our own interest as textile manufacturers, to find ways to make our products clearly marked as identifiable originals."

Within the sector many protective measures have already been tried, but without achieving a long term desired effect: One company for example works with holograms on the label. For professional plagiarists a hologram provides no bigger hurdle in these days, stated Dieter Ebert, CTO at the product protection specialist swiss authentication research and development AG (SARD) explains. As another possibility sewing threads will be soaked with safety fluids. "The disadvantage is that all known substances will sooner or later be completely washed out of the fabric in the washing process," the expert said. Several manufacturers of high-quality functional wear labeled their products temporarily with RFID chips. However, they also were destroyed in the washing process sooner or later - partly through the water, partially mechanically, so that this solution has been abandoned. Others prefer to educate their customers trying to explain differences between original and copied patches.

Individual, clearly identifiable marking

For the marking with the by SARD developed safety substance wederundgut ag decided due to the utter counterfeit security and adaptability for different applications. "The substance contains a custom mixture of lanthanides, which form a very complex, high-covalent and doped crystal lattice," the CTO explains. "In the production of a patented process at a defined point some foreign substances in the smallest amounts will be added that changes the emission spectrum significantly." By excitation in the UV or IR range the substance sends the customized optical spectra. These are stored in an associated detector, which has been developed by SARD for this application, and can only be recognized by the latter. All mixtures of the substance are stable at temperatures far above 1,700°C, resistant to acids, bases and radiation, highly resistant to chemicals and toxicologically safe. The particles, which generally have a size of about 1 to 10 microns, also allow no interactions with any other substances.

A decisive advantage of the substance is that the production process is not possible to replicate due to the artificial emission spectra: "Through the endowment spectra will be generated, of which it cannot be determined which elements are involved. Therefor a replica of the substance through reverse engineering is not possible, Ebert says.

Also the laser measuring device cannot be manipulated, since it has its own software and a virus free operating system and uses for algorithm and cryptography the FPGA technology. When evaluating the marking SARD also focuses on the key-lock principle: "The two independent emission spectra of custom substances serve as the key. They are stimulated and measured by the two independent laser systems of the detector”, so the CTO. “Decoding is performed with in the device stored, cryptographically encrypted information. They therefore act as a lock." Only when the correct substance is detected, a protected algorithm shows the customer-specific information on the display of the detector. This feature ensures a highly secure authentication.

Not leachable substance

In addition to the protection against forgery wederundgut is demanding further properties on the marking. "The label should not get an optically negative change, should be completely hypoallergenic and should remain from the cost point on an acceptable level," Fish says. The most important point for the textile manufacturer however was, that even after repeated washing the substance remains detectable: "That was at first a great challenge for us," Ebert says. "If we would have brought he SARD-substance in a conventional manner into the material, for example just with a color - as with solutions of other manufacturers - then there would have been the risk that the substance would be washed out by the surfactants of the detergent. Therefore we had to find at first a suitable carrier material. Together with the Munich label specialists RATHGEBER GmbH & Co. KG SARD finally developed a solution in which the substance will be incorporated into an iron-on label made of plastic composite material from which it cannot be removed. "This label is produced in several layers," Ebert says. "In one of them the SARD-substance will be incorporated and permanently sealed with another layer."

The label corresponds optically with the known company label of UNiSONO, the safety substance is difficult to detect with the bare eye. The final label is, among other things, resistant to alkalis, chemical cleaning agents, UV radiation, mechanical stress, acids, weather influences and keeps temperatures from -30 to 120°C. It will be ironed onto the shirt using a special hot-melt adhesive. This agent is very resistant and does not dissolve from the fabric, even at very frequent washing as is common for example in sports clothing. "At this project together with SARD we achieved great results very fast. With the current result, a very uncomplicated solution for us, we are very satisfied,” Fish explains, who puts the security label directly in the clothing factory on the shirts. “In the future we'd like to get a label that is even more soft and thinner than the current one. We intend to work on it together with SARD," the CEO said.