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Nordic cooperation on circular innovation focusing on workwear Photo: Sven, pixabay
16.04.2024

Nordic cooperation on circular innovation focusing on workwear

The University of Borås, Aalborg University Business School and Circular Innovation Lab have just started the 'North-South Circular Value Chains Within Textiles' project - an explorative project that aims at bridging textile brands in the Nordics with a strong focus on sustainability with innovative producers in the South.

Focus areas are Circular Value Chains (CVCs), Circular and resource-efficient textiles economy, Workwear and technical clothing, Sectors such as construction, energy, electronics and IT, plastics, textiles, retail and metals.

Made possible by a grant from the Interreg ÖKS programme, the first step is to create a specific economic, legal and technological framework allowing Scandinavian workwear companies to enter into close collaboration on circular solutions in the overall textile value chain and to prepare, and adapt their global value chains to the upcoming EU regulations on circular economy.

The University of Borås, Aalborg University Business School and Circular Innovation Lab have just started the 'North-South Circular Value Chains Within Textiles' project - an explorative project that aims at bridging textile brands in the Nordics with a strong focus on sustainability with innovative producers in the South.

Focus areas are Circular Value Chains (CVCs), Circular and resource-efficient textiles economy, Workwear and technical clothing, Sectors such as construction, energy, electronics and IT, plastics, textiles, retail and metals.

Made possible by a grant from the Interreg ÖKS programme, the first step is to create a specific economic, legal and technological framework allowing Scandinavian workwear companies to enter into close collaboration on circular solutions in the overall textile value chain and to prepare, and adapt their global value chains to the upcoming EU regulations on circular economy.

Recently, the consortium partners convened for an initial meeting at The Swedish School of Textiles to discuss the project framework, which is a feasibility study intended to lead to a multi-year project involving workwear companies in the Öresund-Kattegat-Skagerrak (ÖKS) region, including their supply chains in Asia.

Kim Hjerrild, Strategic Partnerships Lead at the Danish think tank Circular Innovation Lab, Copenhagen, explained: "The goal is to assist workwear producers in Denmark, Sweden, and Norway in becoming more sustainable through circular product design, production, and service concepts. We are pleased to have The Swedish School of Textiles lead the project as they have a strong tradition of collaborating with textile companies."

Complex branch
The decision to focus specifically on workwear stems from it being a complex part of the textile industry, demanding strict standards, certifications, safety aspects, and specific functions depending on the application area, such as specific high-performance environments, healthcare, and hospitality. "To future-proof their operations, companies need to become more resource efficient and circular by producing durable and long lasting workwear that can be repaired and reused. Additionally, they must reduce their carbon footprint per product, as well as minimize problematic chemical usage, and increasingly use recycled materials" explained Kim Hjerrild.

Wants to provide companies with tools and knowledge
Apoorva Arya, founder and CEO of Circular Innovation Lab, elaborates: "Our first and primary goal is to equip Scandinavian workwear companies with tools and knowledge in order to comply with the upcoming EU directives and policies. This includes regulations on product-specific design requirements to labour conditions for employees, human rights, all the way from production to third-party suppliers. Ensuring these companies, especially their suppliers, can transition to a circular supply chain, and navigate the legislative landscape, while guaranteeing competitiveness in the global market."

Focus on new structures
Rudrajeet Pal, Professor of Textile Management at The Swedish School of Textiles, is pleased that the university can be the coordinator of the project. "From the perspective of my research group, this
is incredibly interesting given the focus on the examination and development of ‘new’ supply chain and business model structures that would enable sustainable value generation in textile enterprises, industry, and for the environment and society at large. We have conducted several projects where such global north-south value chain focus is eminent, and this time particularly in workwear companies’ value chain between Scandinavia and Asia. We are delighted to contribute expertise and our experience of working internationally."

About the pre-project North-South Circular Value Chains Within Textiles, NSCirTex
The project aims to support the circular transition in the Nordics by setting up a shared governance model to enable pre-competitive collaboration and the design of circular value chains between Scandinavian workwear companies in the ÖKS-region and producers in India, Bangladesh, Vietnam, and Türkiye.

The next step is to achieve a multi-year main project where workwear companies with their suppliers in Asian countries, can test tailored models for shared governance as a way to develop practical circular solutions, such as post-consumer recycling, circular material procurement, develop safe and resource efficient circular products, enhance social sustainability and due diligence, among others. The main project will thus develop solutions to reduce material footprint, and resource usage while generating both commercial viability and prepare for new regulation, reporting, and accountability.

Partners in this feasibility study: University of Borås, Aalborg University Business School, and Circular Innovation Lab. The feasibility study is funded by the EU through the Interreg Öresund-Kattegat-Skagerrak European Regional Development Fund.

Source:

University of Borås, Solveig Klug

textile waste AI generated image: Pete Linforth, Pixabay
02.04.2024

The Future of Circular Textiles: New Cotton Project completed

In a world first for the fashion industry, in October 2020 twelve pioneering players came together to break new ground by demonstrating a circular model for commercial garment production. Over more than three years, textile waste was collected and sorted, and regenerated into a new, man-made cellulosic fiber that looks and feels like cotton – a “new cotton” – using Infinited Fiber Company’s textile fiber regeneration technology.
 

In a world first for the fashion industry, in October 2020 twelve pioneering players came together to break new ground by demonstrating a circular model for commercial garment production. Over more than three years, textile waste was collected and sorted, and regenerated into a new, man-made cellulosic fiber that looks and feels like cotton – a “new cotton” – using Infinited Fiber Company’s textile fiber regeneration technology.
 
The pioneering New Cotton Project launched in October 2020 with the aim of demonstrating a circular value chain for commercial garment production. Through-out the project the consortium worked to collect and sort end-of-life textiles, which using pioneering Infinited Fiber technology could be regenerated into a new man-made cellulosic fibre called Infinna™ which looks and feels just like virgin cotton. The fibres were then spun into yarns and manufactured into different types of fabric which were designed, produced, and sold by adidas and H&M, making the adidas by Stella McCartney tracksuit and a H&M printed jacket and jeans the first to be produced through a collaborative circular consortium of this scale, demonstrating a more innovative and circular way of working for the fashion industry.
 
As the project completes in March 2024, the consortium highlights eight key factors they have identified as fundamental to the successful scaling of fibre-to-fibre recycling.

The wide scale adoption of circular value chains is critical to success
Textile circularity requires new forms of collaboration and open knowledge exchange among different actors in circular ecosystems. These ecosystems must involve actors beyond traditional supply chains and previously disconnected industries and sectors, such as the textile and fashion, waste collection and sorting and recycling industries, as well as digital technology, research organisations and policymakers. For the ecosystem to function effectively, different actors need to be involved in aligning priorities, goals and working methods, and to learn about the others’ needs, requirements and techno-economic possibilities. From a broader perspective, there is also a need for a more fundamental shift in mindsets and business models concerning a systemic transition toward circularity, such as moving away from the linear fast fashion business models. As well as sharing knowledge openly within such ecosystems, it also is important to openly disseminate lessons learnt and insights in order to help and inspire other actors in the industry to transition to the Circular Economy.

Circularity starts with the design process
When creating new styles, it is important to keep an end-of-life scenario in mind right from the beginning. As this will dictate what embellishments, prints, accessories can be used. If designers make it as easy as possible for the recycling process, it has the bigger chance to actually be feedstock again. In addition to this, it is important to develop business models that enable products to be used as long as possible, including repair, rental, resale, and sharing services.

Building and scaling sorting and recycling infrastructure is critical
In order to scale up circular garment production, there is a need for technological innovation and infrastructure development in end-of-use textiles collection, sorting, and the mechanical pre-processing of feedstock. Currently, much of the textiles sorting is done manually, and the available optical sorting and identification technologies are not able to identify garment layers, complex fibre blends, or which causes deviations in feedstock quality for fibre-to-fibre recycling. Feedstock preprocessing is a critical step in textile-to-textile recycling, but it is not well understood outside of the actors who actually implement it. This requires collaboration across the value chain, and it takes in-depth knowledge and skill to do it well. This is an area that needs more attention and stronger economic incentives as textile-to-textile recycling scales up.

Improving quality and availability of data is essential
There is still a significant lack of available data to support the shift towards a circular textiles industry. This is slowing down development of system level solutions and economic incentives for textile circulation. For example, quantities of textiles put on the market are often used as a proxy for quantities of post-consumer textiles, but available data is at least two years old and often incomplete. There can also be different textile waste figures at a national level that do not align, due to different methodologies or data years. This is seen in the Dutch 2018 Mass Balance study reports and 2020 Circular Textile Policy Monitoring Report, where there is a 20% difference between put on market figures and measured quantities of post-consumer textiles collected separately and present in mixed residual waste. With the exception of a few good studies such as Sorting for Circularity Europe and ReFashion’s latest characterization study, there is almost no reliable information about fibre composition in the post-consumer textile stream either. Textile-to-textile recyclers would benefit from better availability of more reliable data. Policy monitoring for Extended Producer Responsibility schemes should focus on standardising reporting requirements across Europe from post-consumer textile collection through their ultimate end point and incentivize digitization so that reporting can be automated, and high-quality textile data becomes available in near-real time.

The need for continuous research and development across the entire value chain
Overall, the New Cotton Project’s findings suggest that fabrics incorporating Infinna™ fibre offer a more sustainable alternative to traditional cotton and viscose fabrics, while maintaining similar performance and aesthetic qualities. This could have significant implications for the textile industry in terms of sustainability and lower impact production practices. However, the project also demonstrated that the scaling of fibre-to-fibre recycling will continue to require ongoing research and development across the entire value chain. For example, the need for research and development around sorting systems is crucial. Within the chemical recycling process, it is also important to ensure the high recovery rate and circulation of chemicals used to limit the environmental impact of the process. The manufacturing processes also highlighted the benefit for ongoing innovation in the processing method, requiring technologies and brands to work closely with manufacturers to support further development in the field.

Thinking beyond lower impact fibres
The New Cotton Project value chain third party verified LCA reveals that the cellulose carbamate fibre, and in particular when produced with a renewable electricity source, shows potential to lower environmental impacts compared to conventional cotton and viscose. Although, it's important to note that this comparison was made using average global datasets from Ecoinvent for cotton and viscose fibres, and there are variations in the environmental performance of primary fibres available on the market. However, the analysis also highlights the importance of the rest of the supply chain to reduce environmental impact. The findings show that even if we reduce the environmental impacts by using recycled fibres, there is still work to do in other life cycle stages. For example; garment quality and using the garment during their full life span are crucial for mitigating the environmental impacts per garment use.
          
Citizen engagement
The EU has identified culture as one of the key barriers to the adoption of the circular economy within Europe. An adidas quantitative consumer survey conducted across three key markets during the project revealed that there is still confusion around circularity in textiles, which has highlighted the importance of effective citizen communication and engagement activities.

Cohesive legislation
Legislation is a powerful tool for driving the adoption of more sustainable and circular practices in the textiles industry. With several pieces of incoming legislation within the EU alone, the need for a cohesive and harmonised approach is essential to the successful implementation of policy within the textiles industry. Considering the link between different pieces of legislation such as Extended Producer Responsibility and the Ecodesign for Sustainable Products Regulation, along with their corresponding timeline for implementation will support stakeholders from across the value chain to prepare effectively for adoption of these new regulations.

The high, and continuously growing demand for recycled materials implies that all possible end-of-use textiles must be collected and sorted. Both mechanical and chemical recycling solutions are needed to meet the demand. We should also implement effectively both paths; closed-loop (fibre-to-fibre) and open -loop recycling (fibre to other sectors). There is a critical need to reconsider the export of low-quality reusable textiles outside the EU. It would be more advantageous to reuse them in Europe, or if they are at the end of their lifetime recycle these textiles within the European internal market rather than exporting them to countries where demand is often unverified and waste management inadequate.

Overall, the learnings spotlight the need for a holistic approach and a fundamental mindset shift in ways of working for the textiles industry. Deeper collaboration and knowledge exchange is central to developing effective circular value chains, helping to support the scaling of innovative recycling technologies and increase availability of recycled fibres on the market. The further development and scaling of collecting and sorting, along with the need to address substantial gaps in the availability of quality textile flow data should be urgently prioritised. The New Cotton Project has also demonstrated the potential of recycled fibres such as Infinna™ to offer a more sustainable option to some other traditional fibres, but at the same time highlights the importance of addressing the whole value chain holistically to make greater gains in lowering environmental impact. Ongoing research and development across the entire value chain is also essential to ensure we can deliver recycled fabrics at scale in the future.

The New Cotton Project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 101000559.

 

Source:

Fashion for Good

Image: Udo Jandrey
22.03.2024

New model for sustainable structures of textile-reinforced concrete

By reinforcing concrete with textiles instead of steel, it is possible to use less material and create slender, lightweight structures with a significantly lower environmental impact. The technology to utilise carbon fibre textiles already exists, but it has been challenging, among other things, to produce a basis for reliable calculations for complex and vaulted structures. Researchers from Chalmers University of Technology, in Sweden, are now presenting a method that makes it easier to scale up analyses and thus facilitate the construction of more environmentally friendly bridges, tunnels and buildings.

By reinforcing concrete with textiles instead of steel, it is possible to use less material and create slender, lightweight structures with a significantly lower environmental impact. The technology to utilise carbon fibre textiles already exists, but it has been challenging, among other things, to produce a basis for reliable calculations for complex and vaulted structures. Researchers from Chalmers University of Technology, in Sweden, are now presenting a method that makes it easier to scale up analyses and thus facilitate the construction of more environmentally friendly bridges, tunnels and buildings.

"A great deal of the concrete we use today has the function to act as a protective layer to prevent the steel reinforcement from corroding. If we can use textile reinforcement instead, we can reduce cement consumption and also use less concrete − and thus reduce the climate impact," says Karin Lundgren, who is Professor in Concrete Structures at the Department of Architecture and Civil Engineering at Chalmers.

Cement is a binder in concrete and its production from limestone has a large impact on the climate. One of the problems is that large amounts of carbon dioxide that have been sequestered in the limestone are released during production. Every year, about 4.5 billion tonnes of cement are produced in the world and the cement industry accounts for about 8 percent of global carbon dioxide emissions. Intensive work is therefore underway to find alternative methods and materials for concrete structures.

Reduced carbon footprint with thinner constructions and alternative binders
By using alternative binders instead of cement, such as clay or volcanic ash, it is possible to further reduce carbon dioxide emissions. But so far, it is unclear how well such new binders can protect steel reinforcement in the long term.

"You could get away from the issue of corrosion protection, by using carbon-fibres as reinforcement material instead of steel, because it doesn't need to be protected in the same way. You can also gain even more by optimising thin shell structures with a lower climate impact," says Karin Lundgren.

In a recently published study in the journal Construction and Building Materials, Karin Lundgren and her colleagues describe a new modelling technique that was proved to be reliable in analyses describing how textile reinforcement interacts with concrete.

"What we have done is to develop a method that facilitates the calculation work of complex structures and reduces the need for testing of the load-bearing capacity," says Karin Lundgren.

One area where textile reinforcement technology could significantly reduce the environmental impact is in the construction of arched floors. Since the majority of a building’s climate impact during production comes from the floor structures, it is an effective way to build more sustainably. A previous research study from the University of Cambridge shows that textile reinforcement can reduce carbon dioxide emissions by up to 65 percent compared to traditional solid floors.

Method that facilitates calculations
A textile reinforcement mesh consists of yarns, where each yarn consists of thousands of thin filaments (long continuous fibres). The reinforcement mesh is cast into concrete, and when the textile-reinforced concrete is loaded, the filaments slip both against the concrete and against each other inside the yarn. A textile yarn in concrete does not behave as a unit, which is important when you want to understand the composite material's ability to carry loads. The modelling technique developed by the Chalmers researchers describes these effects.

"You could describe it as the yarn consisting of an inner and an outer core, which is affected to varying degrees when the concrete is loaded. We developed a test and calculation method that describes this interaction. In experiments, we were able to show that our way of calculating is reliable enough even for complex structures," says Karin Lundgren.

The work together with colleagues is now continuing to develop optimisation methods for larger structures.

"Given that the United Nations Environment Programme (UNEP) expects the total floor area in the world to double over the next 40 years due to increased prosperity and population growth, we must do everything we can to build as resource-efficiently as possible to meet the climate challenge," says Karin Lundgren.

Source:

Chalmers | Mia Halleröd Palmgren

Empa researcher Simon Annaheim is working to develop a mattress for newborn babies. Image: Empa
11.03.2024

Medical textiles and sensors: Smart protection for delicate skin

Skin injuries caused by prolonged pressure often occur in people who are unable to change their position independently – such as sick newborns in hospitals or elderly people. Thanks to successful partnerships with industry and research, Empa scientists are now launching two smart solutions for pressure sores.

If too much pressure is applied to our skin over a long period of time, it becomes damaged. Populations at high risk of such pressure injuries include people in wheelchairs, newborns in intensive care units and the elderly. The consequences are wounds, infections and pain.

Skin injuries caused by prolonged pressure often occur in people who are unable to change their position independently – such as sick newborns in hospitals or elderly people. Thanks to successful partnerships with industry and research, Empa scientists are now launching two smart solutions for pressure sores.

If too much pressure is applied to our skin over a long period of time, it becomes damaged. Populations at high risk of such pressure injuries include people in wheelchairs, newborns in intensive care units and the elderly. The consequences are wounds, infections and pain.

Treatment is complex and expensive: Healthcare costs of around 300 million Swiss francs are incurred every year. "In addition, existing illnesses can be exacerbated by such pressure injuries," says Empa researcher Simon Annaheim from the Biomimetic Membranes and Textiles laboratory in St. Gallen. According to Annaheim, it would be more sustainable to prevent tissue damage from occurring in the first place. Two current research projects involving Empa researchers are now advancing solutions: A pressure-equalizing mattress for newborns in intensive care units and a textile sensor system for paraplegics and bedridden people are being developed.

Optimally nestled at the start of life
The demands of our skin are completely different depending on age: In adults, the friction of the skin on the lying surface, physical shear forces in the tissue and the lack of breathability of textiles are the main risk factors. In contrast, the skin of newborns receiving intensive care is extremely sensitive per se, and any loss of fluid and heat through the skin can become a problem. "While these particularly vulnerable babies are being nursed back to health, the lying situation should not cause any additional complications," says Annaheim. He thinks conventional mattresses are not appropriate for newborns with very different weights and various illnesses. Annaheim's team is therefore working with researchers from ETH Zurich, the Zurich University of Applied Sciences (ZHAW) and the University Children's Hospital Zurich to find an optimal lying surface for babies' delicate skin. This mattress should be able to adapt individually to the body in order to help children with a difficult start in life.

In order to do this, the researchers first determined the pressure conditions in the various regions of the newborn's body. "Our pressure sensors showed that the head, shoulders and lower spine are the areas with the greatest risk of pressure sores," says Annaheim. These findings were incorporated into the development of a special kind of air-filled mattress: With the help of pressure sensors and a microprocessor, its three chambers can be filled precisely via an electronic pump so that the pressure in the respective areas is minimized. An infrared laser process developed at Empa made it possible to produce the mattress from a flexible, multi-layered polymer membrane that is gentle on the skin and has no irritating seams.

After a multi-stage development process in the laboratory, the first small patients were allowed to lie on the prototype mattress. The effect was immediately noticeable when the researchers filled the mattress with air to varying degrees depending on the individual needs of the babies: Compared to a conventional foam mattress, the prototype reduced the pressure on the vulnerable parts of the body by up to 40 percent.

Following this successful pilot study, the prototype is now being optimized in the Empa labs. Simon Annaheim and doctoral student Tino Jucker will soon be starting a larger-scale study with the new mattress with the Department of Intensive Care Medicine & Neonatology at University Children's Hospital Zurich.

Intelligent sensors prevent injuries
In another project, Empa researchers are working on preventing so-called pressure ulcer tissue damage in adults. This involves converting the risk factors of pressure and circulatory disorders into helpful warning signals.

If you lie in the same position for a long time, pressure and circulatory problems lead to an undersupply of oxygen to the tissue. While the lack of oxygen triggers a reflex to move in healthy people, this neurological feedback loop can be disrupted in people with paraplegia or coma patients, for example. Here, smart sensors can help to provide early warning of the risk of tissue damage.

In the ProTex project, a team of researchers from Empa, the University of Bern, the OST University of Applied Sciences and Bischoff Textil AG in St. Gallen has developed a sensor system made of smart textiles with associated data analysis in real time. "The skin-compatible textile sensors contain two different functional polymer fibers," says Luciano Boesel from Empa's Biomimetic Membranes and Textiles laboratory in St. Gallen. In addition to pressure-sensitive fibers, the researchers integrated light-conducting polymer fibers (POFs), which are used to measure oxygen. "As soon as the oxygen content in the skin drops, the highly sensitive sensor system signals an increasing risk of tissue damage," explains Boesel. The data is then transmitted directly to the patient or to the nursing staff. This means, for instance, that a lying person can be repositioned in good time before the tissue is damaged.

Patented technology
The technology behind this also includes a novel microfluidic wet spinning process developed at Empa for the production of POFs. It allows precise control of the polymer components in the micrometer range and smoother, more environmentally friendly processing of the fibers. The microfluidic process is one of three patents that have emerged from the ProTex project to date.

Another product is a breathable textile sensor that is worn directly on the skin. The spin-off Sensawear in Bern, which emerged from the project in 2023, is currently pushing ahead with the market launch. Empa researcher Boesel is also convinced: "The findings and technologies from ProTex will enable further applications in the field of wearable sensor technology and smart clothing in the future."

Source:

Dr. Andrea Six, Empa

Photo: guentherlig, Pixabay
01.03.2024

The most tasteful kind of coating

Tiny external structures in the wax coating of blueberries give them their blue colour, researchers at the University of Bristol can reveal. This applies to lots of fruits that are the same colour including damsons, sloes and juniper berries.

In the study, published in Science Advances, researchers show why blueberries are blue despite the dark red colour of the pigments in the fruit skin. Their blue colour is instead provided by a layer of wax that surrounds the fruit which is made up of miniature structures that scatter blue and UV light. This gives blueberries their blue appearance to humans and blue-UV to birds. The chromatic blue-UV reflectance arises from the interaction of the randomly arranged crystal structures of the epicuticular wax with light.

Tiny external structures in the wax coating of blueberries give them their blue colour, researchers at the University of Bristol can reveal. This applies to lots of fruits that are the same colour including damsons, sloes and juniper berries.

In the study, published in Science Advances, researchers show why blueberries are blue despite the dark red colour of the pigments in the fruit skin. Their blue colour is instead provided by a layer of wax that surrounds the fruit which is made up of miniature structures that scatter blue and UV light. This gives blueberries their blue appearance to humans and blue-UV to birds. The chromatic blue-UV reflectance arises from the interaction of the randomly arranged crystal structures of the epicuticular wax with light.

Rox Middleton, Research Fellow at Bristol’s School of Biological Sciences, explained: “The blue of blueberries can’t be ‘extracted’ by squishing – because it isn’t located in the pigmented juice that can be squeezed from the fruit. That was why we knew that there must be something strange about the colour.

“So we removed the wax and re-crystallised it on card and in doing so we were able to create a brand new blue-UV coating.”

The ultra-thin colourant is around two microns thick, and although less reflective, it’s visibly blue and reflects UV well, possibly paving the way for new colorant methods.

“It shows that nature has evolved to use a really neat trick, an ultrathin layer for an important colorant," added Rox.

Most plants are coated in a thin layer of wax which has multiple functions, many of them that scientists still don’t understand. They know that it can be very effective as a hydrophobic, self-cleaning coating.

However until now, researchers did not know how important the structure was for visible colouration.

Now the team plan to look at easier ways of recreating the coating and applying it. This could lead to a more sustainable, biocompatible and even edible UV and blue-reflective paint.

Furthermore these coatings could have the same multiple functions as natural biological ones that protect plants.

Rox added: “It was really interesting to find that there was an unknown coloration mechanism right under our noses, on popular fruits that we grow and eat all the time.

“It was even more exciting to be able to reproduce that colour by harvesting the wax to make a new blue coating that no-one’s seen before.

“Building all that functionality of this natural wax into artificially engineered materials is the dream!”

Source:

Bristol University

Paper: ‘Self-assembled, Disordered Structural Colour from Fruit Wax Bloom’ by Rox Middleton et al in Science Advances.

(c) RMIT University
26.02.2024

Cooling down with Nanodiamonds

Researchers from RMIT University are using nanodiamonds to create smart textiles that can cool people down faster.

The study found fabric made from cotton coated with nanodiamonds, using a method called electrospinning, showed a reduction of 2-3 degrees Celsius during the cooling down process compared to untreated cotton. They do this by drawing out body heat and releasing it from the fabric – a result of the incredible thermal conductivity of nanodiamonds.

Published in Polymers for Advanced Technologies, project lead and Senior Lecturer, Dr Shadi Houshyar, said there was a big opportunity to use these insights to create new textiles for sportswear and even personal protective clothing, such as underlayers to keep fire fighters cool.

The study also found nanodiamonds increased the UV protection of cotton, making it ideal for outdoor summer clothing.

Researchers from RMIT University are using nanodiamonds to create smart textiles that can cool people down faster.

The study found fabric made from cotton coated with nanodiamonds, using a method called electrospinning, showed a reduction of 2-3 degrees Celsius during the cooling down process compared to untreated cotton. They do this by drawing out body heat and releasing it from the fabric – a result of the incredible thermal conductivity of nanodiamonds.

Published in Polymers for Advanced Technologies, project lead and Senior Lecturer, Dr Shadi Houshyar, said there was a big opportunity to use these insights to create new textiles for sportswear and even personal protective clothing, such as underlayers to keep fire fighters cool.

The study also found nanodiamonds increased the UV protection of cotton, making it ideal for outdoor summer clothing.

“While 2 or 3 degrees may not seem like much of a change, it does make a difference in comfort and health impacts over extended periods and in practical terms, could be the difference between keeping your air conditioner off or turning it on,” Houshyar said. “There’s also potential to explore how nanodiamonds can be used to protect buildings from overheating, which can lead to environmental benefits.”

The use of this fabric in clothing was projected to lead to a 20-30% energy saving due to lower use of air conditioning.

Based in the Centre for Materials Innovation and Future Fashion (CMIFF), the research team is made up of RMIT engineers and textile researchers who have strong expertise in developing next-generation smart textiles, as well as working with industry to develop realistic solutions.

Contrary to popular belief, nanodiamonds are not the same as the diamonds that adorn jewellery, said Houshyar. “They’re actually cheap to make — cheaper than graphene oxide and other types of carbon materials,” she said. “While they have a carbon lattice structure, they are much smaller in size. They’re also easy to make using methods like detonation or from waste materials.”

How it works
Cotton material was first coated with an adhesive, then electrospun with a polymer solution made from nanodiamonds, polyurethane and solvent.

This process creates a web of nanofibres on the cotton fibres, which are then cured to bond the two.

Lead researcher and research assistant, Dr Aisha Rehman, said the coating with nanodiamonds was deliberately applied to only one side of the fabric to restrict heat in the atmosphere from transferring back to the body.  

“The side of the fabric with the nanodiamond coating is what touches the skin. The nanodiamonds then transfer heat from the body into the air,” said Rehman, who worked on the study as part of her PhD. “Because nanodiamonds are such good thermal conductors, it does it faster than untreated fabric.”

Nanodiamonds were chosen for this study because of their strong thermal conductivity properties, said Rehman. Often used in IT, nanodiamonds can also help improve thermal properties of liquids and gels, as well as increase corrosive resistance in metals.

“Nanodiamonds are also biocompatible, so they’re safe for the human body. Therefore, it has great potential not just in textiles, but also in the biomedical field,” Rehman said.

While the research was still preliminary, Houshyar said this method of coating nanofibres onto textiles had strong commercial potential.
 
“This electrospinning approach is straightforward and can significantly reduce the variety of manufacturing steps compared to previously tested methods, which feature lengthy processes and wastage of nanodiamonds,” Houshyar said.

Further research will study the durability of the nanofibres, especially during the washing process.

Source:

Shu Shu Zheng, RMIT University

Wearable Robots for Parkinson’s Disease Image: Tom Claes, unsplash
19.02.2024

Wearable Robots for Parkinson’s Disease

Freezing is one of the most common and debilitating symptoms of Parkinson’s disease, a neurodegenerative disorder that affects more than 9 million people worldwide. When individuals with Parkinson’s disease freeze, they suddenly lose the ability to move their feet, often mid-stride, resulting in a series of staccato stutter steps that get shorter until the person stops altogether. These episodes are one of the biggest contributors to falls among people living with Parkinson’s disease.

Today, freezing is treated with a range of pharmacological, surgical or behavioral therapies, none of which are particularly effective. What if there was a way to stop freezing altogether?

Freezing is one of the most common and debilitating symptoms of Parkinson’s disease, a neurodegenerative disorder that affects more than 9 million people worldwide. When individuals with Parkinson’s disease freeze, they suddenly lose the ability to move their feet, often mid-stride, resulting in a series of staccato stutter steps that get shorter until the person stops altogether. These episodes are one of the biggest contributors to falls among people living with Parkinson’s disease.

Today, freezing is treated with a range of pharmacological, surgical or behavioral therapies, none of which are particularly effective. What if there was a way to stop freezing altogether?

Researchers from the Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS) and the Boston University Sargent College of Health & Rehabilitation Sciences have used a soft, wearable robot to help a person living with Parkinson’s walk without freezing. The robotic garment, worn around the hips and thighs, gives a gentle push to the hips as the leg swings, helping the patient achieve a longer stride.

The device completely eliminated the participant’s freezing while walking indoors, allowing them to walk faster and further than they could without the garment’s help.

“We found that just a small amount of mechanical assistance from our soft robotic apparel delivered instan-taneous effects and consistently improved walking across a range of conditions for the individual in our study,” said Conor Walsh, the Paul A. Maeder Professor of Engineering and Applied Sciences at SEAS and co-corresponding author of the study.

The research demonstrates the potential of soft robotics to treat this frustrating and potentially dangerous symptom of Parkinson’s disease and could allow people living with the disease to regain not only their mobility but their independence.

For over a decade, Walsh’s Biodesign Lab at SEAS has been developing assistive and rehabilitative robotic technologies to improve mobility for individuals’ post-stroke and those living with ALS or other diseases that impact mobility. Some of that technology, specifically an exosuit for post-stroke gait retraining, received support from the Wyss Institute for Biologically Inspired Engineering, and Harvard’s Office of Technology Development coordinated a license agreement with ReWalk Robotics to commercialize the technology.

In 2022, SEAS and Sargent College received a grant from the Massachusetts Technology Collaborative to support the development and translation of next-generation robotics and wearable technologies. The research is centered at the Move Lab, whose mission is to support advances in human performance enhancement with the collaborative space, funding, R&D infrastructure, and experience necessary to turn promising research into mature technologies that can be translated through collaboration with industry partners. This research emerged from that partnership.

“Leveraging soft wearable robots to prevent freezing of gait in patients with Parkinson’s required a collaboration between engineers, rehabilitation scientists, physical therapists, biomechanists and apparel designers,” said Walsh, whose team collaborated closely with that of Terry Ellis,  Professor and Physical Therapy Department Chair and Director of the Center for Neurorehabilitation at Boston University.

Leveraging soft wearable robots to prevent freezing of gait in patients with Parkinson’s required a collaboration between engineers, rehabilitation scientists, physical therapists, biomechanists and apparel designers.

The team spent six months working with a 73-year-old man with Parkinson’s disease, who — despite using both surgical and pharmacologic treatments — endured substantial and incapacitating freezing episodes more than 10 times a day, causing him to fall frequently. These episodes prevented him from walking around his community and forced him to rely on a scooter to get around outside.

In previous research, Walsh and his team leveraged human-in-the-loop optimization to demonstrate that a soft, wearable device could be used to augment hip flexion and assist in swinging the leg forward to provide an efficient approach to reduce energy expenditure during walking in healthy individuals.

Here, the researchers used the same approach but to address freezing. The wearable device uses cable-driven actuators and sensors worn around the waist and thighs. Using motion data collected by the sensors, algorithms estimate the phase of the gait and generate assistive forces in tandem with muscle movement.

The effect was instantaneous. Without any special training, the patient was able to walk without any freezing indoors and with only occasional episodes outdoors. He was also able to walk and talk without freezing, a rarity without the device.

“Our team was really excited to see the impact of the technology on the participant’s walking,” said Jinsoo Kim, former PhD student at SEAS and co-lead author on the study.

During the study visits, the participant told researchers: “The suit helps me take longer steps and when it is not active, I notice I drag my feet much more. It has really helped me, and I feel it is a positive step forward. It could help me to walk longer and maintain the quality of my life.”

“Our study participants who volunteer their time are real partners,” said Walsh. “Because mobility is difficult, it was a real challenge for this individual to even come into the lab, but we benefited so much from his perspective and feedback.”

The device could also be used to better understand the mechanisms of gait freezing, which is poorly understood.

“Because we don’t really understand freezing, we don’t really know why this approach works so well,” said Ellis. “But this work suggests the potential benefits of a ’bottom-up’ rather than ’top-down’ solution to treating gait freezing. We see that restoring almost-normal biomechanics alters the peripheral dynamics of gait and may influence the central processing of gait control.”

The research was co-authored by Jinsoo Kim, Franchino Porciuncula, Hee Doo Yang, Nicholas Wendel, Teresa Baker and Andrew Chin. Asa Eckert-Erdheim and Dorothy Orzel also contributed to the design of the technology, as well as Ada Huang, and Sarah Sullivan managed the clinical research. It was supported by the National Science Foundation under grant CMMI-1925085; the National Institutes of Health under grant NIH U01 TR002775; and the Massachusetts Technology Collaborative, Collaborative Research and Development Matching Grant.

Source:

The research is published in Nature Medicine.
Source Leah Burrows
Harvard John A. Paulson. School of Engineering and Applied Sciences

Researchers led by Bernd Nowack have investigated the release of nanoparticles during the washing of polyester textiles. Image: Empa Image: Empa
14.02.2024

Release of oligomers from polyester textiles

When nanoplastics are not what they seem ... Textiles made of synthetic fibers release micro- and nanoplastics during washing. Empa researchers have now been able to show: Some of the supposed nanoplastics do not actually consist of plastic particles, but of water-insoluble oligomers. The effects they have on humans and the environment are not yet well-understood.

Plastic household items and clothing made of synthetic fibers release microplastics: particles less than five millimetres in size that can enter the environment unnoticed. A small proportion of these particles are so small that they are measured in nanometers. Such nanoplastics are the subject of intensive research, as nanoplastic particles can be absorbed into the human body due to their small size – but, as of today, little is known about their potential toxicity.

When nanoplastics are not what they seem ... Textiles made of synthetic fibers release micro- and nanoplastics during washing. Empa researchers have now been able to show: Some of the supposed nanoplastics do not actually consist of plastic particles, but of water-insoluble oligomers. The effects they have on humans and the environment are not yet well-understood.

Plastic household items and clothing made of synthetic fibers release microplastics: particles less than five millimetres in size that can enter the environment unnoticed. A small proportion of these particles are so small that they are measured in nanometers. Such nanoplastics are the subject of intensive research, as nanoplastic particles can be absorbed into the human body due to their small size – but, as of today, little is known about their potential toxicity.

Empa researchers from Bernd Nowack's group in the Technology and Society laboratory have now joined forces with colleagues from China to take a closer look at nanoparticles released from textiles. Tong Yang, first author of the study, carried out the investigations during his doctorate at Empa. In earlier studies, Empa researchers were already able to demonstrate that both micro- and nanoplastics are released when polyester is washed. A detailed examination of the released nanoparticles released has now shown that not everything that appears to be nanoplastic at first glance actually is nanoplastic.

To a considerable extent, the released particles were in fact not nanoplastics, but clumps of so-called oligomers, i.e. small to medium-sized molecules that represent an intermediate stage between the long-chained polymers and their individual building blocks, the monomers. These molecules are even smaller than nanoplastic particles, and hardly anything is known about their toxicity either. The researchers published their findings in the journal Nature Water.

For the study, the researchers examined twelve different polyester fabrics, including microfiber, satin and jersey. The fabric samples were washed up to four times and the nanoparticles released in the process were analyzed and characterized. Not an easy task, says Bernd Nowack. "Plastic, especially nanoplastics, is everywhere, including on our devices and utensils," says the scientist. "When measuring nanoplastics, we have to take this 'background noise' into account."

Large proportion of soluble particles
The researchers used an ethanol bath to distinguish nanoplastics from clumps of oligomers. Plastic pieces, no matter how small, do not dissolve in ethanol, but aggregations of oligomers do. The result: Around a third to almost 90 percent of the nanoparticles released during washing could be dissolved in ethanol. "This allowed us to show that not everything that looks like nanoplastics at first glance is in fact nanoplastics," says Nowack.

It is not yet clear whether the release of so-called nanoparticulate oligomers during the washing of textiles has negative effects on humans and the environment. "With other plastics, studies have already shown that nanoparticulate oligomers are more toxic than nanoplastics," says Nowack. "This is an indication that this should be investigated more closely." However, the researchers were able to establish that the nature of the textile and the cutting method – scissors or laser – have no major influence on the quantity of particles released.

The mechanism of release has not been clarified yet either – neither for nanoplastics nor for the oligomer particles. The good news is that the amount of particles released decreases significantly with repeated washes. It is conceivable that the oligomer particles are created during the manufacturing of the textile or split off from the fibers through chemical processes during storage. Further studies are also required in this area.

Nowack and his team are focusing on larger particles for the time being: In their next project, they want to investigate which fibers are released during washing of textiles made from renewable raw materials and whether these could be harmful to the environment and health. "Semi-synthetic textiles such as viscose or lyocell are being touted as a replacement for polyester," says Nowack. "But we don't yet know whether they are really better when it comes to releasing fibers."

Source:

Empa

Bacteria, eating Plastic and producing Multipurpose Spider Silk Photo: Kareni, Pixabay
05.02.2024

Bacteria, eating Plastic and producing Multipurpose Spider Silk

For the first time, researchers have used bacteria to “upcycle” waste polyethylene: Move over Spider-Man: Researchers at Rensselaer Polytechnic Institute have developed a strain of bacteria that can turn plastic waste into a biodegradable spider silk with multiple uses.

Their new study marks the first time scientists have used bacteria to transform polyethylene plastic — the kind used in many single-use items — into a high-value protein product.

That product, which the researchers call “bio-inspired spider silk” because of its similarity to the silk spiders use to spin their webs, has applications in textiles, cosmetics, and even medicine.

For the first time, researchers have used bacteria to “upcycle” waste polyethylene: Move over Spider-Man: Researchers at Rensselaer Polytechnic Institute have developed a strain of bacteria that can turn plastic waste into a biodegradable spider silk with multiple uses.

Their new study marks the first time scientists have used bacteria to transform polyethylene plastic — the kind used in many single-use items — into a high-value protein product.

That product, which the researchers call “bio-inspired spider silk” because of its similarity to the silk spiders use to spin their webs, has applications in textiles, cosmetics, and even medicine.

“Spider silk is nature’s Kevlar,” said Helen Zha, Ph.D., an assistant professor of chemical and biological engineering and one of the RPI researchers leading the project. “It can be nearly as strong as steel under tension. However, it’s six times less dense than steel, so it’s very lightweight. As a bioplastic, it’s stretchy, tough, nontoxic, and biodegradable.”

All those attributes make it a great material for a future where renewable resources and avoidance of persistent plastic pollution are the norm, Zha said.

Polyethylene plastic, found in products such as plastic bags, water bottles, and food packaging, is the biggest contributor to plastic pollution globally and can take upward of 1,000 years to degrade naturally. Only a small portion of polyethylene plastic is recycled, so the bacteria used in the study could help “upcycle” some of the remaining waste.

Pseudomonas aeruginosa, the bacteria used in the study, can naturally consume polyethylene as a food source. The RPI team tackled the challenge of engineering this bacteria to convert the carbon atoms of polyethylene into a genetically encoded silk protein. Surprisingly, they found that their newly developed bacteria could make the silk protein at a yield rivaling some bacteria strains that are more conventionally used in biomanufacturing.

The underlying biological process behind this innovation is something people have employed for millennia.

“Essentially, the bacteria are fermenting the plastic. Fermentation is used to make and preserve all sorts of foods, like cheese, bread, and wine, and in biochemical industries it’s used to make antibiotics, amino acids, and organic acids,” said Mattheos Koffas, Ph.D., Dorothy and Fred Chau ʼ71 Career Development Constellation Professor in Biocatalysis and Metabolic Engineering, and the other researcher leading the project, and who, along with Zha, is a member of the Center for Biotechnology and Interdisciplinary Studies at Rensselaer.

To get bacteria to ferment polyethylene, the plastic is first “predigested,” Zha said. Just like humans need to cut and chew our food into smaller pieces before our bodies can use it, the bacteria has difficulty eating the long molecule chains, or polymers, that comprise polyethylene.

In the study, Zha and Koffas collaborated with researchers at Argonne National Laboratory, who depolymerized the plastic by heating it under pressure, producing a soft, waxy substance. Next, the team put a layer of the plastic-derived wax on the bottoms of flasks, which served as the nutrient source for the bacteria culture. This contrasts with typical fermentation, which uses sugars as the nutrient source.

“It’s as if, instead of feeding the bacteria cake, we’re feeding it the candles on the cake,” Zha said.

Then, as a warming plate gently swirled the flasks’ contents, the bacteria went to work. After 72 hours, the scientists strained out the bacteria from the liquid culture, purified the silk protein, and freeze dried it. At that stage, the protein, which resembled torn up cotton balls, could potentially be spun into thread or made into other useful forms.

“What’s really exciting about this process is that, unlike the way plastics are produced today, our process is low energy and doesn’t require the use of toxic chemicals,” Zha said. “The best chemists in the world could not convert polyethylene into spider silk, but these bacteria can. We’re really harnessing what nature has developed to do manufacturing for us.”

However, before upcycled spider silk products become a reality, the researchers will first need to find ways to make the silk protein more efficiently.

“This study establishes that we can use these bacteria to convert plastic to spider silk. Our future work will investigate whether tweaking the bacteria or other aspects of the process will allow us to scale up production,” Koffas said.

“Professors Zha and Koffas represent the new generation of chemical and biological engineers merging biological engineering with materials science to manufacture ecofriendly products. Their work is a novel approach to protecting the environment and reducing our reliance on nonrenewable resources,” said Shekhar Garde, Ph.D., dean of RPI’s School of Engineering.

The study, which was conducted by first author Alexander Connor, who earned his doctorate from RPI in 2023, and co-authors Jessica Lamb and Massimiliano Delferro with Argonne National Laboratory, is published in the journal “Microbial Cell Factories.”

Source:

Samantha Murray, Rensselaer

Photo: Sibi Suku, unsplash
29.01.2024

Naturalistic silk spun from artificial spider gland

Researchers led by Keiji Numata at the RIKEN Center for Sustainable Resource Science in Japan, along with colleagues from the RIKEN Pioneering Research Cluster, have succeeded in creating a device that spins artificial spider silk that closely matches what spiders naturally produce. The artificial silk gland was able to re-create the complex molecular structure of silk by mimicking the various chemical and physical changes that naturally occur in a spider’s silk gland. This eco-friendly innovation is a big step towards sustainability and could impact several industries. This study was published January 15 in the scientific journal Nature Communications.

Researchers led by Keiji Numata at the RIKEN Center for Sustainable Resource Science in Japan, along with colleagues from the RIKEN Pioneering Research Cluster, have succeeded in creating a device that spins artificial spider silk that closely matches what spiders naturally produce. The artificial silk gland was able to re-create the complex molecular structure of silk by mimicking the various chemical and physical changes that naturally occur in a spider’s silk gland. This eco-friendly innovation is a big step towards sustainability and could impact several industries. This study was published January 15 in the scientific journal Nature Communications.

Famous for its strength, flexibility, and light weight, spider silk has a tensile strength that is comparable to steel of the same diameter, and a strength to weight ratio that is unparalleled. Added to that, it’s biocompatible, meaning that it can be used in medical applications, as well as biodegradable. So why isn’t everything made from spider silk? Large-scale harvesting of silk from spiders has proven impractical for several reasons, leaving it up to scientists to develop a way to produce it in the laboratory.

Spider silk is a biopolymer fiber made from large proteins with highly repetitive sequences, called spidroins. Within the silk fibers are molecular substructures called beta sheets, which must be aligned properly for the silk fibers to have their unique mechanical properties. Re-creating this complex molecular architecture has confounded scientists for years. Rather than trying to devise the process from scratch, RIKEN scientists took a biomimicry approach. As Numata explains, “in this study, we attempted to mimic natural spider silk production using microfluidics, which involves the flow and manipulation of small amounts of fluids through narrow channels. Indeed, one could say that that the spider’s silk gland functions as a sort of natural microfluidic device.”

The device developed by the researchers looks like a small rectangular box with tiny channels grooved into it. Precursor spidroin solution is placed at one end and then pulled towards the other end by means of negative pressure. As the spidroins flow through the microfluidic channels, they are exposed to precise changes in the chemical and physical environment, which are made possible by the design of the microfluidic system. Under the correct conditions, the proteins self-assembled into silk fibers with their characteristic complex structure.

The researchers experimented to find these correct conditions, and eventually were able to optimize the interactions among the different regions of the microfluidic system. Among other things, they discovered that using force to push the proteins through did not work; only when they used negative pressure to pull the spidroin solution could continuous silk fibers with the correct telltale alignment of beta sheets be assembled.

“It was surprising how robust the microfluidic system was, once the different conditions were established and optimized,” says Senior Scientist Ali Malay, one of the paper’s co-authors. “Fiber assembly was spontaneous, extremely rapid, and highly reproducible. Importantly, the fibers exhibited the distinct hierarchical structure that is found in natural silk fiber.”

The ability to artificially produce silk fibers using this method could provide numerous benefits. Not only could it help reduce the negative impact that current textile manufacturing has on the environment, but the biodegradable and biocompatible nature of spider silk makes it ideal for biomedical applications, such as sutures and artificial ligaments.

“Ideally, we want to have a real-world impact,” says Numata. “For this to occur, we will need to scale-up our fiber-production methodology and make it a continuous process. We will also evaluate the quality of our artificial spider silk using several metrics and make further improvements from there.”

Source:

RIKEN Center for Sustainable Resource Science, Japan

Converting CO2 to Solid Carbon Nanofibers (c) Zhenhua Xie/Brookhaven National Laboratory and Columbia University; Erwei Huang/Brookhaven National Laboratory
22.01.2024

Converting CO2 to Solid Carbon Nanofibers

Tandem electrocatalytic-thermocatalytic conversion could help offset emissions of potent greenhouse gas by locking carbon away in a useful material.

Scientists at the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory and Columbia University have developed a way to convert carbon dioxide (CO2), a potent greenhouse gas, into carbon nanofibers, materials with a wide range of unique properties and many potential long-term uses. Their strategy uses tandem electrochemical and thermochemical reactions run at relatively low temperatures and ambient pressure. As the scientists describe in the journal Nature Catalysis, this approach could successfully lock carbon away in a useful solid form to offset or even achieve negative carbon emissions.

Tandem electrocatalytic-thermocatalytic conversion could help offset emissions of potent greenhouse gas by locking carbon away in a useful material.

Scientists at the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory and Columbia University have developed a way to convert carbon dioxide (CO2), a potent greenhouse gas, into carbon nanofibers, materials with a wide range of unique properties and many potential long-term uses. Their strategy uses tandem electrochemical and thermochemical reactions run at relatively low temperatures and ambient pressure. As the scientists describe in the journal Nature Catalysis, this approach could successfully lock carbon away in a useful solid form to offset or even achieve negative carbon emissions.

“You can put the carbon nanofibers into cement to strengthen the cement,” said Jingguang Chen, a professor of chemical engineering at Columbia with a joint appointment at Brookhaven Lab who led the research. “That would lock the carbon away in concrete for at least 50 years, potentially longer. By then, the world should be shifted to primarily renewable energy sources that don’t emit carbon.”

As a bonus, the process also produces hydrogen gas (H2), a promising alternative fuel that, when used, creates zero emissions.

Capturing or converting carbon?
The idea of capturing CO2 or converting it to other materials to combat climate change is not new. But simply storing CO2 gas can lead to leaks. And many CO2 conversions produce carbon-based chemicals or fuels that are used right away, which releases CO2 right back into the atmosphere.

“The novelty of this work is that we are trying to convert CO2 into something that is value-added but in a solid, useful form,” Chen said.

Such solid carbon materials—including carbon nanotubes and nanofibers with dimensions measuring billionths of a meter—have many appealing properties, including strength and thermal and electrical conductivity. But it’s no simple matter to extract carbon from carbon dioxide and get it to assemble into these fine-scale structures. One direct, heat-driven process requires temperatures in excess of 1,000 degrees Celsius.

“It’s very unrealistic for large-scale CO2 mitigation,” Chen said. “In contrast, we found a process that can occur at about 400 degrees Celsius, which is a much more practical, industrially achievable temperature.”

The tandem two-step
The trick was to break the reaction into stages and to use two different types of catalysts—materials that make it easier for molecules to come together and react.

“If you decouple the reaction into several sub-reaction steps you can consider using different kinds of energy input and catalysts to make each part of the reaction work,” said Brookhaven Lab and Columbia research scientist Zhenhua Xie, lead author on the paper.

The scientists started by realizing that carbon monoxide (CO) is a much better starting material than CO2 for making carbon nanofibers (CNF). Then they backtracked to find the most efficient way to generate CO from CO2.

Earlier work from their group steered them to use a commercially available electrocatalyst made of palladium supported on carbon. Electrocatalysts drive chemical reactions using an electric current. In the presence of flowing electrons and protons, the catalyst splits both CO2 and water (H2O) into CO and H2.

For the second step, the scientists turned to a heat-activated thermocatalyst made of an iron-cobalt alloy. It operates at temperatures around 400 degrees Celsius, significantly milder than a direct CO2-to-CNF conversion would require. They also discovered that adding a bit of extra metallic cobalt greatly enhances the formation of the carbon nanofibers.

“By coupling electrocatalysis and thermocatalysis, we are using this tandem process to achieve things that cannot be achieved by either process alone,” Chen said.

Catalyst characterization
To discover the details of how these catalysts operate, the scientists conducted a wide range of experiments. These included computational modeling studies, physical and chemical characterization studies at Brookhaven Lab’s National Synchrotron Light Source II (NSLS-II)—using the Quick X-ray Absorption and Scattering (QAS) and Inner-Shell Spectroscopy (ISS) beamlines—and microscopic imaging at the Electron Microscopy facility at the Lab’s Center for Functional Nanomaterials (CFN).

On the modeling front, the scientists used “density functional theory” (DFT) calculations to analyze the atomic arrangements and other characteristics of the catalysts when interacting with the active chemical environment.

“We are looking at the structures to determine what are the stable phases of the catalyst under reaction conditions,” explained study co-author Ping Liu of Brookhaven’s Chemistry Division who led these calculations. “We are looking at active sites and how these sites are bonding with the reaction intermediates. By determining the barriers, or transition states, from one step to another, we learn exactly how the catalyst is functioning during the reaction.”

X-ray diffraction and x-ray absorption experiments at NSLS-II tracked how the catalysts change physically and chemically during the reactions. For example, synchrotron x-rays revealed how the presence of electric current transforms metallic palladium in the catalyst into palladium hydride, a metal that is key to producing both H2 and CO in the first reaction stage.

For the second stage, “We wanted to know what’s the structure of the iron-cobalt system under reaction conditions and how to optimize the iron-cobalt catalyst,” Xie said. The x-ray experiments confirmed that both an alloy of iron and cobalt plus some extra metallic cobalt are present and needed to convert CO to carbon nanofibers.

“The two work together sequentially,” said Liu, whose DFT calculations helped explain the process.

“According to our study, the cobalt-iron sites in the alloy help to break the C-O bonds of carbon monoxide. That makes atomic carbon available to serve as the source for building carbon nanofibers. Then the extra cobalt is there to facilitate the formation of the C-C bonds that link up the carbon atoms,” she explained.

Recycle-ready, carbon-negative
“Transmission electron microscopy (TEM) analysis conducted at CFN revealed the morphologies, crystal structures, and elemental distributions within the carbon nanofibers both with and without catalysts,” said CFN scientist and study co-author Sooyeon Hwang.

The images show that, as the carbon nanofibers grow, the catalyst gets pushed up and away from the surface. That makes it easy to recycle the catalytic metal, Chen said.

“We use acid to leach the metal out without destroying the carbon nanofiber so we can concentrate the metals and recycle them to be used as a catalyst again,” he said.

This ease of catalyst recycling, commercial availability of the catalysts, and relatively mild reaction conditions for the second reaction all contribute to a favorable assessment of the energy and other costs associated with the process, the researchers said.

“For practical applications, both are really important—the CO2 footprint analysis and the recyclability of the catalyst,” said Chen. “Our technical results and these other analyses show that this tandem strategy opens a door for decarbonizing CO2 into valuable solid carbon products while producing renewable H2.”

If these processes are driven by renewable energy, the results would be truly carbon-negative, opening new opportunities for CO2 mitigation.

Source:

Brookhaven National Laboratory

Better Manufacturing Method for Wound Closures (c) Wilson College of Textiles
03.01.2024

Better Manufacturing Method for Wound Closures

If you’ve ever gotten stitches or had surgery, you may have had a suture. They’re the threads used to close wounds or join tissues together for other purposes.

But did you know that there are different types of sutures which can have an effect on your experience at the doctor or surgeon’s office?

Barbed sutures, for example, can reduce the amount of time you spend on the operating table and lower the likelihood of surgical complications. That type of suture has its roots in the Triangle and is being advanced by students and faculty at the Wilson College of Textiles.

Dr. Gregory Ruff, a nationally-renowned plastic surgeon, first invented the innovative closure in 1991, just down the road in Chapel Hill, North Carolina.

“I was thinking about the fact that we sew wounds together with a loop and a knot and if you tie it too tight, it can constrict the circulation and kill the tissue in that loop,” Dr. Ruff remembers.

If you’ve ever gotten stitches or had surgery, you may have had a suture. They’re the threads used to close wounds or join tissues together for other purposes.

But did you know that there are different types of sutures which can have an effect on your experience at the doctor or surgeon’s office?

Barbed sutures, for example, can reduce the amount of time you spend on the operating table and lower the likelihood of surgical complications. That type of suture has its roots in the Triangle and is being advanced by students and faculty at the Wilson College of Textiles.

Dr. Gregory Ruff, a nationally-renowned plastic surgeon, first invented the innovative closure in 1991, just down the road in Chapel Hill, North Carolina.

“I was thinking about the fact that we sew wounds together with a loop and a knot and if you tie it too tight, it can constrict the circulation and kill the tissue in that loop,” Dr. Ruff remembers.

“I was thinking about animals, and a porcupine’s quill came to mind. And the aha moment was, ‘What if we put a quill on one side of the wound and another one on the other side of the wound, so there’s no loop: the barbs go in but they don’t come out?’”

As the name suggests, barbed sutures have small projections shooting out of them that can latch onto tissues: think about barbed wire or a fishing hook. Those “quills,” or barbs, allow the suture to self-anchor. Since no knot is needed to secure the suture, the closure is faster, and the lack of knots and constricting loops promotes healing. This also allows surgeons to schedule more surgeries.

Soon after his aha moment, Dr. Ruff started his own company, Quill Medical, to fabricate these barbed sutures. While he had the medical expertise and a solid business partner, Dr. Ruff was looking for someone who could advise him in terms of the material makeup of the suture. The Wilson College’s Biomedical Textile Research Group, under the direction of Professor Martin King, quickly proved to be the perfect partner.

Using the Wilson College’s labs, King’s graduate students conducted a number of tests on Ruff’s sutures across different types of tissues (such as skin, muscle, etc.). One of those students, Nilesh Ingle, found that the barbed sutures worked best when the angles of the barbs were tailored specifically to the type of tissue being sutured.

Years later, one of King’s current graduate students is building on that research insight.
 
Understanding challenges and innovating solutions
Nearly three decades after the barbed suture’s invention, the majority of surgeons still use conventional sutures despite the advantages documented by researchers and surgeons. Why?

Karuna Nambi Gowri, a fiber and polymer science doctoral student in King’s research group, says it comes down to two reasons. The first of these is resistance to change. Most practicing surgeons learned how to use a suture before barbed sutures became more broadly available.

The second obstacle to the use of barbed sutures is procuring them. Barbed sutures tend to be both expensive and low in supply. That’s because the current process for making them (mechanical and blade-based) is inefficient in terms of both time and resources.

That’s where Nambi Gowri’s research with the Wilson College’s Biomedical Textiles Research Group comes in. She’s developing a faster and cheaper method for making the same quality of barbed suture.

“If I fabricate using a laser, the fabrication time is pretty short compared to a mechanical barbing technique,” Nambi Gowri says.

Moving from a mechanical method to a laser method has another advantage.

“The manipulation of the barbed suture itself is easier using a laser,” she says.

In other words, using the lasers will allow Nambi Gowri to apply the custom barb geometries, or angles, suggested by prior researchers on a commercial scale. These custom geometries will allow the barbed suture to be optimized for the type of tissue it will be connecting.

In addition to the new process, Nambi Gowri is also developing a new suture.

“I’m the first one to actually study Catgut barbed sutures,” she explains.

Catgut was actually one of the earliest materials used to make sutures. The filament is made from tissue taken from an animal’s stomach – especially cattle stomachs – hence the name. While the industry had moved away from this material in favor of synthetic polymers, Nambi Gowri sees the potential for Catgut in barbed sutures because of their quick degradation rate.

“These are useful external wound closures,” she says. “Because our body contains so much collagen and Catgut is made up of 90% collagen, it’s a more suitable polymer that can be used in human tissue.”

Hands-on experience informs research
In the meantime, Nambi Gowri has gained hands-on experience to inform her research by fabricating all of the barbed sutures used in Dr. Ruff’s micro facelift surgeries.

The surgery itself is made possible because of the shape and the material composition of the sutures: poly 4-hydroxybutyrate (P4HB). This polymer is already present naturally within our bodies, so sutures made from P4HB are naturally and safely absorbed by the body over time. That means patients don’t have to schedule an appointment after surgery for the sutures to be removed.
 
P4HB also provides the perfect combination of strength and elasticity to hold up the facial tissue until the wound has healed. The barbs, on the other hand, allow for the suture to be placed and stay secure within the skin without the need for large incisions.

“That skin tightens up right away,” Dr. Ruff says of the procedure, which draws patients from across the country. “So I don’t have to remove hair, and I don’t have to put a scar at the hairline.”

“These sutures are not available commercially anywhere in the world. So, to be able to mechanically barb different size sutures in a reliable and consistent manner for use in clinical practice, requires skill, experience and knowledge of quality control,” Professor King says of Nambi Gowri’s work.

This has given Karuna a hands-on understanding of the sutures she’s hoping to improve upon.

She says her fiber and polymer science knowledge has played a key role in helping her approach all sides of her research.

“All the analytical characterization techniques that are used for characterization of sutures – like identifying mechanical properties and measuring tensile strength – is actually from my knowledge of textiles,” she says. “I’m applying my polymer chemistry knowledge  to make sure that the laser doesn’t cause the sutures to degrade, melt or experience thermal damage.”

What’s next?
As she works to patent her designs, Nambi Gowri feels confident that her dissertation will set her up for success in the research and development (R&D) field after graduation.

In the meantime, she’s already finding out about the ways her research can have a broader impact.

“Dr. Dan Duffy, DVM, a surgeon at the NC State College of Veterinary Medicine is also interested in using barbed sutures to repair torn and failed tendons on his animals, but he finds the cost of buying commercial barbed sutures prohibitively expensive. So we need to collaborate,” King says. “Karuna to the rescue!”

Source:

North Carolina State University, Sarah Stone

New conductive, cotton-based fiber developed for smart textiles Photo: Dean Hare, WSU Photo Services
29.12.2023

New conductive, cotton-based fiber developed for smart textiles

A single strand of fiber developed at Washington State University has the flexibility of cotton and the electric conductivity of a polymer, called polyaniline.

The newly developed material showed good potential for wearable e-textiles. The WSU researchers tested the fibers with a system that powered an LED light and another that sensed ammonia gas, detailing their findings in the journal Carbohydrate Polymers.

“We have one fiber in two sections: one section is the conventional cotton: flexible and strong enough for everyday use, and the other side is the conductive material,” said Hang Liu, WSU textile researcher and the study’s corresponding author. “The cotton can support the conductive material which can provide the needed function.”

A single strand of fiber developed at Washington State University has the flexibility of cotton and the electric conductivity of a polymer, called polyaniline.

The newly developed material showed good potential for wearable e-textiles. The WSU researchers tested the fibers with a system that powered an LED light and another that sensed ammonia gas, detailing their findings in the journal Carbohydrate Polymers.

“We have one fiber in two sections: one section is the conventional cotton: flexible and strong enough for everyday use, and the other side is the conductive material,” said Hang Liu, WSU textile researcher and the study’s corresponding author. “The cotton can support the conductive material which can provide the needed function.”

While more development is needed, the idea is to integrate fibers like these into apparel as sensor patches with flexible circuits. These patches could be part of uniforms for firefighters, soldiers or workers who handle chemicals to detect for hazardous exposures. Other applications include health monitoring or exercise shirts that can do more than current fitness monitors.

“We have some smart wearables, like smart watches, that can track your movement and human vital signs, but we hope that in the future your everyday clothing can do these functions as well,” said Liu. “Fashion is not just color and style, as a lot of people think about it: fashion is science.”

In this study, the WSU team worked to overcome the challenges of mixing the conductive polymer with cotton cellulose. Polymers are substances with very large molecules that have repeating patterns. In this case, the researchers used polyaniline, also known as PANI, a synthetic polymer with conductive properties already used in applications such as printed circuit board manufacturing.

While intrinsically conductive, polyaniline is brittle and by itself, cannot be made into a fiber for textiles. To solve this, the WSU researchers dissolved cotton cellulose from recycled t-shirts into a solution and the conductive polymer into another separate solution. These two solutions were then merged together side-by-side, and the material was extruded to make one fiber.

The result showed good interfacial bonding, meaning the molecules from the different materials would stay together through stretching and bending.

Achieving the right mixture at the interface of cotton cellulose and polyaniline was a delicate balance, Liu said.

“We wanted these two solutions to work so that when the cotton and the conductive polymer contact each other they mix to a certain degree to kind of glue together, but we didn’t want them to mix too much, otherwise the conductivity would be reduced,” she said.

Additional WSU authors on this study included first author Wangcheng Liu as well as Zihui Zhao, Dan Liang, Wei-Hong Zhong and Jinwen Zhang. This research received support from the National Science Foundation and the Walmart Foundation Project.

Source:

Sara Zaske, WSU News & Media Relations

Firefighter Photo: 12019 at Pixabay
11.12.2023

Study tests firefighter turnout gear with, without PFAS


Transitioning away from per- and polyfluoroalkyl substances (PFAS), which offer water- and oil-repelling properties on the outer shells of firefighter turnout gear, could bring potential performance tradeoffs, according to a new study from North Carolina State University.

The study showed that turnout gear without PFAS outer shell coatings were not oil-repellent, posing a potential flammability hazard to firefighters if exposed to oil and flame, said Bryan Ormond, assistant professor of textile engineering, chemistry and science at NC State and corresponding author of a paper describing the research.

“All oil repellents can also repel water, but all water repellents don’t necessarily repel oil,” Ormond said. “Diesel fuel is really difficult to repel, as is hydraulic fluid; in our testing, PFAS-treated materials repel both. In our tests, turnout gear without PFAS repelled water but not oil or hydraulic fluid.


Transitioning away from per- and polyfluoroalkyl substances (PFAS), which offer water- and oil-repelling properties on the outer shells of firefighter turnout gear, could bring potential performance tradeoffs, according to a new study from North Carolina State University.

The study showed that turnout gear without PFAS outer shell coatings were not oil-repellent, posing a potential flammability hazard to firefighters if exposed to oil and flame, said Bryan Ormond, assistant professor of textile engineering, chemistry and science at NC State and corresponding author of a paper describing the research.

“All oil repellents can also repel water, but all water repellents don’t necessarily repel oil,” Ormond said. “Diesel fuel is really difficult to repel, as is hydraulic fluid; in our testing, PFAS-treated materials repel both. In our tests, turnout gear without PFAS repelled water but not oil or hydraulic fluid.

“Further, oils seem to spread out even more on the PFAS-free gear, potentially increasing the hazard.”

PFAS chemicals – known as forever chemicals because of their environmental persistence – are used in food packaging, cookware and cosmetics, among other uses, but have recently been implicated in higher risks of cancer, higher cholesterol levels and compromised immune systems in humans. In response, firefighters have sought alternative chemical compounds – like the hydrocarbon wax coating used in the study – on turnout gear to repel water and oils.

Besides testing the oil- and water-repelling properties of PFAS-treated and PFAS-free outer garments, the NC State researchers also compared how the outer shells aged in job-related exposures like weathering, high heat and repeated laundering, and whether the garments remained durable and withstood tears and rips.

The study showed that PFAS-treated and PFAS-free outer shells performed similarly after exposure to UV rays and various levels of heat and moisture, as well as passes through heating equipment – similar to a pizza oven – and through washing machines.

“Laundering the gear is actually very damaging to turnout gear because of the washing machine’s agitation and cleaning agents used,” Ormond said.

“We also performed chemical analyses to see what’s happening during the weathering process,” said Nur Mazumder, an NC State doctoral student in fiber and polymer science and lead author of the paper. “Are we losing the PFAS chemistries, the PFAS-free chemistries or both when we age the garments? It turns out that we lost significant amounts of both of these finishes after the aging tests.”

Both types of garments performed similarly when tested for strength against tearing the outer shell fabric. The researchers say the PFAS and PFAS-free coatings didn’t seem to affect this attribute.

Ormond said that future work will explore how much oil repellency is needed by firefighters out in the field.
“Even with PFAS treatment, you see a difference between a splash of fluid and soaked-in fluid,” Ormond said. “For all of its benefits, PFAS-treated gear, when soaked, is dangerous to firefighters. So we need to really ask ‘What do firefighters need?’ If you’re not experiencing this need for oil repellency, there’s no worry about switching to non-PFAS gear. But firefighters need to know the non-PFAS gear will absorb oil, regardless of what those oils are.”

Andrew Hall, another NC State doctoral student in fiber and polymer science and co-author on the paper, is also testing dermal absorption, or taking the aged outer shell materials and placing them on a skin surrogate for a day or two. Are outer shell chemicals absorbed in the skin surrogate after these admittedly extreme exposure durations?

“Firefighting as a job is classified as a carcinogen but it shouldn’t have to be,” Ormond said. “How do we make better gear for them? How do we come up with better finishes and strategies for them?

“These aren’t just fabrics,” Ormond said. “They are highly engineered pieces of material that aren’t easily replaced.”

The paper appears in the Journal of Industrial Textiles. Funding for the research came from the Federal Emergency Management Agency’s Assistance to Firefighters Grants Program.

Source:

North Carolina State University, Mick Kulikowski

Researchers made shape-changing fibers by encapsulating a balloon-like tube in a braided textile sheath. (c) : Muh Amdadul Hoque. Researchers made shape-changing fibers by encapsulating a balloon-like tube in a braided textile sheath.
27.09.2023

Artificial Muscle Fibers Could Serve as Cell Scaffolds

In two new studies, North Carolina State University researchers designed and tested a series of textile fibers that can change shape and generate force like a muscle. In the first study, the researchers focused on the materials’ influence on the artificial muscles’ strength and contraction length. The findings could help researchers tailor the fibers for different applications.

In the second, proof-of-concept study, the researchers tested their fibers as scaffolds for live cells. Their findings suggest the fibers – known as “fiber robots” – could potentially be used to develop 3D models of living, moving systems in the human body.

In two new studies, North Carolina State University researchers designed and tested a series of textile fibers that can change shape and generate force like a muscle. In the first study, the researchers focused on the materials’ influence on the artificial muscles’ strength and contraction length. The findings could help researchers tailor the fibers for different applications.

In the second, proof-of-concept study, the researchers tested their fibers as scaffolds for live cells. Their findings suggest the fibers – known as “fiber robots” – could potentially be used to develop 3D models of living, moving systems in the human body.

“We found that our fiber robot is a very suitable scaffold for the cells, and we can alter the frequency and contraction ratio to create a more suitable environment for cells,” said Muh Amdadul Hoque, graduate student in textile engineering, chemistry and science at NC State. “These were proof-of concept studies; ultimately, our goal is to see if we can study these fibers as a scaffold for stem cells, or use them to develop artificial organs in future studies.”
 
Researchers made the shape-changing fibers by encapsulating a balloon-like tube, made of a material similar to rubber, in a braided textile sheath. Inflating the interior balloon with an air pump makes the braided sheath expand, causing it to shorten.

The researchers measured the force and contraction rates of fibers made from different materials in order to understand the relationship between material and performance. They found that stronger, larger diameter yarns generated a stronger contraction force. In addition, they found that the material used to make the balloon impacted the magnitude of the contraction and generated force.
 
“We found that we could tailor the material properties to the required performance of the device,” said Xiaomeng Fang, assistant professor of textile engineering, chemistry and science at NC State. “We also found that we can make this device small enough so we can potentially use it in fabric formation and other textile applications, including in wearables and assistive devices.”
 
In a follow-up study, researchers evaluated whether they could use the shape-changing fibers as a scaffold for fibroblasts, a cell type found in connective tissues that help support other tissues or organs.

“The idea with stretching is to mimic the dynamic nature of how your body moves,” said Jessica Gluck, assistant professor of textile engineering, chemistry and science at NC State, and a study co-author.

They studied the cells’ response to the motion of the shape-changing fibers, and to different materials used in the fibers’ construction. They found the cells were able to cover and even penetrate the fiber robot’s braiding sheath. However, they saw decreases in the cells’ metabolic activity when the fiber robot’s contraction extended beyond a certain level, compared to a device made of the same material that they kept stationary.

The researchers are interested in building on the findings to see if they could use the fibers as a 3D biological model, and to investigate whether movement would impact cell differentiation. They said their model would be an advance over other existing experimental models that have been developed to show cellular response to stretching and other motion, since they can only move in two dimensions.
 
“Typically, if you want to add stretch or strain on cells, you would put them onto a plastic dish, and stretch them in one or two directions,” Gluck said. “In this study, we were able to show that in this 3D dynamic culture, the cells can survive for up to 72 hours.

“This is particularly useful for stem cells,” Gluck added. “What we could do in the future is look at what could happen at the cellular level with mechanical stress on the cells. You could look at muscle cells and see how they’re developing, or see how the mechanical action would help differentiate the cells.”

The study, “Effect of Material Properties on Fiber-Shaped Pneumatic Actuators Performance” was published in Actuators on March 18. Emily Petersen was a co-author. The study was funded by start-up funding awarded to Fang from the Department of Textile Engineering, Chemistry and Science at NC State.

The study, “Development of a Pneumatic-Driven Fiber-Shaped Robot Scaffold for Use as a Complex 3D Dynamic Culture System” was published online in Biomimetics on April 21. In addition to Gluck, Hoque and Fang, co-authors included Nasif Mahmood, Kiran M. Ali, Eelya Sefat, Yihan Huang, Emily Petersen and Shane Harrington. The study was funded by the NC State Wilson College of Textiles, the Department of Textile Engineering, Chemistry and Science and the Wilson College of Textiles Research Opportunity Seed Fund Program.

Source:

North Carolina State University, Laura Oleniacz. Übersetzung Textination

Point of View: Let’s end fast fashion, Prof Minna Halme. Photo: Veera Konsti / Aalto University
18.08.2023

Point of View: Let’s end fast fashion

Focusing on short-term profit isn’t sustainable. So what can we do to move in the right direction: favour resilience over efficiency in all industries.

We buy cheap products knowing we’ll need to replace them soon. We throw out used items rather than repairing or re-using them. Our employers plan in terms of financial quarters despite hoping to remain relevant and resilient longer-term. Even countries prioritise short-term economic output, focusing on gross domestic product (GDP) above any other indicator.

But does this way of living, working and weighing decisions make sense in the 21st century?

Our global obsession with economic short-term efficiency – and how to transform it – is a conundrum that Professor of Sustainability Management Minna Halme has been thinking about for most of her career. Even as a business school student, she felt flummoxed by how focused her classes were on short-term goals.

Focusing on short-term profit isn’t sustainable. So what can we do to move in the right direction: favour resilience over efficiency in all industries.

We buy cheap products knowing we’ll need to replace them soon. We throw out used items rather than repairing or re-using them. Our employers plan in terms of financial quarters despite hoping to remain relevant and resilient longer-term. Even countries prioritise short-term economic output, focusing on gross domestic product (GDP) above any other indicator.

But does this way of living, working and weighing decisions make sense in the 21st century?

Our global obsession with economic short-term efficiency – and how to transform it – is a conundrum that Professor of Sustainability Management Minna Halme has been thinking about for most of her career. Even as a business school student, she felt flummoxed by how focused her classes were on short-term goals.

'It was about selling more, about maximising shareholder profits, about economic growth – but not really asking, Why? What's the purpose of all this?'

Halme says. 'Even 20-year-old me somehow just felt that this was strange.

'What are we trying to do here? Are we trying to create a better economy for all, or most, people? Whose lives are we trying to improve when we are selling more differently-packaged types of yoghurt or clothes that quickly become obsolete?'

Halme has devoted her career to studying these questions. Today, she is a thought leader in innovative business practices, with recognitions including serving on Finland's National Expert Panel for Sustainable Development and on the United Nation's Panel on Global Sustainability.

Her ultimate goal? Pioneering, researching and advocating for alternative ways of thinking that prioritise values like long-term economic sustainability and resilience – alternatives that she and other experts believe would provide more lasting, widespread benefit to all.

How traditional indicators have failed
One way in which our preference for economic efficiency shapes how we measure a country's overall well-being or status is GDP. This isn't the fault of the originator of the modern concept of GDP, who specifically warned against using it in this way in the 1930s.

'GDP was never meant to tell us about the wellbeing of the citizens of a country,' Halme says. Seventy-five years ago, however, it was easy to conflate the two. Many countries were more committed to redistributing their wealth among their citizens, and population surveys show that until the 1970s, GDP often correlated with general wellbeing.

But with the rise of increasingly heedless free-market capitalism, this became less the case – and GDP's shortcomings became all the more apparent. 'We are in a situation where the wealth distribution is more and more trickling up to those who already have capital. Those who don't have it are in declining economic positions,' Halme says. In fact, the richest 1% of the global population now own nearly half of the world's wealth.

Some governments, such as Finland's, do take indicators of environmental and social progress into account. 'But none is considered as important for decision-making as GDP,' Halme says – and GDP is also considered the arbiter of a government's success. It is that attitude that, through her work advising the Finnish government on sustainability practises as well as in her own research, Halme is trying to shift.

Where industries have failed
Our often-exclusive focus on the economy – and, in particular, on making profits as quickly and efficiently as possible – doesn’t provide a clear picture of how everyone in a society is faring. Worse yet, it has encouraged industries to act with a short-term view that makes for longer-term problems.

Fast fashion is one example. At the moment, supply chains for clothing – as for most other goods – are linear. Raw materials come from one place and are transformed step by step, usually at different factories around the world, using materials, energy and transport that are “cheap” because their high environmental costs aren’t included. They are ultimately purchased by a consumer, who wears the product temporarily before discarding it. To expand profit margins, the industry pushes fast-changing trends. A shocking amount of this clothing ends up in landfill – some of it before it's even been worn.

As the COVID lockdowns showed, this kind of linear supply system isn't resilient. Nor is it sustainable.

Currently, fashion is estimated to be the world's second most polluting industry, accounting for up to 10% of all greenhouse gas emissions. Aalto University researchers have reported that the industry produces more than 92 million tonnes of landfill waste per year. By 2030, that is expected to rise to 134 million tonnes.

Cutting fashion's carbon footprint isn't just good for the environment; it will help the longer-term prospects of the industry itself. 'With this kind of wrong thinking about efficiency, you're eroding the basis of our long-term resilience both for ecology and for society,' Halme says.

Getting out of this trap, she and other researchers say, requires a complete paradigm shift. 'It's really difficult to just tweak around the edges,' she says.

Towards resilience
For several years, Halme researched and studied ecological efficiency, looking at ways that businesses could make more products with a smaller environmental impact. But gradually she realised this wasn't the answer. Although businesses could innovate to have more efficient products and technologies, their absolute use of natural resource use kept growing.

'I began to think, "If not efficiency, then what?"' Halme says. She realised the answer was resilience: fostering ways for systems, including the environment, to continue and even regenerate in the future, rather than continuing to degrade them in the present.

The solution isn’t more of anything, even ‘sustainable’ materials. It’s less.

'The only way to fix fast fashion is to end it,' Halme and her co-authors write. This means designing clothes to last, business models that make reuse and repair more accessible, and prioritising upcycling. Recycling systems also need to be overhauled for when an item really is at the end of its life – particularly regarding blended synthetic fibres, which are difficult to separate and break down.

This would upend the current focus on short-term revenue above all else. And, says Halme, it is one more example of how we need better ways to measure the success of these industries, taking into account factors like resilience and sustainability – rather than just short-term profits.

And while individuals can make an impact, these changes ultimately have to be industry-led.

'Textiles are a good example, because if they break quickly, and if you don't have repair services nearby, or if the fabrics are of such lousy quality that it doesn't make any sense to repair them, then it's too much trouble for most people,' Halme says. 'So most solutions should come from the business side. And the attempt should be to make it both fashionable and easy for consumers to make ecologically and socially sustainable choices.'

What will it take?
The ultimate challenge, says Lauri Saarinen, Assistant Professor at the Aalto University Department of Industrial Engineering and Management, is how to shift towards a more sustainable model while keeping companies competitive. But he believes there are ways.

One option is to keep production local. 'If we compete with low-cost, offshore manufacturing by doing things more locally, and in a closed loop, then we get the double benefit of actually providing some local work and moving towards a more sustainable supply chain,' Saarinen says. For example, if clothing were produced closer to consumers, it would be easier to send garments back for repair or for brands to take back used items and resell them.

Local production is yet another example of the need to rethink how we measure societal success. After all, outsourcing and offshoring in favour of cheaper production may appear to cut costs in short term, but this is done at the expense of what Halme and other experts argue really matters – longer-term economic viability, resilience and sustainability.

Shifting towards this kind of thinking isn't easy. Still, Saarinen and Halme have seen promising signs.

In Finland, for example, Halme points to the start-up Menddie, which makes it easy and convenient to send items away for repairs or alterations. She also highlights the clothing and lifestyle brand Marimekko, which re-sells its used items in an online secondhand shop, and the Anna Ruohonen label, a made-to-measurecollection and customer on-demand concept which creates no excess garments.

It's these kinds of projects that Halme finds interesting – and that, through her work, she hopes to both advocate for and pioneer.

At the moment, she says, these changes haven't yet added up to a true transformation. On a global scale, we remain far from a genuine shift towards longer-term resilience. But as she points out, that can change quickly. After all, it has in the past. Just look at what got us here.

'The pursuit of economic growth became such a dominant focus in a relatively short time – only about seven decades,' she says. 'The shift toward longer-term resilience is certainly possible. Scientists and decision-makers just need to change their main goal to long-term resilience. The key question is, are our most powerful economic players wise enough to do so?'

As part of her research, Halme has led projects pioneering the kinds of changes that the fashion industry could adapt. For example, along with her Aalto colleague Linda Turunen, she recently developed a measurement that the fashion industry could use to classify how sustainable a product really is – measuring things like its durability, how easily it can be recycled, and whether its production uses hazardous chemicals – which could help consumers to decide whether to buy. Her colleagues curated a recent exhibition that showcased what we might be wearing in a sustainable future, such as a leather alternative made from discarded flower cuttings, or modular designs to get multiple uses from the same garment – turning a skirt into a shirt, for example.
 
Because all of this requires longer-term thinking, innovation and investment, industry is reticent to make these shifts, Halme says. One way to encourage industries to change more quickly is with regulation. In the European Union, for example, an updated set of directives now requires companies with more than 500 employees to report on a number of corporate responsibility factors, ranging from environmental impact to the treatment of employees. These rules won't just help inform consumers, investors and other stakeholders about a company's role in global challenges. They’ll also help assess investment risks – weighing whether a company is taking the actions necessary to be financially resilient in the long-term.

Source:

Aalto University, Amanda Ruggeri

Functional textiles – an alternative to antibiotics University of Borås
04.07.2023

Functional textiles – an alternative to antibiotics

Tuser Biswas conducts research that aims to develop modern medical textiles that are good for both the environment and human health. Textiles with antimicrobial properties could reduce the use of antibiotics.

Tuser Biswas conducts research that aims to develop modern medical textiles that are good for both the environment and human health. Textiles with antimicrobial properties could reduce the use of antibiotics.

His work involves research and teaching activities within the area of textile material technology. The current research involves resource-efficient inkjet printing of functional materials on various textile surfaces for advanced applications.
 
The conventional textile industry devours natural resources in the form of water, energy, and chemicals. A more resource-efficient way to produce textiles is with ink jet printing. Tuser Biswas, who recently defended his doctoral thesis in Textile Material Technology, seeks to develop methods for functional textiles. He has shown that it is possible to print enzymes on textiles. These are proteins that function as catalysts in the body, as they set chemical processes in motion without themselves changing. They could, for example, be used in medical textiles with antimicrobial properties or to measure biological or chemical reactions.

“Ever since the industrial revolution, our society has used an abundance of synthetic and harsh chemicals. Our research works to replace these chemicals with environmentally friendly and bio-based materials,” said Tuser Biswas.
 
Promising results with enzymes on textiles
Developing a good enzyme ink was not entirely easy and it took a number of attempts before he finally, to his great joy, had successful results. Tuser Biswas explained that the most important result is to show how a printed enzyme could bind another enzyme to the surface of a fabric. Although the activity of the enzymes decreased by 20-30 percent after printing, the results are still promising for future applications. At the same time, the work has provided new knowledge about many fundamental questions about printing biomaterials on fabric.

“Before starting the project, we found several related studies that focused on producing a finished product. But we wanted to study the fundamental challenges of this subject, and now we know how to make it work,” said Tuser Biswas.

He is now seeking funding to continue researching the subject and has so far received a grant from the Sjuhärad Savings Bank Foundation. During the Days of Knowledge event in April 2023, he presented his research to representatives from the City of Borås and business, the Sjuhärad Savings Bank Foundation, and the University of Borås.
     
Medical textiles instead of antibiotics
Tuser Biswas hopes that continued research in textile technology can provide alternatives to using antibiotics. With increasing antibiotic resistance, it is an important issue not only locally but worldwide.

“Instead of treating the patient with a course of antibiotics, one can act preventively and more effectively by damaging the bacteria on the surface where they start to grow. In a wound dressing, for example. Nanoparticle-based antimicrobials can reduce growth effectively. It is possible as nanoparticles can interact better with the bacterial membrane and reach the target more easily than conventional antimicrobials.”

Source:

Lina Färm. Translation by Eva Medin. University of Borås

Thread-like pumps can be woven into clothes (c) LMTS EPFL
27.06.2023

Thread-like pumps can be woven into clothes

Ecole Polytechnique Fédérale de Lausanne (EPFL) researchers have developed fiber-like pumps that allow high-pressure fluidic circuits to be woven into textiles without an external pump. Soft supportive exoskeletons, thermoregulatory clothing, and immersive haptics can therefore be powered from pumps sewn into the fabric of the devices themselves.

Many fluid-based wearable assistive technologies today require a large and noisy pump that is impractical – if not impossible – to integrate into clothing. This leads to a contradiction: wearable devices are routinely tethered to unearable pumps. Now, researchers at the Soft Transducers Laboratory (LMTS) in the School of Engineering have developed an elegantly simple solution to this dilemma.

Ecole Polytechnique Fédérale de Lausanne (EPFL) researchers have developed fiber-like pumps that allow high-pressure fluidic circuits to be woven into textiles without an external pump. Soft supportive exoskeletons, thermoregulatory clothing, and immersive haptics can therefore be powered from pumps sewn into the fabric of the devices themselves.

Many fluid-based wearable assistive technologies today require a large and noisy pump that is impractical – if not impossible – to integrate into clothing. This leads to a contradiction: wearable devices are routinely tethered to unearable pumps. Now, researchers at the Soft Transducers Laboratory (LMTS) in the School of Engineering have developed an elegantly simple solution to this dilemma.

“We present the world’s first pump in the form of a fiber; in essence, tubing that generates its own pressure and flow rate,” says LMTS head Herbert Shea. “Now, we can sew our fiber pumps directly into textiles and clothing, leaving conventional pumps behind.” The research has been published in the journal Science.

Lightweight, powerful…and washable
Shea’s lab has a history of forward-thinking fluidics. In 2019, they produced the world’s first stretchable pump.

“This work builds on our previous generation of soft pump,” says Michael Smith, an LMTS post-doctoral researcher and lead author of the study. “The fiber format allows us to make lighter, more powerful pumps that are inherently more compat-ible with wearable technology.”

The LMTS fiber pumps use a principle called charge injection electrohydrodynamics (EHD) to generate a fluid flow without any moving parts. Two helical electrodes embedded in the pump wall ionize and accelerate molecules of a special non-conductive liquid. The ion movement and electrode shape generate a net forward fluid flow, resulting in silent, vibration-free operation, and requiring just a palm-sized power supply and battery.

To achieve the pump’s unique structure, the researchers developed a novel fabrication technique that involves twisting copper wires and polyurethane threads together around a steel rod, and then fusing them with heat. After the rod is removed, the 2 mm fibers can be integrated into textiles using standard weaving and sewing techniques.

The pump’s simple design has a number of advantages. The materials required are cheap and readily available, and the manufacturing process can be easily scaled up. Because the amount of pressure generated by the pump is directly linked to its length, the tubes can be cut to match the application, optimizing performance while minimizing weight. The robust design can also be washed with conventional detergents.

From exoskeletons to virtual reality
The authors have already demonstrated how these fiber pumps can be used in new and exciting wearable technologies. For example, they can circulate hot and cold fluid through garments for those working in extreme temperature environments or in a therapeutic setting to help manage inflammation; and even for those looking to optimize athletic performance.

“These applications require long lengths of tubing anyway, and in our case, the tubing is the pump. This means we can make very simple and lightweight fluidic circuits that are convenient and comfortable to wear,” Smith says.

The study also describes artificial muscles made from fabric and embedded fiber pumps, which could be used to power soft exoskeletons to help patients move and walk.

The pump could even bring a new dimension to the world of virtual reality by simulating the sensation of temperature. In this case, users wear a glove with pumps filled with hot or cold liquid, allowing them to feel temperature changes in response to contact with a virtual object.

Pumped up for the future
The researchers are already looking to improve the performance of their device. “The pumps already perform well, and we’re confident that with more work, we can continue to make improvements in areas like efficiency and lifetime,” says Smith. Work has already started on scaling up the production of the fiber pumps, and the LMTS also has plans to embed them into more complex wearable devices.

“We believe that this innovation is a game-changer for wearable technology,” Shea says.

More information:
EPFL Fibers exoskeleton wearables
Source:

Celia Luterbacher, School of Engineering | STI

A cotton knit fabric dyed blue and washed 10 times to simulate worn garments is enzymatically degraded to a slurry of fine fibers and "blue glucose" syrup that are separated by filtration - both of these separated fractions have potential recycle value. A cotton knit fabric dyed blue and washed 10 times to simulate worn garments is enzymatically degraded to a slurry of fine fibers and "blue glucose" syrup that are separated by filtration - both of these separated fractions have potential recycle value. Credit: Sonja Salmon.
11.04.2023

Researchers Separate Cotton from Polyester in Blended Fabric

In a new study, North Carolina State University researchers found they could separate blended cotton and polyester fabric using enzymes – nature’s tools for speeding chemical reactions. Ultimately, they hope their findings will lead to a more efficient way to recycle the fabric’s component materials, thereby reducing textile waste. However, they also found the process need more steps if the blended fabric was dyed or treated with chemicals that increase wrinkle resistance.

In a new study, North Carolina State University researchers found they could separate blended cotton and polyester fabric using enzymes – nature’s tools for speeding chemical reactions. Ultimately, they hope their findings will lead to a more efficient way to recycle the fabric’s component materials, thereby reducing textile waste. However, they also found the process need more steps if the blended fabric was dyed or treated with chemicals that increase wrinkle resistance.

“We can separate all of the cotton out of a cotton-polyester blend, meaning now we have clean polyester that can be recycled,” said the study’s corresponding author Sonja Salmon, associate professor of textile engineering, chemistry and science at NC State. “In a landfill, the polyester is not going to degrade, and the cotton might take several months or more to break down. Using our method, we can separate the cotton from polyester in less than 48 hours.”
 
According to the U.S. Environmental Protection Agency, consumers throw approximately 11 million tons of textile waste into U.S. landfills each year. Researchers wanted to develop a method of separating the cotton from the polyester so each component material could be recycled.

In the study, researchers used a “cocktail” of enzymes in a mildly acidic solution to chop up cellulose in cotton. Cellulose is the material that gives structure to plants’ cell walls. The idea is to chop up the cellulose so it will “fall out” out of the blended woven structure, leaving some tiny cotton fiber fragments remaining, along with glucose. Glucose is the biodegradable byproduct of degraded cellulose. Then, their process involves washing away the glucose and filtering out the cotton fiber fragments, leaving clean polyester.
 
“This is a mild process – the treatment is slightly acidic, like using vinegar,” Salmon said. “We also ran it at 50 degrees Celsius, which is like the temperature of a hot washing machine.
“It’s quite promising that we can separate the polyester to a clean level,” Salmon added. “We still have some more work to do to characterize the polyester’s properties, but we think they will be very good because the conditions are so mild. We’re just adding enzymes that ignore the polyester.”

They compared degradation of 100% cotton fabric to degradation of cotton and polyester blends, and also tested fabric that was dyed with red and blue reactive dyes and treated with durable press chemicals. In order to break down the dyed materials, the researchers had to increase the amount of time and enzymes used. For fabrics treated with durable press chemicals, they had to use a chemical pre-treatment before adding the enzymes.

“The dye that you choose has a big impact on the potential degradation of the fabric,” said the study’s lead author Jeannie Egan, a graduate student at NC State. “Also, we found the biggest obstacle so far is the wrinkle-resistant finish. The chemistry behind that creates a significant block for the enzyme to access the cellulose. Without pre-treating it, we achieved less than 10% degradation, but after, with two enzyme doses, we were able to fully degrade it, which was a really exciting result.”

Researchers said the polyester could be recycled, while the slurry of cotton fragments could be valuable as an additive for paper or useful addition to composite materials. They’re also investigating whether the glucose could be used to make biofuels.

“The slurry is made of residual cotton fragments that resist a very powerful enzymatic degradation,” Salmon said. “It has potential value as a strengthening agent. For the glucose syrup, we’re collaborating on a project to see if we can feed it into an anaerobic digester to make biofuel. We’d be taking waste and turning it into bioenergy, which would be much better than throwing it into a landfill.”

The study, “Enzymatic textile fiber separation for sustainable waste processing,” was published in Resources, Environment and Sustainability. Co-authors included Siyan Wang, Jialong Shen, Oliver Baars and Geoffrey Moxley. Funding was provided by the Environmental Research and Education Foundation, Kaneka Corporation and the Department of Textile Engineering, Chemistry and Science at NC State.

Source:

North Carolina State University, Laura Oleniacz

Vadim Zharkov: https://youtu.be/x9gCrhIPaPM
28.02.2023

‘Smart’ Coating Could Make Fabrics into Protective Gear

Precisely applied metal-organic technology detects and captures toxic gases in air.

A durable copper-based coating developed by Dartmouth researchers can be precisely integrated into fabric to create responsive and reusable materials such as protective equipment, environmental sensors, and smart filters, according to a recent study.
 
The coating responds to the presence of toxic gases in the air by converting them into less toxic substances that become trapped in the fabric, the team reports in Journal of the American Chemical Society.

Precisely applied metal-organic technology detects and captures toxic gases in air.

A durable copper-based coating developed by Dartmouth researchers can be precisely integrated into fabric to create responsive and reusable materials such as protective equipment, environmental sensors, and smart filters, according to a recent study.
 
The coating responds to the presence of toxic gases in the air by converting them into less toxic substances that become trapped in the fabric, the team reports in Journal of the American Chemical Society.

The findings hinge on a conductive metal-organic technology, or framework, developed in the laboratory of corresponding author Katherine Mirica, an associate professor of chemistry. First reported in JACS in 2017, the framework was a simple coating that could be layered onto cotton and polyester to create smart fabrics the researchers named SOFT—Self-Organized Framework on Textiles. Their paper demonstrated that SOFT smart fabrics could detect and capture toxic substances in the surrounding environment.

For the newest study, the researchers found that—instead of the simple coating reported in 2017—they can precisely embed the framework into fabrics using a copper precursor that allows them to create specific patterns and more effectively fill in the tiny gaps and holes between threads.

The researchers found that the framework technology effectively converted the toxin nitric oxide into nitrite and nitrate, and transformed the poisonous, flammable gas hydrogen sulfide into copper sulfide. They also report that the framework’s ability to capture and convert toxic materials withstood wear and tear, as well as standard washing.
 
The versatility and durability the new method provides would allow the framework to be applied for specific uses and in more precise locations, such as a sensor on protective clothing, or as a filter in a particular environment, Mirica said.

“This new method of deposition means that the electronic textiles could potentially interface with a broader range of systems because they’re so robust,” she said. “This technological advance paves the way for other applications of the framework’s combined filtration and sensing abilities that could be valuable in biomedical settings and environmental remediation.”
The technique also could eventually be a low-cost alternative to technologies that are cost prohibitive and limited in where they can be deployed by needing an energy source, or—such as catalytic converters in automobiles—rare metals, Mirica said.
 
“Here we’re relying on an Earth-abundant matter to detoxify toxic chemicals, and we’re doing it without any input of outside energy, so we don’t need high temperature or electric current to achieve that function,” Mirica said.

Co-first author Michael Ko, initially observed the new process in 2018 as he attempted to deposit the metal-organic framework onto thin-film copper-based electrodes, Mirica said. But the copper electrodes would be replaced by the framework.

“He wanted it on top of the electrodes, not to replace them,” Mirica said. “It took us four years to figure out what was happening and how it was beneficial. It’s a very straightforward process, but the chemistry behind it is not and it took us some time and additional involvement of students and collaborators to understand that.”

The team discovered that the metal-organic framework “grows” over copper, replacing it with a material with the ability to filter and convert toxic gases, Mirica said. Ko and co-author Lukasz Mendecki, a postdoctoral scholar in the Mirica Group from 2017-18, investigated methods for applying the framework material to fabric in specific designs and patterns.

Co-first author Aileen Eagleton, who is also in the Mirica Group, finalized the technique by optimizing the process for imprinting the metal-organic framework onto fabric, as well as identifying how its structure and properties are influenced by chemical exposure and reaction conditions.

Future work will focus on developing new multifunctional framework materials and scaling up the process of embedding the metal-organic coatings into fabric, Mirica said.

Source:

Dartmouth / Textination