Textination Newsline

When nanoplastics are not what they seem ... Textiles made of synthetic fibers release micro- and nanoplastics during washing. Empa researchers have now been able to show: Some of the supposed nanoplastics do not actually consist of plastic particles, but of water-insoluble oligomers. The effects they have on humans and the environment are not yet well-understood.

Plastic household items and clothing made of synthetic fibers release microplastics: particles less than five millimetres in size that can enter the environment unnoticed. A small proportion of these particles are so small that they are measured in nanometers. Such nanoplastics are the subject of intensive research, as nanoplastic particles can be absorbed into the human body due to their small size – but, as of today, little is known about their potential toxicity.

Empa researchers from Bernd Nowack's group in the Technology and Society laboratory have now joined forces with colleagues from China to take a closer look at nanoparticles released from textiles. Tong Yang, first author of the study, carried out the investigations during his doctorate at Empa. In earlier studies, Empa researchers were already able to demonstrate that both micro- and nanoplastics are released when polyester is washed. A detailed examination of the released nanoparticles released has now shown that not everything that appears to be nanoplastic at first glance actually is nanoplastic.

To a considerable extent, the released particles were in fact not nanoplastics, but clumps of so-called oligomers, i.e. small to medium-sized molecules that represent an intermediate stage between the long-chained polymers and their individual building blocks, the monomers. These molecules are even smaller than nanoplastic particles, and hardly anything is known about their toxicity either. The researchers published their findings in the journal Nature Water.

For the study, the researchers examined twelve different polyester fabrics, including microfiber, satin and jersey. The fabric samples were washed up to four times and the nanoparticles released in the process were analyzed and characterized. Not an easy task, says Bernd Nowack. "Plastic, especially nanoplastics, is everywhere, including on our devices and utensils," says the scientist. "When measuring nanoplastics, we have to take this 'background noise' into account."

Large proportion of soluble particles
The researchers used an ethanol bath to distinguish nanoplastics from clumps of oligomers. Plastic pieces, no matter how small, do not dissolve in ethanol, but aggregations of oligomers do. The result: Around a third to almost 90 percent of the nanoparticles released during washing could be dissolved in ethanol. "This allowed us to show that not everything that looks like nanoplastics at first glance is in fact nanoplastics," says Nowack.

It is not yet clear whether the release of so-called nanoparticulate oligomers during the washing of textiles has negative effects on humans and the environment. "With other plastics, studies have already shown that nanoparticulate oligomers are more toxic than nanoplastics," says Nowack. "This is an indication that this should be investigated more closely." However, the researchers were able to establish that the nature of the textile and the cutting method – scissors or laser – have no major influence on the quantity of particles released.

The mechanism of release has not been clarified yet either – neither for nanoplastics nor for the oligomer particles. The good news is that the amount of particles released decreases significantly with repeated washes. It is conceivable that the oligomer particles are created during the manufacturing of the textile or split off from the fibers through chemical processes during storage. Further studies are also required in this area.

Nowack and his team are focusing on larger particles for the time being: In their next project, they want to investigate which fibers are released during washing of textiles made from renewable raw materials and whether these could be harmful to the environment and health. "Semi-synthetic textiles such as viscose or lyocell are being touted as a replacement for polyester," says Nowack. "But we don't yet know whether they are really better when it comes to releasing fibers."

Hospital germs and pathogens are not always transmitted directly from person to person. They can also spread via germ-contaminated surfaces and objects. Empa researchers, together with the chemical company BASF, Spiez Laboratory and the Technical University of Berlin, have now developed coated textiles that inhibit or even kill pathogens. They could be used as antimicrobial curtains in hospitals in the future.

Countless times a day, patients, visitors and medical staff in hospitals touch surfaces of all kinds. Door handles, railings or elevator buttons can serve as transport vehicles for pathogens such as hospital germs or viruses. Smooth surfaces are comparatively easy to clean after contamination. With porous structures such as textiles, however, this is not that simple. Empa researchers have solved this problem together with experts from BASF, Spiez Laboratory and the Technical University of Berlin: A coating process can now be used to treat fabrics in such a way that bacterial and viral pathogens are killed or inhibited in their growth. In hospitals, the coated textiles could be used in future as antimicrobial curtains between patient beds, for example.

Active for months
"We were looking for a process that reliably prevents germs from contaminating textiles that come into contact with a large number of people during use," explains Peter Wick from Empa's Particles-Biology Interactions laboratory in St. Gallen. In this way, chains of infection could be interrupted in which multi-resistant bacteria or viral pathogens, for example, settle on hospital curtains and can then be spread by people.

The researchers ultimately developed a coating process in which a benzalkonium chloride-containing disinfectant was evenly applied to hospital curtains. After optimizing parameters such as concentration, exposure time, processing pressure and drying, the coating adhered stably to the textile surface. But did the coated textiles also exhibit a germicidal effect? This was to be shown by analyzing the antimicrobial activity of the first fabric samples.

"The results of the laboratory tests were very encouraging," says Wick. When the bacterial cultures of some typical problem germs were incubated with the fabric samples, the coated textiles inhibited the growth of staphylococci and pseudomonas bacteria, for example. "The hospital germs were significantly reduced or even killed after just ten minutes of exposure," says the Empa researcher. Moreover, the coating was also active against viral pathogens: Over 99 percent of the viruses were killed by the coated fabric samples.

Another advantage: The coatings remained effective even after several months of storage. This allows production in stock. With the new process, other textiles, filters or cleaning utensils could also be quickly and safely treated with antimicrobials in the future, for example in the event of an epidemic, emphasizes Empa researcher Wick.

The low-cost FibeRobo, which is compatible with existing textile manufacturing techniques, could be used in adaptive performance wear or compression garments.

Researchers from MIT and Northeastern University developed a liquid crystal elastomer fiber that can change its shape in response to thermal stimuli. The fiber, which is fully compatible with existing textile manufacturing machinery, could be used to make morphing textiles, like a jacket that becomes more insulating to keep the wearer warm when temperatures drop.

Instead of needing a coat for each season, imagine having a jacket that would dynamically change shape so it becomes more insulating to keep you warm as the temperature drops.
A programmable, actuating fiber developed by an interdisciplinary team of MIT researchers could someday make this vision a reality. Known as FibeRobo, the fiber contracts in response to an increase in temperature, then self-reverses when the temperature decreases, without any embedded sensors or other hard components.

The low-cost fiber is fully compatible with textile manufacturing techniques, including weaving looms, embroidery, and industrial knitting machines, and can be produced continuously by the kilometer. This could enable designers to easily incorporate actuation and sensing capabilities into a wide range of fabrics for myriad applications.

The fibers can also be combined with conductive thread, which acts as a heating element when electric current runs through it. In this way, the fibers actuate using electricity, which offers a user digital control over a textile’s form. For instance, a fabric could change shape based on any piece of digital information, such as readings from a heart rate sensor.

“We use textiles for everything. We make planes with fiber-reinforced composites, we cover the International Space Station with a radiation-shielding fabric, we use them for personal expression and performance wear. So much of our environment is adaptive and responsive, but the one thing that needs to be the most adaptive and responsive — textiles — is completely inert,” says Jack Forman, a graduate student in the Tangible Media Group of the MIT Media Lab, with a secondary affiliation at the Center for Bits and Atoms, and lead author of a paper on the actuating fiber.

He is joined on the paper by 11 other researchers at MIT and Northeastern University, including his advisors, Professor Neil Gershenfeld, who leads the Center for Bits and Atoms, and Hiroshi Ishii, the Jerome B. Wiesner Professor of Media Arts and Sciences and director of the Tangible Media Group. The research will be presented at the ACM Symposium on User Interface Software and Technology.

Morphing materials
The MIT researchers wanted a fiber that could actuate silently and change its shape dramatically, while being compatible with common textile manufacturing procedures. To achieve this, they used a material known as liquid crystal elastomer (LCE).

A liquid crystal is a series of molecules that can flow like liquid, but when they’re allowed to settle, they stack into a periodic crystal arrangement. The researchers incorporate these crystal structures into an elastomer network, which is stretchy like a rubber band.

As the LCE material heats up, the crystal molecules fall out of alignment and pull the elastomer network together, causing the fiber to contract. When the heat is removed, the molecules return to their original alignment, and the material to its original length, Forman explains.

By carefully mixing chemicals to synthesize the LCE, the researchers can control the final properties of the fiber, such as its thickness or the temperature at which it actuates.

They perfected a preparation technique that creates LCE fiber which can actuate at skin-safe temperatures, making it suitable for wearable fabrics.

“There are a lot of knobs we can turn. It was a lot of work to come up with this process from scratch, but ultimately it gives us a lot of freedom for the resulting fiber,” he adds.
However, the researchers discovered that making fiber from LCE resin is a finicky process. Existing techniques often result in a fused mass that is impossible to unspool.

Researchers are also exploring other ways to make functional fibers, such as by incorporating hundreds of microscale digital chips into a polymer, utilizing an activated fluidic system, or including piezoelectric material that can convert sound vibrations into electrical signals.

Fiber fabrication
Forman built a machine using 3D-printed and laser-cut parts and basic electronics to overcome the fabrication challenges. He initially built the machine as part of the graduate-level course MAS.865 (Rapid-Prototyping of Rapid-Prototyping Machines: How to Make Something that Makes [almost] Anything).

To begin, the thick and viscous LCE resin is heated, and then slowly squeezed through a nozzle like that of a glue gun. As the resin comes out, it is cured carefully using UV lights that shine on both sides of the slowly extruding fiber.

If the light is too dim, the material will separate and drip out of the machine, but if it is too bright, clumps can form, which yields bumpy fibers.

Then the fiber is dipped in oil to give it a slippery coating and cured again, this time with UV lights turned up to full blast, creating a strong and smooth fiber. Finally, it is collected into a top spool and dipped in powder so it will slide easily into machines for textile manufacturing.
From chemical synthesis to finished spool, the process takes about a day and produces approximately a kilometer of ready-to-use fiber.

“At the end of the day, you don’t want a diva fiber. You want a fiber that, when you are working with it, falls into the ensemble of materials — one that you can work with just like any other fiber material, but then it has a lot of exciting new capabilities,” Forman says.

Creating such a fiber took a great deal of trial and error, as well as the collaboration of researchers with expertise in many disciplines, from chemistry to mechanical engineering to electronics to design.

The resulting fiber, called FibeRobo, can contract up to 40 percent without bending, actuate at skin-safe temperatures (the skin-safe version of the fiber contracts up to about 25 percent), and be produced with a low-cost setup for 20 cents per meter, which is about 60 times cheaper than commercially available shape-changing fibers.

The fiber can be incorporated into industrial sewing and knitting machines, as well as nonindustrial processes like hand looms or manual crocheting, without the need for any process modifications.
The MIT researchers used FibeRobo to demonstrate several applications, including an adaptive sports bra made by embroidery that tightens when the user begins exercising.

They also used an industrial knitting machine to create a compression jacket for Forman’s dog, whose name is Professor. The jacket would actuate and “hug” the dog based on a Bluetooth signal from Forman’s smartphone. Compression jackets are commonly used to alleviate the separation anxiety a dog can feel while its owner is away.

In the future, the researchers want to adjust the fiber’s chemical components so it can be recyclable or biodegradable. They also want to streamline the polymer synthesis process so users without wet lab expertise could make it on their own.

Forman is excited to see the FibeRobo applications other research groups identify as they build on these early results. In the long run, he hopes FibeRobo can become something a maker could buy in a craft store, just like a ball of yarn, and use to easily produce morphing fabrics.

“LCE fibers come to life when integrated into functional textiles. It is particularly fascinating to observe how the authors have explored creative textile designs using a variety of weaving and knitting patterns,” says Lining Yao, the Cooper-Siegel Associate Professor of Human Computer Interaction at Carnegie Mellon University, who was not involved with this work.

This research was supported, in part, by the William Asbjornsen Albert Memorial Fellowship, the Dr. Martin Luther King Jr. Visiting Professor Program, Toppan Printing Co., Honda Research, Chinese Scholarship Council, and Shima Seiki. The team included Ozgun Kilic Afsar, Sarah Nicita, Rosalie (Hsin-Ju) Lin, Liu Yang, Akshay Kothakonda, Zachary Gordon, and Cedric Honnet at MIT; and Megan Hofmann and Kristen Dorsey at Northeastern University.

Set against the vast and surreal backdrop of the Black Rock Desert in Nevada, Burning Man is an annual gathering that transforms the flat, barren expanse into a vibrant playground for artistic and creative expression. Here, "Burners" come to both witness and contribute to the ephemeral Black Rock City, which participants build anew each year. With its myriad art installations and performances, Black Rock City is a temporary home for creative minds from around the world.

This year among the large-scale art stood the Living Knitwork Pavilion, an unusual architectural piece crafted from knitted textiles and a lattice network of wood. Developed and built by a team of researchers from the MIT Media Lab and MIT School of Architecture and Planning, and led by PhD student Irmandy Wicaksono, the installation received a 2023 Black Rock City Honorarium. For the team, it was a highly challenging and fulfilling project, full of learning and surprises. Seeing it emerge and illuminate in the middle of the desert was truly magical.

In the Living Knitwork Pavilion, 12 modular fabric panels, known as Knitwork petals, are connected through a central tower. The whole installation stood as a dodecagonal pyramid shade structure, 18 feet tall and 26 feet wide, resembling a teepee. The fabrics were developed using digital machine knitting and a collection of functional and common yarns, including photochromic, luminous, and conductive yarns. Taking inspiration from the intricacy of textile patterns and temple carvings of Indonesia, Wicaksono leveraged the tension between knitted polyester and spandex yarns to create textural textile patterns or reliefs. The fusion of parametric and hand-designed motifs transforms the "Living Knitwork" into a narrative artwork, reflecting both a reverence for ancient artistry and a vision of the future. These reliefs, full of symbols and illustrations, depict 12 stories of the future — from solarpunk cities and bio-machine interfaces to the deep ocean and space exploration.

Burning Man and the Black Rock Desert are famed for their climbing enthusiasts and intense winds. Given that strong winds can make the fabrics behave like sails, exerting significant force, the team designed a structure capable of supporting the weight of many climbers, and withstanding wind speeds of up to 70 mph.

The finalized central structure of the pavilion consists of an asymptotic lattice network of lumber and joint elements, optimized for structural integrity while minimizing material use. The knitwork petals, integrated with double-knit structure and mesh openings, and thermoformed through melting yarns, maintain structural stability. Tailored channels for ropes and cables were also incorporated into the knitting design, ensuring each fabric and electrical component is securely anchored and protected, without compromising visual elegance. Facing winds that reached 36 mph this year, the Living Knitwork Pavilion remained steadfast throughout the Burning Man event, demonstrating its resilience in extreme desert conditions.

In support of Burning Man's push for more sustainable art, the Living Knitwork Pavilion utilized additive manufacturing of digital knitting. This method allowed for the creation of custom multi-layer textiles that are both aesthetic and functional, all while minimizing raw material use and waste. The team incorporated recycled materials in their fabrics, with 60 percent of the yarns coming from recycled plastic bottles. The pavilion also runs entirely on battery power and solar cells. The team worked together with the Solar Library, a sculptural solar panel that distributes energy to other arts on the playa, to eliminate generators and noise while promoting the use of renewable energy sources.

By day, the Living Knitwork Pavilion served as a shade structure, while providing a communal space for meditation and discovery. As the sun shifts through the day, hidden-encrypted textile patterns and visual experience are revealed through photochromism and luminescent glow. As dusk descended upon the desert, the pavilion underwent a metamorphosis, illuminating its surroundings through an immersive lighting and audio system. Through a distributed network of antennas embedded within the central structure and each knitwork petal, the team’s ultimate goal was to create an intimate experience that allows individual and collective movement and activity to influence the overall ambience of the space, involving sound and illumination.

Throughout Burning Man, the pavilion also hosted pop-up events, from yoga sessions, dance performances, live music, and even a wedding ceremony. Unfortunately, in the last two days of the event, a heavy rainstorm hit the Black Rock Desert — a rarity for the event. Yet, this climatic twist worked in favor of the pavilion, helping cleanse its textile surface from the accumulated dust and reviving its vivid blue color.

The result of this grand project is a collaboration that transcends disciplinary boundaries. The research team aims to exemplify the remarkable possibilities that arise when architecture, technology, and textile arts converge and bring communities together.

The interdisciplinary group behind the Living Knitwork Pavilion includes researchers from across the Media Lab, the MIT Center for Bits and Atoms, and the Department of Architecture: Irmandy Wicaksono, Sam Chin, Alfonso Parra Rubio, Nicole Bakker, Erik Strand, Gabriela Advincula, Manaswi Mishra, Age van der Mei, Judyta Cichoka, Tongge Yu, and Angelica Zhang.

Business leaders, product developers, and technology scouts convened at the RISE® (Research, Innovation & Science for Engineered Fabrics) Conference, Sept. 26-27, Raleigh, NC for two days of valuable insights in material science, process and sustainability innovations. RISE is co-organized by INDA and The Nonwovens Institute, North Carolina State University.

Industry, academic, and government experts shared their expertise in these key areas:

• The future of nonwoven manufacturing
• Real-world applications and advances in filter media
• rPolymers and sustainability
• Innovative strategies and circular solutions
• Advancements in sustainable nonwoven applications
• Market statistics and data trends

A highlight of RISE was a poster presentation of fundamental nonwovens research by The Nonwovens Institute’s graduate students. As an added value, The Nonwovens Institute offered RISE participants a tour of its world-class facilities located on the Centennial Campus of North Carolina State University, featuring the most extensive set of lab- and pilot-scale equipment found anywhere including all the nonwovens platform and testing technologies.

RISE® Innovation Award Winner
TiHive won the 2023 RISE Innovation Award for their SAPMonit technology. TiHive’s innovation, SAPMonit – a technology breakthrough, inspects millions of diapers weekly. SAPMonit delivers lightning-speed inline inspection of superabsorbents’ weight and distribution, optimizes resources, detects flaws, and accelerates R&D. SAPMonit utilizes advanced see-through cameras, high-speed vision algorithms, and secure cloud integration, revolutionizing industry norms. SAPMonit has great potential for sustainability, cost reduction, and enhanced customer satisfaction as it avoids hundreds of tons of plastic waste per year per machine.

The RISE Innovation Award finalists included Curt. G. Joa, Inc. for their ESC-8 – The JOA® Electronic Size Change, Fiberpartner Aps for their BicoBio Fiber, and Reifenhäuser REICOFIL GmbH & Co. KG for their Reifenhäuser Reicofil RF5 XHL.  Together, these finalists’ innovations have the potential to reduce plastic waste by millions of kgs.

DiaperRecycle won the 2022 RISE® Innovation Award for its innovative technology to recycle used diapers into absorbent and flushable cat litter. By diverting used diapers from households and institutions, and separating the plastic and fiber, DiaperRecycle strives to decrease the climate-changing emissions of diapers from landfills.

2023 INDA Lifetime Technical Achievement Award
Ed Thomas, President, Nonwoven Technology Associates, LLC, received the 2023 INDA Lifetime Technical Achievement Award for his decades of nonwoven contributions to the growth and success of the nonwoven industry.

RISE 2024 will be held October 1-2, 2024 at the James B. Hunt Jr. Library at North Carolina State University in Raleigh, NC.

Focusing on short-term profit isn’t sustainable. So what can we do to move in the right direction: favour resilience over efficiency in all industries.

We buy cheap products knowing we’ll need to replace them soon. We throw out used items rather than repairing or re-using them. Our employers plan in terms of financial quarters despite hoping to remain relevant and resilient longer-term. Even countries prioritise short-term economic output, focusing on gross domestic product (GDP) above any other indicator.

But does this way of living, working and weighing decisions make sense in the 21st century?

Our global obsession with economic short-term efficiency – and how to transform it – is a conundrum that Professor of Sustainability Management Minna Halme has been thinking about for most of her career. Even as a business school student, she felt flummoxed by how focused her classes were on short-term goals.

'It was about selling more, about maximising shareholder profits, about economic growth – but not really asking, Why? What's the purpose of all this?'

Halme says. 'Even 20-year-old me somehow just felt that this was strange.

'What are we trying to do here? Are we trying to create a better economy for all, or most, people? Whose lives are we trying to improve when we are selling more differently-packaged types of yoghurt or clothes that quickly become obsolete?'

Halme has devoted her career to studying these questions. Today, she is a thought leader in innovative business practices, with recognitions including serving on Finland's National Expert Panel for Sustainable Development and on the United Nation's Panel on Global Sustainability.

Her ultimate goal? Pioneering, researching and advocating for alternative ways of thinking that prioritise values like long-term economic sustainability and resilience – alternatives that she and other experts believe would provide more lasting, widespread benefit to all.

How traditional indicators have failed
One way in which our preference for economic efficiency shapes how we measure a country's overall well-being or status is GDP. This isn't the fault of the originator of the modern concept of GDP, who specifically warned against using it in this way in the 1930s.

'GDP was never meant to tell us about the wellbeing of the citizens of a country,' Halme says. Seventy-five years ago, however, it was easy to conflate the two. Many countries were more committed to redistributing their wealth among their citizens, and population surveys show that until the 1970s, GDP often correlated with general wellbeing.

But with the rise of increasingly heedless free-market capitalism, this became less the case – and GDP's shortcomings became all the more apparent. 'We are in a situation where the wealth distribution is more and more trickling up to those who already have capital. Those who don't have it are in declining economic positions,' Halme says. In fact, the richest 1% of the global population now own nearly half of the world's wealth.

Some governments, such as Finland's, do take indicators of environmental and social progress into account. 'But none is considered as important for decision-making as GDP,' Halme says – and GDP is also considered the arbiter of a government's success. It is that attitude that, through her work advising the Finnish government on sustainability practises as well as in her own research, Halme is trying to shift.

Where industries have failed
Our often-exclusive focus on the economy – and, in particular, on making profits as quickly and efficiently as possible – doesn’t provide a clear picture of how everyone in a society is faring. Worse yet, it has encouraged industries to act with a short-term view that makes for longer-term problems.

Fast fashion is one example. At the moment, supply chains for clothing – as for most other goods – are linear. Raw materials come from one place and are transformed step by step, usually at different factories around the world, using materials, energy and transport that are “cheap” because their high environmental costs aren’t included. They are ultimately purchased by a consumer, who wears the product temporarily before discarding it. To expand profit margins, the industry pushes fast-changing trends. A shocking amount of this clothing ends up in landfill – some of it before it's even been worn.

As the COVID lockdowns showed, this kind of linear supply system isn't resilient. Nor is it sustainable.

Currently, fashion is estimated to be the world's second most polluting industry, accounting for up to 10% of all greenhouse gas emissions. Aalto University researchers have reported that the industry produces more than 92 million tonnes of landfill waste per year. By 2030, that is expected to rise to 134 million tonnes.

Cutting fashion's carbon footprint isn't just good for the environment; it will help the longer-term prospects of the industry itself. 'With this kind of wrong thinking about efficiency, you're eroding the basis of our long-term resilience both for ecology and for society,' Halme says.

Getting out of this trap, she and other researchers say, requires a complete paradigm shift. 'It's really difficult to just tweak around the edges,' she says.

Towards resilience
For several years, Halme researched and studied ecological efficiency, looking at ways that businesses could make more products with a smaller environmental impact. But gradually she realised this wasn't the answer. Although businesses could innovate to have more efficient products and technologies, their absolute use of natural resource use kept growing.

'I began to think, "If not efficiency, then what?"' Halme says. She realised the answer was resilience: fostering ways for systems, including the environment, to continue and even regenerate in the future, rather than continuing to degrade them in the present.

The solution isn’t more of anything, even ‘sustainable’ materials. It’s less.

'The only way to fix fast fashion is to end it,' Halme and her co-authors write. This means designing clothes to last, business models that make reuse and repair more accessible, and prioritising upcycling. Recycling systems also need to be overhauled for when an item really is at the end of its life – particularly regarding blended synthetic fibres, which are difficult to separate and break down.

This would upend the current focus on short-term revenue above all else. And, says Halme, it is one more example of how we need better ways to measure the success of these industries, taking into account factors like resilience and sustainability – rather than just short-term profits.

And while individuals can make an impact, these changes ultimately have to be industry-led.

'Textiles are a good example, because if they break quickly, and if you don't have repair services nearby, or if the fabrics are of such lousy quality that it doesn't make any sense to repair them, then it's too much trouble for most people,' Halme says. 'So most solutions should come from the business side. And the attempt should be to make it both fashionable and easy for consumers to make ecologically and socially sustainable choices.'

What will it take?
The ultimate challenge, says Lauri Saarinen, Assistant Professor at the Aalto University Department of Industrial Engineering and Management, is how to shift towards a more sustainable model while keeping companies competitive. But he believes there are ways.

One option is to keep production local. 'If we compete with low-cost, offshore manufacturing by doing things more locally, and in a closed loop, then we get the double benefit of actually providing some local work and moving towards a more sustainable supply chain,' Saarinen says. For example, if clothing were produced closer to consumers, it would be easier to send garments back for repair or for brands to take back used items and resell them.

Local production is yet another example of the need to rethink how we measure societal success. After all, outsourcing and offshoring in favour of cheaper production may appear to cut costs in short term, but this is done at the expense of what Halme and other experts argue really matters – longer-term economic viability, resilience and sustainability.

Shifting towards this kind of thinking isn't easy. Still, Saarinen and Halme have seen promising signs.

In Finland, for example, Halme points to the start-up Menddie, which makes it easy and convenient to send items away for repairs or alterations. She also highlights the clothing and lifestyle brand Marimekko, which re-sells its used items in an online secondhand shop, and the Anna Ruohonen label, a made-to-measurecollection and customer on-demand concept which creates no excess garments.

It's these kinds of projects that Halme finds interesting – and that, through her work, she hopes to both advocate for and pioneer.

At the moment, she says, these changes haven't yet added up to a true transformation. On a global scale, we remain far from a genuine shift towards longer-term resilience. But as she points out, that can change quickly. After all, it has in the past. Just look at what got us here.

'The pursuit of economic growth became such a dominant focus in a relatively short time – only about seven decades,' she says. 'The shift toward longer-term resilience is certainly possible. Scientists and decision-makers just need to change their main goal to long-term resilience. The key question is, are our most powerful economic players wise enough to do so?'

As part of her research, Halme has led projects pioneering the kinds of changes that the fashion industry could adapt. For example, along with her Aalto colleague Linda Turunen, she recently developed a measurement that the fashion industry could use to classify how sustainable a product really is – measuring things like its durability, how easily it can be recycled, and whether its production uses hazardous chemicals – which could help consumers to decide whether to buy. Her colleagues curated a recent exhibition that showcased what we might be wearing in a sustainable future, such as a leather alternative made from discarded flower cuttings, or modular designs to get multiple uses from the same garment – turning a skirt into a shirt, for example.
 
Because all of this requires longer-term thinking, innovation and investment, industry is reticent to make these shifts, Halme says. One way to encourage industries to change more quickly is with regulation. In the European Union, for example, an updated set of directives now requires companies with more than 500 employees to report on a number of corporate responsibility factors, ranging from environmental impact to the treatment of employees. These rules won't just help inform consumers, investors and other stakeholders about a company's role in global challenges. They’ll also help assess investment risks – weighing whether a company is taking the actions necessary to be financially resilient in the long-term.

A newly developed concept for chemical protective suits is designed to make use more comfortable and safer for the user. New materials and an improved design increase wearer comfort. The integration of sensor technology enables the monitoring of vital functions.

In the event of hazards from chemical, biological or radioactive substances, chemical protective suits (CSA) protect people from physical contact. CSAs consist of breathing apparatus, head protection, carrying frames and the suit itself. This adds up to a weight of around 25 kg. The construction of a multi-coated fabric makes the CSA stiff and provides for considerable restrictions in freedom of movement. As a result, the emergency forces are exposed to significant physical stress. For this reason, the total deployment time when using a CSA is limited to 30 minutes.

In a joint project with various companies, institutes and professional fire departments, work is currently underway to completely redesign both the textile material composite and the hard components and connecting elements between the two. The goal is a so-called "AgiCSA", which offers significantly more comfort for the emergency forces due to its lighter and more flexible construction. The DITF subproject focuses on the development of a more individually adaptable, body-hugging suit on the one hand, and on the integration of sensors that serve the online monitoring of important body functions of the emergency personnel on the other.

At the beginning of the project, the DITF received support from the Esslingen Fire Department. They provided a complete CSA that is used as standard today. This could be tested at the DITF for its wearing properties. The researchers in Denkendorf are investigating where there is a need for optimization to improve ergonomic wearing comfort.

The aim is to construct a chemical- and gas-tight suit that fits relatively closely to the body. It quickly became clear that it was necessary to move away from the previous concept of using woven fabrics as the basic textile material and think in terms of elastic knitted fabrics. In implementing this idea, the researchers were helped by recent developments in the field of knitted fabric technology in the form of spacer fabrics. By using spacer textiles, many of the requirements placed on the base substrate can be met very well.

Spacer textiles have a voluminous, elastic structure. From a wide range of usable fiber types and three-dimensional design features, a 3 mm thick spacer textile made of a polyester pile yarn and a flame-retardant fiber blend of aramid and viscose was selected for the new CSA. This textile is coated on both sides with fluorinated or butyl rubber. This gives the textile a barrier function that prevents the penetration of toxic liquids and gases. The coating is applied to the finished suit by a newly developed spraying process. The advantage of this process over the conventional coating process is that the desired elasticity of the suit is retained.

Another innovation is the integration of a diagonal zipper. This makes it easier to put on and take off the suit. Whereas this was previously only possible with the help of another person, the new suit can in principle be put on by the emergency responder alone. The new design is modeled on modern dry suits with diagonal, gas-tight zippers.
The new AgiSCA also features integrated sensors that allow the transmission and monitoring of the vital and environmental data of the emergency worker as well as their location via GPS data. These additional functions significantly enhance operational safety.

For the hard components, i.e. the helmet and the backpack for the compressed air supply, lightweight carbon fiber-reinforced composite materials from Wings and More GmbH & Co. KG are used.
The first demonstrators are available and are available to the project partners for testing purposes. The combination of current textile technology, lightweight construction concepts and IT integration in textiles has led to a comprehensive improvement of a high-tech product in this project.
 
BMBF project "Development of a chemical protection suit with increased mobility for more efficient operational concepts through increased autonomy of the emergency forces (AgiCSA)".
The project addresses the objectives of the Federal Government's framework program "Research for Civil Security 2018-2023 and the funding measure "SME-innovative: Research for Civil Security" of July 3, 2018.

 

Researchers have developed next-generation smart textiles – incorporating LEDs, sensors, energy harvesting, and storage – that can be produced inexpensively, in any shape or size, using conventional industrial looms used to make the clothing worn every day.
 
An international team, led by the University of Cambridge, have previously demonstrated that woven displays can be made at large sizes, but these earlier examples were made using specialised manual laboratory equipment. Other smart textiles can be manufactured in specialised microelectronic fabrication facilities, but these are highly expensive and produce large volumes of waste.

However, the team found that flexible displays and smart fabrics can be made much more cheaply, and more sustainably, by weaving electronic, optoelectronic, sensing and energy fibre components on the same industrial looms used to make conventional textiles. Their results, reported in the journal Science Advances, demonstrate how smart textiles could be an alternative to larger electronics in sectors including automotive, electronics, fashion and construction.

Despite recent progress in the development of smart textiles, their functionality, dimensions and shapes have been limited by current manufacturing processes.
“We could make these textiles in specialised microelectronics facilities, but these require billions of pounds of investment,” said Dr Sanghyo Lee from Cambridge’s Department of Engineering, the paper’s first author. “In addition, manufacturing smart textiles in this way is highly limited, since everything has to be made on the same rigid wafers used to make integrated circuits, so the maximum size we can get is about 30 centimetres in diameter.”

“Smart textiles have also been limited by their lack of practicality,” said Dr Luigi Occhipinti, also from the Department of Engineering, who co-led the research. “You think of the sort of bending, stretching and folding that normal fabrics have to withstand, and it’s been a challenge to incorporate that same durability into smart textiles.”
Last year, some of the same researchers showed that if the fibres used in smart textiles were coated with materials that can withstand stretching, they could be compatible with conventional weaving processes. Using this technique, they produced a 46-inch woven demonstrator display.

Now, the researchers have shown that smart textiles can be made using automated processes, with no limits on their size or shape. Multiple types of fibre devices, including energy storage devices, light-emitting diodes, and transistors were fabricated, encapsulated, and mixed with conventional fibres, either synthetic or natural, to build smart textiles by automated weaving. The fibre devices were interconnected by an automated laser welding method with electrically conductive adhesive.
 
The processes were all optimised to minimise damage to the electronic components, which in turn made the smart textiles durable enough to withstand the stretching of an industrial weaving machine. The encapsulation method was developed to consider the functionality of the fibre devices, and the mechanical force and thermal energy were investigated systematically to achieve automated weaving and laser-based interconnection, respectively.

The research team, working in partnership with textile manufacturers, were able to produce test patches of smart textiles of roughly 50x50 centimetres, although this can be scaled up to larger dimensions and produced in large volumes.
 
“These companies have well-established manufacturing lines with high throughput fibre extruders and large weaving machines that can weave a metre square of textiles automatically,” said Lee. “So when we introduce the smart fibres to the process, the result is basically an electronic system that is manufactured exactly the same way other textiles are manufactured.”
The researchers say it could be possible for large, flexible displays and monitors to be made on industrial looms, rather than in specialised electronics manufacturing facilities, which would make them far cheaper to produce. Further optimisation of the process is needed, however.

“The flexibility of these textiles is absolutely amazing,” said Occhipinti. “Not just in terms of their mechanical flexibility, but the flexibility of the approach, and to deploy sustainable and eco-friendly electronics manufacturing platforms that contribute to the reduction of carbon emissions and enable real applications of smart textiles in buildings, car interiors and clothing. Our approach is quite unique in that way.”

The research was supported in part by the European Union and UK Research and Innovation.

In a new study, North Carolina State University researchers found they could separate blended cotton and polyester fabric using enzymes – nature’s tools for speeding chemical reactions. Ultimately, they hope their findings will lead to a more efficient way to recycle the fabric’s component materials, thereby reducing textile waste. However, they also found the process need more steps if the blended fabric was dyed or treated with chemicals that increase wrinkle resistance.

“We can separate all of the cotton out of a cotton-polyester blend, meaning now we have clean polyester that can be recycled,” said the study’s corresponding author Sonja Salmon, associate professor of textile engineering, chemistry and science at NC State. “In a landfill, the polyester is not going to degrade, and the cotton might take several months or more to break down. Using our method, we can separate the cotton from polyester in less than 48 hours.”
 
According to the U.S. Environmental Protection Agency, consumers throw approximately 11 million tons of textile waste into U.S. landfills each year. Researchers wanted to develop a method of separating the cotton from the polyester so each component material could be recycled.

In the study, researchers used a “cocktail” of enzymes in a mildly acidic solution to chop up cellulose in cotton. Cellulose is the material that gives structure to plants’ cell walls. The idea is to chop up the cellulose so it will “fall out” out of the blended woven structure, leaving some tiny cotton fiber fragments remaining, along with glucose. Glucose is the biodegradable byproduct of degraded cellulose. Then, their process involves washing away the glucose and filtering out the cotton fiber fragments, leaving clean polyester.
 
“This is a mild process – the treatment is slightly acidic, like using vinegar,” Salmon said. “We also ran it at 50 degrees Celsius, which is like the temperature of a hot washing machine.
“It’s quite promising that we can separate the polyester to a clean level,” Salmon added. “We still have some more work to do to characterize the polyester’s properties, but we think they will be very good because the conditions are so mild. We’re just adding enzymes that ignore the polyester.”

They compared degradation of 100% cotton fabric to degradation of cotton and polyester blends, and also tested fabric that was dyed with red and blue reactive dyes and treated with durable press chemicals. In order to break down the dyed materials, the researchers had to increase the amount of time and enzymes used. For fabrics treated with durable press chemicals, they had to use a chemical pre-treatment before adding the enzymes.

“The dye that you choose has a big impact on the potential degradation of the fabric,” said the study’s lead author Jeannie Egan, a graduate student at NC State. “Also, we found the biggest obstacle so far is the wrinkle-resistant finish. The chemistry behind that creates a significant block for the enzyme to access the cellulose. Without pre-treating it, we achieved less than 10% degradation, but after, with two enzyme doses, we were able to fully degrade it, which was a really exciting result.”

Researchers said the polyester could be recycled, while the slurry of cotton fragments could be valuable as an additive for paper or useful addition to composite materials. They’re also investigating whether the glucose could be used to make biofuels.

“The slurry is made of residual cotton fragments that resist a very powerful enzymatic degradation,” Salmon said. “It has potential value as a strengthening agent. For the glucose syrup, we’re collaborating on a project to see if we can feed it into an anaerobic digester to make biofuel. We’d be taking waste and turning it into bioenergy, which would be much better than throwing it into a landfill.”

The study, “Enzymatic textile fiber separation for sustainable waste processing,” was published in Resources, Environment and Sustainability. Co-authors included Siyan Wang, Jialong Shen, Oliver Baars and Geoffrey Moxley. Funding was provided by the Environmental Research and Education Foundation, Kaneka Corporation and the Department of Textile Engineering, Chemistry and Science at NC State.

Precisely applied metal-organic technology detects and captures toxic gases in air.

A durable copper-based coating developed by Dartmouth researchers can be precisely integrated into fabric to create responsive and reusable materials such as protective equipment, environmental sensors, and smart filters, according to a recent study.
 
The coating responds to the presence of toxic gases in the air by converting them into less toxic substances that become trapped in the fabric, the team reports in Journal of the American Chemical Society.

The findings hinge on a conductive metal-organic technology, or framework, developed in the laboratory of corresponding author Katherine Mirica, an associate professor of chemistry. First reported in JACS in 2017, the framework was a simple coating that could be layered onto cotton and polyester to create smart fabrics the researchers named SOFT—Self-Organized Framework on Textiles. Their paper demonstrated that SOFT smart fabrics could detect and capture toxic substances in the surrounding environment.

For the newest study, the researchers found that—instead of the simple coating reported in 2017—they can precisely embed the framework into fabrics using a copper precursor that allows them to create specific patterns and more effectively fill in the tiny gaps and holes between threads.

The researchers found that the framework technology effectively converted the toxin nitric oxide into nitrite and nitrate, and transformed the poisonous, flammable gas hydrogen sulfide into copper sulfide. They also report that the framework’s ability to capture and convert toxic materials withstood wear and tear, as well as standard washing.
 
The versatility and durability the new method provides would allow the framework to be applied for specific uses and in more precise locations, such as a sensor on protective clothing, or as a filter in a particular environment, Mirica said.

“This new method of deposition means that the electronic textiles could potentially interface with a broader range of systems because they’re so robust,” she said. “This technological advance paves the way for other applications of the framework’s combined filtration and sensing abilities that could be valuable in biomedical settings and environmental remediation.”
The technique also could eventually be a low-cost alternative to technologies that are cost prohibitive and limited in where they can be deployed by needing an energy source, or—such as catalytic converters in automobiles—rare metals, Mirica said.
 
“Here we’re relying on an Earth-abundant matter to detoxify toxic chemicals, and we’re doing it without any input of outside energy, so we don’t need high temperature or electric current to achieve that function,” Mirica said.

Co-first author Michael Ko, initially observed the new process in 2018 as he attempted to deposit the metal-organic framework onto thin-film copper-based electrodes, Mirica said. But the copper electrodes would be replaced by the framework.

“He wanted it on top of the electrodes, not to replace them,” Mirica said. “It took us four years to figure out what was happening and how it was beneficial. It’s a very straightforward process, but the chemistry behind it is not and it took us some time and additional involvement of students and collaborators to understand that.”

The team discovered that the metal-organic framework “grows” over copper, replacing it with a material with the ability to filter and convert toxic gases, Mirica said. Ko and co-author Lukasz Mendecki, a postdoctoral scholar in the Mirica Group from 2017-18, investigated methods for applying the framework material to fabric in specific designs and patterns.

Co-first author Aileen Eagleton, who is also in the Mirica Group, finalized the technique by optimizing the process for imprinting the metal-organic framework onto fabric, as well as identifying how its structure and properties are influenced by chemical exposure and reaction conditions.

Future work will focus on developing new multifunctional framework materials and scaling up the process of embedding the metal-organic coatings into fabric, Mirica said.